2,6-二溴-4-壬基苯酚 | 103526-64-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 2,6-二溴-4-壬基苯酚
• 英文名称: 2,6-dibromononylphenol
• 英文别名: 2,6-dibromo-4-nonylphenol
• CAS: 103526-64-3
• 化学式: C₁₅H₂₂Br₂O
• 分子量: 378.147
• InChiKey: JEGPPLVKZCYSRR-UHFFFAOYSA-N

物化性质

• 沸点：
  376.3±37.0 °C(Predicted)
• 密度：
  1.407±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,6-二溴-4-壬基苯酚 在 palladium on activated charcoal 超重氢 作用下， 生成 对壬基酚
  参考文献：
  名称：

  Characterization of biliary metabolites of 4-n-nonylphenol in rainbow trout (Oncorhynchus mykiss)

  摘要：

  1. [R-2,6-H-3]-4-n-nonylphenol was synthesized and a single dose (5 mg, 1850 KBq) orally administered to rainbow trout. After 48 h, the radioactivity present in the bile amounted 5.5 %. More than ten biliary metabolites were separated by hplc and collected for subsequent mass spectrometry analysis. The metabolic profile was totally modified by beta-glucuronidase hydrolysis, showing that most of the metabolites were glucuronic acid conjugates.2. Conjugated metabolites were identified by Ic-ms analysis and their aglycones were analysed by gc-ms analysis as TMS and acetyl derivatives.3. The major metabolite accounted for 52 +/- 11% of the biliary radioactivity and was identified as nonylphenol-glucuronide.4. Nonylphenol was hydroxylated at both omega and omega-1 positions of the alkyl chain, giving 9-hydroxynonylphenol and 8-hydroxynonylphenol.5. 9-Hydroxynonylphenol was oxidized to the corresponding acid, and subsequently beta-oxidized, yielding 7-(4-hydroxyphenyl)heptanoic acid, 5-(4-hydroxyphenyl)pentanoic acid, 3-(4-hydroxyphenyl)propionic acid and 3-(4-hydroxyphenyl)-2-propenoic acid.

  DOI：

  10.1080/004982598239164
• 作为产物：
  描述：

  对壬基酚 在 溴 作用下， 生成 2,6-二溴-4-壬基苯酚
  参考文献：
  名称：

  Brominated materials

  摘要：

  描述了由（烷基，溴基）苯氧基烷基（甲基）丙烯酸酯单体制备的聚合物。

  公开号：

  US06359170B1

文献信息

• High refractive index pressure-sensitive adhesives
  申请人：Olson B. David

  公开号：US20050272949A1

  公开（公告）日：2005-12-08

  The present invention provides pressure-sensitive adhesives having a refractive index of at least 1.48. The pressure-sensitive adhesives comprise at least one monomer containing a substituted or an unsubstituted aromatic moiety.

  本发明提供了折射率至少为1.48的压敏胶粘剂。这些压敏胶粘剂包括至少一种含有取代或未取代芳香基团的单体。
• HIGH REFRACTIVE INDEX PRESSURE-SENSITIVE ADHESIVES
  申请人：OLSON B. DAVID

  公开号：US20070264517A1

  公开（公告）日：2007-11-15

  The present invention provides pressure-sensitive adhesives having a refractive index of at least 1.48. The pressure-sensitive adhesives comprise at least one monomer containing a substituted or an unsubstituted aromatic moiety.

  本发明提供了折射率至少为1.48的压敏胶粘剂。压敏胶粘剂包括至少一个含有取代或未取代芳香基团的单体。
• HIGH INDEX OF REFRACTION MONOMERS
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0994844B1

  公开（公告）日：2002-07-31
• CHEMICAL COMPOSITION AND POLYMERS AND POLYMERIC MATERIALS DERIVED THEREFROM
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0980398A1

  公开（公告）日：2000-02-23
• OPTICAL PRODUCT PREPARED FROM HIGH INDEX OF REFRACTION BROMINATED MONOMERS
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0980532A1

  公开（公告）日：2000-02-23