1-allyl-3,5-dimethylisocyanurate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1-allyl-3,5-dimethylisocyanurate
• 英文别名: 5-allyl-1,3-dimethylisocyanurate；dimethyl monoallyl isocyanurate；Allyldimethyliso cyanurate；1,3-dimethyl-5-prop-2-enyl-1,3,5-triazinane-2,4,6-trione
• 化学式: C₈H₁₁N₃O₃
• 分子量: 197.194
• InChiKey: JAJDXONFQWQAGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-allyl-3,5-dimethylisocyanurate 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 64.5h， 以73.1%的产率得到dimethyl monoglycidyl isocyanurate
  参考文献：
  名称：

  MONOGLYCIDYL ISOCYANURATE COMPOUND AND PRODUCTION METHOD THEREFOR

  摘要：

  提供了一种新的异氰酸酯化合物，其具有作为取代基的环氧丙烯基与氮原子结合。以下是一种单环氧丙烯基异氰酸酯化合物的化学式（1）、（2）或（3）。其中两个R1均为C2-10烷基基团，两个R2均为C1-5烷基烯基团，两个R3均为C1-2烷基基团，两个R4均为C1-2烷基烯基团，两个R5均为C1-2烷基基团。

  公开号：

  US20190135795A1
• 作为产物：
  描述：

  3-溴丙烯 、 1,3-dimethylisocyanurate 在 sodium 作用下， 以 正丁醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 以71%的产率得到1-allyl-3,5-dimethylisocyanurate
  参考文献：
  名称：

  Electrocatalytic fluoroalkylation of olefins. Nickel-catalyzed polyfluoroalkylation of allylisocyanurates

  摘要：

  烯丙基异氰尿酸盐和多氟烷基卤化物在带有 α-二亚胺配体的镍络合物存在下发生电化学共还原反应，导致多氟烷基加到 C=C 键上，然后中间加合物发生二聚反应。

  DOI：

  10.1007/s11172-013-0342-4

文献信息

• CURABLE RESIN COMPOSITION, AND CURED PRODUCT, SEALING AGENT, AND OPTICAL SEMICONDUCTOR DEVICE USING SAME
  申请人：Daicel Corporation

  公开号：EP2857457A1

  公开（公告）日：2015-04-08

  Provided is a curable resin composition capable of forming a cured product that excels in heat resistance, transparency, and flexibility and particularly excels in barrier properties against a corrosive gas (e.g., sulfur oxide). The curable resin composition includes a compound (U) containing an aliphatic carbon-carbon unsaturated bond and a compound (H) containing a hydrosilyl group and includes at least one of a ladder-type silsesquioxane [A1] and a ladder-type silsesquioxane [A2], where the ladder-type silsesquioxane [A1] contains an aliphatic carbon-carbon unsaturated bond and has a number-average molecular weight of 500-1500 and a molecular weight dispersity (Mw/Mn) of 1.00-1.40 as determined by gel permeation chromatography and calibrated with a polystyrene standard, and the ladder-type silsesquioxane [A2] contains a hydrosilyl group and has a number-average molecular weight of 500-1500 and a molecular weight dispersity (Mw/Mn) of 1.00-1.40 as determined by gel permeation chromatography and calibrated with a polystyrene standard.

  本发明提供了一种可固化树脂组合物，该组合物能够形成具有优异耐热性、透明度和柔韧性的固化产品，尤其是对腐蚀性气体（如氧化硫）具有优异的阻隔性能。 可固化树脂组合物包括含有脂肪族碳-碳不饱和键的化合物（U）和含有氢硅烷基的化合物（H），并包括梯形硅倍半氧烷[A1]和梯形硅倍半氧烷[A2]中的至少一种，其中梯形硅倍半氧烷[A1]含有脂肪族碳-碳不饱和键，其数均分子量为 500-1500，分子量分散度（Mw/Mn）为 1.阶梯型硅倍半氧烷[A2]含有一个氢硅烷基，平均分子量为500-1500，分子量分散度（Mw/Mn）为1.00-1.40（通过凝胶渗透色谱法测定，并用聚苯乙烯标准校准）。
• CURABLE RESIN COMPOSITION, AND CURED PRODUCT OF SAME
  申请人：Daicel Corporation

  公开号：EP2944675A1

  公开（公告）日：2015-11-18

  Provided is a curable resin composition capable of forming a cured product that has excellent heat resistance, transparency, and flexibility and, in particular, offers superior reflow resistance and barrier properties to a corrosive gas. The curable resin composition according to the present invention includes a polyorganosiloxane (A), a silsesquioxane (B), an isocyanurate compound (C), and a silane coupling agent (D). The polyorganosiloxane (A) is a polyorganosiloxane approximately devoid of aryl groups. The silsesquioxane (B) includes a ladder-like silsesquioxane.

  本发明提供了一种可固化树脂组合物，该组合物能够形成具有优异耐热性、透明度和柔韧性的固化产品，特别是具有优异的耐回流性和对腐蚀性气体的阻隔性。 根据本发明的可固化树脂组合物包括聚有机硅氧烷（A）、硅烷氧基硅烷（B）、异氰尿酸酯化合物（C）和硅烷偶联剂（D）。聚有机硅氧烷（A）是一种近似不含芳基的聚有机硅氧烷。硅倍半氧烷（B）包括阶梯状硅倍半氧烷。
• CURABLE RESIN COMPOSITION, CURED PRODUCT, SEALING MEMBER SEMICONDUCTOR DEVICE
  申请人：Daicel Corporation

  公开号：EP2957599A1

  公开（公告）日：2015-12-23

  Provided is a curable resin composition capable of forming a cured product that has excellent heat resistance and transparency and, in particular, offers excellent barrier properties to a corrosive gas. The curable resin composition according to the present invention includes a polyorganosiloxane (A), an isocyanurate compound (B), and a silane coupling agent (C). The polyorganosiloxane (A) is an aryl-containing polyorganosiloxane. The polyorganosiloxane (A) preferably includes a polyorganosiloxane having a number-average molecular weight (Mn) of 500 to 4000 as determined by gel permeation chromatography and calibrated with a polystyrene standard.

  本发明提供了一种可固化树脂组合物，该组合物能够形成具有优异耐热性和透明度的固化产品，特别是对腐蚀性气体具有优异的阻隔性能。 根据本发明的可固化树脂组合物包括聚有机硅氧烷（A）、异氰尿酸酯化合物（B）和硅烷偶联剂（C）。聚有机硅氧烷（A）是一种含芳基的聚有机硅氧烷。聚有机硅氧烷（A）最好包括经凝胶渗透色谱法测定并用聚苯乙烯标准校准的数均分子量（Mn）为 500 至 4000 的聚有机硅氧烷。
• Curable resin composition and cured product thereof, encapsulant, and semiconductor device
  申请人：Daicel Corporation

  公开号：EP2985317A1

  公开（公告）日：2016-02-17

  Provided is a curable resin composition capable of forming a cured product that has excellent heat resistance and transparency and, in particular, offers excellent barrier properties to a corrosive gas. The curable resin composition according to the present invention includes a polyorganosiloxane (A), an isocyanurate compound (B), and a silane coupling agent (C). The polyorganosiloxane (A) is an aryl-containing polyorganosiloxane. The polyorganosiloxane (A) preferably includes a polyorganosiloxane having a number-average molecular weight (Mn) of 500 to 4000 as determined by gel permeation chromatography and calibrated with a polystyrene standard.

  本发明提供了一种可固化树脂组合物，该组合物能够形成具有优异耐热性和透明度的固化产品，特别是对腐蚀性气体具有优异的阻隔性能。 根据本发明的可固化树脂组合物包括聚有机硅氧烷（A）、异氰尿酸酯化合物（B）和硅烷偶联剂（C）。聚有机硅氧烷（A）是一种含芳基的聚有机硅氧烷。聚有机硅氧烷（A）最好包括一种通过凝胶渗透色谱法测定并用聚苯乙烯标准校准的数均分子量（Mn）为 500 至 4000 的聚有机硅氧烷。
• GLYCOLURILS HAVING FUNCTIONAL GROUP AND USE THEREOF
  申请人：Shikoku Chemicals Corporation

  公开号：EP3075735A1

  公开（公告）日：2016-10-05

  The invention provides a glycoluril represented by the general formula (Z): wherein the group Z represents a carboxyalkyl, a glycidyl or an allyl group; R1 and R2 each independently represents a hydrogen atom, a lower alkyl or a phenyl group; R3, R4 and R5 each independently represents a hydrogen atom or the group identical with the group Z; however, when the group Z is a carboxyalkyl group, R3, R4 and R5 are the same carboxyalkyl groups as the group Z; and when the group Z is an allyl group, R5 represents a hydrogen atom. The invention further provides various resin compositions, for example, polyester resin compositions, epoxy resin compositions, and silicone resin compositions each comprising the glycoluril.

  本发明提供了一种由通式 (Z) 代表的羟基苯磺酸： 其中基团 Z 代表羧烷基、缩水甘油基或烯丙基；R1 和 R2 各自独立地代表氢原子、低级烷基或苯基；R3、R4 和 R5 各自独立地代表氢原子或与基团 Z 相同的基团；但是，当基团 Z 是羧烷基时，R3、R4 和 R5 是与基团 Z 相同的羧烷基；当基团 Z 是烯丙基时，R5 代表氢原子。本发明进一步提供了各种树脂组合物，例如，聚酯树脂组合物、环氧树脂组合物和硅树脂组合物，每种组合物都包含羟基乙酸乙酯。