1H,1H,2H,2H-pentadecafluoro-nonan-1-ol | 755-02-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1H,1H,2H,2H-pentadecafluoro-nonan-1-ol
• 英文别名: 1,1,2,2-tetrahydroperfluorononyl alcohol；Telomer alcohol-L；3.3.4.4.5.5.6.6.7.7.8.8.9.9.9-Pentadecafluor-nonan-1-ol；1H,1H,2H,2H-Pentafluorononanol；2-(Perfluorheptyl)ethanol；3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Pentadecafluorononan-1-ol
• CAS: 755-02-2
• 化学式: C₉H₅F₁₅O
• 分子量: 414.114
• InChiKey: WOBDSRMWHWAQFO-UHFFFAOYSA-N

物化性质

• 沸点：
  84 °C(Press: 10 Torr)
• 密度：
  1.613±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  1H,1H,2H,2H-pentadecafluoro-nonan-1-ol 在 三氧化硫 作用下， 反应 0.5h， 生成 Bis(1H,1H,2H,2H-pentedecafluorononyl)pyrosulfat
  参考文献：
  名称：

  Fluorinated dialkyl mono- and polysulfates. I. Preparation and some reactions

  摘要：

  DOI：

  10.1021/jo00826a026
• 作为产物：
  描述：

  Bis(1H,1H,2H,2H-pentedecafluorononyl)pyrosulfat 在 硫酸 作用下， 生成 1H,1H,2H,2H-pentadecafluoro-nonan-1-ol
  参考文献：
  名称：

  Fluorinated dialkyl mono- and polysulfates. I. Preparation and some reactions

  摘要：

  DOI：

  10.1021/jo00826a026

文献信息

• Non-symmetric, partially fluorinated lubricant additives
  申请人：E. I. du Pont de Nemours and Company

  公开号：US06734320B2

  公开（公告）日：2004-05-11

  Novel non-symmetric, partially fluorinated compositions and method of manufacture which are useful as lubricants or as additives to lubricant formulations involving the molecular structure: R1f—F′—R2—F″—R3h where R1f represents a wholly or partially fluorinated organic residue end group, F′ and F″ represent functional linkages which may be alike or different, R2 represents the backbone and R3h represents a non-fluorinated organic residue end group. Such compositions are produced by reacting a mixture of alcohols, mercaptans or amines containing at least one partially fluorinated compound and at least one non-fluorinated compound in the mixture, thus producing the R1f and the R3h residues, with a difunctional organic compound (e.g., diacid, dinitrile, disulfonyl halide, diisocyanate, diisothiocyanate, diphosphoryl halide or dithiophosphoryl halide).

  一种新型的非对称、部分氟化组合物及其制造方法，可用作润滑剂或作为润滑剂配方的添加剂，其涉及分子结构：R1f—F′—R2—F″—R3h，其中R1f代表全氟或部分氟化有机残基末端基团，F′和F″代表可能相同或不同的功能性连接，R2代表骨架，R3h代表非氟化有机残基末端基团。这种组合物是通过反应含有至少一种部分氟化化合物和至少一种非氟化化合物的醇、巯基或胺的混合物来制备的，从而产生R1f和R3h残基，与双官能有机化合物（例如二酸、二腈、二磺酰卤、二异氰酸酯、二异硫氰酸酯、二磷酰卤或二硫代磷酰卤）反应。
• Fluorinated polyhedral oligomeric silsesquioxanes
  作者：Xiaobai Wang、Qun Ye、Jing Song、Ching Mui Cho、Chaobin He、Jianwei Xu

  DOI：10.1039/c4ra15108a

  日期：——

  A series of fluorinated polyhedral oligomeric silsesquioxane (POSS) derivatives were prepared via hydrosilylation reaction and they were characterized by 1H, 13C, 29Si and 19F nuclear magnetic resonance (NMR) spectroscopy and elemental analysis. The thermal stability of POSS derivatives was studied using thermogravimetric analysis (TGA) and they exhibited high decomposition temperatures ranging from

  通过氢化硅烷化反应制备了一系列氟化多面体低聚倍半硅氧烷（POSS）衍生物，并通过1 H，13 C，29 Si和19 F核磁共振（NMR）光谱和元素分析对其进行了表征。使用热重分析（TGA）研究了POSS衍生物的热稳定性，它们在空气和惰性气氛中表现出327至380°C的高分解温度。在环境温度下，氟化POSS（FluoroPOSS）化合物3a–b和3d–e表现为动态粘度为140–430 mPas的流体油，值得注意的是3a，3d和3e即使在−80°C以下也不要固化。进行了这些FluoroPOSS油的热老化实验，结果表明，这些油表现出优异的长期热稳定性，并在空气中48小时内失重最少，使其成为从- 80至300°C。这些氟化的POSS衍生物还显示出了聚合物表面改性的潜力，这由水接触角从纯亲水性PMMA膜的〜68°到含有5 wt％氟化衍生物的共混膜的94-105°大大增加所证明。水接触角的增加很可能是
• Fluorinated-photoinitiators in dual cure resins
  申请人：——

  公开号：US20040067311A1

  公开（公告）日：2004-04-08

  The present invention relates to a process for the preparation of scratch-resistant coatings by dual cure of compositions comprising surface active benzoyl compounds wherein at least one non-polar fluorinated alkyl group is present. The invention also relates to a process for concentrating these surface-active photoinitiators in the surface of coatings, to novel surface active benzoyl compounds wherein at least one non-polar fluorinated alkyl group is present, to compositions wherein the novel surface active fluorinated photoinitiators are present, and to a method for improving the flow of a curable composition on substrates.

  本发明涉及一种通过表面活性苯甲酰化合物的双重固化制备耐刮花涂层的方法，其中至少存在一个非极性氟化烷基。本发明还涉及一种将这些表面活性光引发剂浓缩在涂层表面的方法，以及至少存在一个非极性氟化烷基的新型表面活性苯甲酰化合物，包含这些新型表面活性氟化光引发剂的组合物，以及用于改善可固化组合物在基底上流动的方法。
• Acid Catalyzed Stereocontrolled Ferrier-Type Glycosylation Assisted by Perfluorinated Solvent
  作者：Zhiqiang Lu、Yanzhi Li、Shaohua Xiang、Mengke Zuo、Yangxing Sun、Xingxing Jiang、Rongkai Jiao、Yinghong Wang、Yuqin Fu

  DOI：10.3390/molecules27217234

  日期：——

  stereoselective formation of O-/S-glycosidic linkages that occurs via a Ferrier rearrangement of acetylated glycals. In this system, the weak interactions between perfluoro-n-hexane and substrates could augment the reactivity and stereocontrol. The initiation of transformation requires only an extremely low loading of resin-H+ and the mild conditions enable the accommodation of a broad spectrum of glycal donors

  本文描述的是全氟化溶剂在通过乙酰化糖醛的费里尔重排发生的O-/S-糖苷键的立体选择性形成中的首次应用。在该系统中，全氟正己烷和底物之间的弱相互作用可以增强反应性和立体控制。转化的启动仅需要极低的树脂-H +负载，并且温和的条件能够容纳广谱的糖供体和受体。这种化学物质的“绿色”特征体现在培养基的低毒性和易于回收以及产品分离操作的简单性。
• Process for rigid foams
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0605105A1

  公开（公告）日：1994-07-06

  Process for the preparation of rigid polyurethane foam by reaction of a polyfunctional isocyanate-reactive composition with a polyisocyanate composition comprising the reaction product of a stoichiometric excess of an organic polyisocyanate and a substantially fluorinated isocyanate-reactive compound, optionally in the presence of an inert, insoluble fluorinated compound.

  通过多官能团异氰酸酯反应组合物与多异氰酸酯组合物反应制备硬质聚氨酯泡沫塑料的工艺，多异氰酸酯组合物包括有机多异氰酸酯与基本上含氟的异氰酸酯反应化合物按一定比例过量的反应产物，可选择在有惰性不溶性含氟化合物存在的情况下进行反应。