3-(2,5-dioxahexyl)-3-methyloxetane | 141100-05-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环丁烷
• 英文名称: 3-(2,5-dioxahexyl)-3-methyloxetane
• 英文别名: 3-(2,5-dioxahexyl)-3-methyoxetane；3-(2-Methoxyethoxymethyl)-3-methyloxetane
• CAS: 141100-05-2
• 化学式: C₈H₁₆O₃
• 分子量: 160.213
• InChiKey: HCEAFVUWVHNOAO-UHFFFAOYSA-N

物化性质

• 沸点：
  192.5±10.0 °C(Predicted)
• 密度：
  0.978±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-(2,5-dioxahexyl)-3-methyloxetane 在 硫酸 作用下， 反应 20.0h， 以52%的产率得到2-(2,5-dioxahexyl)-2-methyl-1,3-propanediol
  参考文献：
  名称：

  Dale, Johannes; Fredriksen, Siw B., Acta Chemica Scandinavica, 1992, vol. 46, # 3, p. 271 - 277

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1,1-三(羟甲基)乙烷 在 吡啶 、 sodium hydride 作用下， 以 氯仿 为溶剂， 反应 24.0h， 生成 3-(2,5-dioxahexyl)-3-methyloxetane
  参考文献：
  名称：

  Dale, Johannes; Fredriksen, Siw B., Acta Chemica Scandinavica, 1992, vol. 46, # 3, p. 278 - 282

  摘要：

  DOI：

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。
• COMPOUND, ORGANIC ELECTROLUMINESCENCE ELEMENT MATERIAL, INK COMPOSITION, ORGANIC ELECTROLUMINESCENCE ELEMENT, ELECTRONIC DEVICE, AND METHOD FOR PRODUCING COMPOUND
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160197288A1

  公开（公告）日：2016-07-07

  A compound represented by formula (1): wherein *a, *b, R 1 , X 1 , L 1 , L 2 , n, A 1 , and A 2 are as defined in the description, and a production method of the compound represented by formula (1) are provide. In the production method, A 1 is introduced under a reaction condition in which the reactivity of Hal 2 in a compound represented by formula (I): wherein *c, *d, R 1 , X 1 , L 1 , L 2 , n, A 1 , A 2 , Hal 1 , and Hal 2 are as defined in the description, is extremely low as compared with that of Hal 1 and then A 2 which is different from A 1 is introduced under a reaction condition in which the reactivity of Hal 2 is high. The compound represented by formula (1) is formed into a layer by a coating method and meets various performance requirements of an organic EL device.

  公式（1）所表示的化合物：其中*a，*b，R1，X1，L1，L2，n，A1和A2的定义如说明书中所定义，并且提供了化合物（1）的生产方法。在生产方法中，A1在反应条件下引入，其中在化合物（I）所表示的卤素2的反应性在Hal1相比下极低，其中* c，* d，R1，X1，L1，L2，n，A1，A2，Hal1和Hal2的定义如说明书中所定义，然后在Hal2的反应性高的反应条件下引入不同于A1的A2。化合物（1）通过涂覆方法形成一层，并满足有机EL器件的各种性能要求。
• COMPOSITION FOR USE IN ORGANIC DEVICE, POLYMER FILM, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3173456A1

  公开（公告）日：2017-05-31

  The present invention relates to a composition for use in an organic device, comprising at least two cross-linking compounds, wherein each of the at least two cross-linking compounds is a polymer that has a hole-transporting site and constitutional repeating units, the at least two polymers having different average numbers of cross-linking groups per constitutional repeating unit and/or different numbers of cross-linking groups in portions other than the constitutional repeating units, and wherein the cross-linking compounds are compounds having a partial structure of the following formula [109]: The present invention further pertains to an organic electroluminescent element that comprises an anode and a cathode on a substrate and at least one organic layer disposed between the anode and the cathode, wherein at least one organic layer is a layer that is produced by forming a film of the composition for use in an organic device above.

  本发明涉及一种用于有机器件的组合物，该组合物包含至少两种交联化合物，其中 至少两种交联化合物中的每一种都是具有空穴传输位点和构型重复单元的聚合物，至少两种聚合物在每个构型重复单元中具有不同的平均交联基团数和/或在构型重复单元以外的部分中具有不同的交联基团数，以及 其中交联化合物是具有下式[109]部分结构的化合物： 本发明还涉及一种有机电致发光元件，该元件包括基底上的阳极和阴极以及设置在阳极和阴极之间的至少一个有机层，其中至少一个有机层是通过形成用于上述有机器件的组合物薄膜而产生的层。
• Compound, organic electroluminescence element material, ink composition, organic electroluminescence element, electronic device, and method for producing compound
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10032991B2

  公开（公告）日：2018-07-24

  A compound represented by formula (1): wherein *a, *b, R1, X1, L1, L2, n, A1, and A2 are as defined in the description, and a production method of the compound represented by formula (1) are provide. In the production method, A1 is introduced under a reaction condition in which the reactivity of Hal2 in a compound represented by formula (I): wherein *c, *d, R1, X1, L1, L2, n, A1, A2, Hal1, and Hal2 are as defined in the description, is extremely low as compared with that of Hal1 and then A2 which is different from A1 is introduced under a reaction condition in which the reactivity of Hal2 is high. The compound represented by formula (1) is formed into a layer by a coating method and meets various performance requirements of an organic EL device.

  式 (1) 所代表的化合物： 其中 *a、*b、R1、X1、L1、L2、n、A1 和 A2 如说明中所定义，并提供了式 (1) 所代表化合物的生产方法。在该生产方法中，A1 是在 Hal2 在式 (I) 所代表化合物中的反应活性的反应条件下引入的： 其中 *c、*d、R1、X1、L1、L2、n、A1、A2、Hal1 和 Hal2 如说明中所定义、 与 Hal1 的反应活性相比，Hal2 的反应活性极低，然后在 Hal2 反应活性较高的反应条件下引入与 A1 不同的 A2。式（1）表示的化合物通过涂层方法形成一层，可满足有机电致发光器件的各种性能要求。