二乙基氟化铝 | 367-44-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 中文名称: 二乙基氟化铝
• 英文名称: Diethylaluminiumfluorid
• 英文别名: Diaethyl-aluminiumfluorid；Diethylaluminum fluoride；diethylalumanylium;fluoride
• CAS: 367-44-2
• 化学式: C₄H₁₀AlF
• 分子量: 104.103
• InChiKey: HRXSKIOIHQEGAI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.99
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  叠氮基三甲基硅烷 、 二乙基氟化铝 在 碳酸氢钠 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成 (2S,3S) 3-Azido-5,5-dimethoxypentane-1,2-diol
  参考文献：
  名称：

  Process for the synthesis of 2',3'-dideoxynucleosides

  摘要：

  公开号：

  US05220003A1
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium fluoride 作用下， 生成 二乙基氟化铝
  参考文献：
  名称：

  Ziegler; Koester, Justus Liebigs Annalen der Chemie, 1957, vol. 608, p. 1,6

  摘要：

  DOI：
• 作为试剂：
  描述：

  苯硒酚 在 叔丁基二甲硅基三氟甲磺酸酯 吡啶 、 盐酸 、 二乙基氟化铝 作用下， 以 二氯甲烷 为溶剂， 生成 5'-acetyl-3'-selenophenylthymidine
  参考文献：
  名称：

  Synthesis of antiviral nucleosides from crotonaldehyde. Part 3.1,2 total synthesis of didehydrodideoxythymidine (d4T)

  摘要：

  The total synthesis of the antiviral agent d4T 3 from the epoxyalcohol 2, itself derived from crotonaldehyde 1, in 6 steps and 18% overall yield is described.

  DOI：

  10.1016/s0040-4039(00)74799-x

文献信息

• Optical and electrochemical properties and the calculated structure of pentacoordinate aluminum 8-hydroxyquinoline
  作者：Cheolbeom Bae、A.J. Saleh Ahammad、Jae-Joon Lee、Gwanghoon Kwag

  DOI：10.1016/j.ica.2011.04.001

  日期：2011.7

  In this study we report on the characterization of a series of pentacoordinate aluminum 8-hydroxyquinolines, AlQ(2)X (X = F, Cl, Br), composed of two 8-hydroxyquinoline (8-HQ) groups and one halogen ligand. These were prepared by reacting 8-hydroxyquinoline and dialkylaluminum halide stoichiometrically. The lambda(max)s of absorption and emission were in the range of 385-388 and 515-516 nm, respectively, which were similar to AlQ(3). The molar absorptivity of AlQ(2)X is similar regardless of the X group but emission efficiency of AlQ(2)X is 2-3 fold higher than that of AlQ(3) when X = F or Br, but not when X = Cl. This result can be attributed to decreased quenching of energy due to a less steric environment by reducing quinolinate content. The overall molecular orbital structures and the absorption spectra of AlQ(2)X and AlQ(3) are very similar due to a single quinolinate unit. The value of the potential difference of AlQ(2)Xs between anodic and cathodic waves (Delta E = 3.12 V) is close to the estimated HOMO-LUMO energy gap (the optical band gap, Delta E-optical similar to 1240/lambda(max)), 3.19 eV. Detailed optical and electrochemical properties of AlQ(2)X are discussed. (C) 2011 Elsevier B. V. All rights reserved.
• Effect of the nature of the organoaluminum compound on the direction of the reaction with xenon difluoride
  作者：R. G. Bulgakov、V. N. Yakovlev、G. Ya. Maistrenko、G. A. Tolstikov、V. P. Kazakov

  DOI：10.1007/bf00952953

  日期：1986.2
• BULGAKOV, R. G.;YAKOVLEV, V. I.;MAJSTRENKO, G. YA.;TOLSTIKOV, G. A.;KAZAK+, IZV. AN CCCP. CEP. XIM., 1986, N 2, 490-491
  作者：BULGAKOV, R. G.、YAKOVLEV, V. I.、MAJSTRENKO, G. YA.、TOLSTIKOV, G. A.、KAZAK+

  DOI：——

  日期：——
• Process for the synthesis of 2',3'-dideoxynucleosides
  申请人：The Regents of the University of California

  公开号：US05220003A1

  公开（公告）日：1993-06-15
• Ziegler; Koester, Justus Liebigs Annalen der Chemie, 1957, vol. 608, p. 1,6
  作者：Ziegler、Koester

  DOI：——

  日期：——