2-(2-allyloxy-1-methylethyl)-2-oxazoline | 112832-68-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑啉类
• 英文名称: 2-(2-allyloxy-1-methylethyl)-2-oxazoline
• 英文别名: 2-{1-[(Prop-2-en-1-yl)oxy]propan-2-yl}-4,5-dihydro-1,3-oxazole；2-(1-prop-2-enoxypropan-2-yl)-4,5-dihydro-1,3-oxazole
• CAS: 112832-68-5
• 化学式: C₉H₁₅NO₂
• 分子量: 169.224
• InChiKey: VOWRVFFCFOMROX-UHFFFAOYSA-N

物化性质

• 沸点：
  229.3±23.0 °C(Predicted)
• 密度：
  1.02±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  30.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-[1-(羟甲基)乙基]唑啉 、 3-氯丙烯 在 sodium hydroxide 作用下， 以 四氢呋喃 、 正庚烷 为溶剂， 以99%的产率得到2-(2-allyloxy-1-methylethyl)-2-oxazoline
  参考文献：
  名称：

  Vinyloxazoline monomer and preparation thereof

  摘要：

  本发明涉及一种新的有机化合物，包括2-(2-烯丙氧基-1-甲基乙基)-2-噁唑啉和2-(乙烯基苄氧基-1-甲基乙基)-2-噁唑啉。其制备方法包括在相转移过程中，将2-(3-羟基-2-丙基)-2-噁唑啉分别与烯丙基氯和乙烯基苄氯缩合。该发明还涉及一种与这些化合物共聚合2-乙氧噁唑啉的方法。

  公开号：

  US04709039A1

文献信息

• CHOU, RICHARD T.
  作者：CHOU, RICHARD T.

  DOI：——

  日期：——
• US4709039A
  申请人：——

  公开号：US4709039A

  公开（公告）日：1987-11-24
• [EN] CURABLE PHOTOCHROMIC COMPOSITIONS INCLUDING AN OXAZOLINE FUNCTIONAL MATERIAL<br/>[FR] COMPOSITIONS PHOTOCHROMIQUES DURCISSABLES COMPRENANT UN MATÉRIAU FONCTIONNEL À BASE D'OXAZOLINE
  申请人：TRANSITIONS OPTICAL LTD

  公开号：WO2021129940A1

  公开（公告）日：2021-07-01

  The present invention relates to curable photochromic compositions which include an at least di-functional oxazoline functional material, an at least di-functional first carboxylic acid functional material, an optional second carboxylic acid functional material having at least three carboxylic acid groups, which optionally includes a carboxylic acid functional polymer, and a photochromic compound. The curable photochromic compositions have an equivalents ratio of oxazoline equivalents of the oxazoline functional material to a total carboxylic acid equivalents of the first and optional second carboxylic acid functional materials of from 0.5:1 to 10:1 when the second carboxylic acid functional material is not present, and from 0.5:1 to 3:1 when the second carboxylic acid functional material is present. The present invention, more particularly, relates to curable photochromic adhesive compositions, and curable photochromic coating compositions.
• Vinyloxazoline monomer and preparation thereof
  申请人：The Dow Chemical Company

  公开号：US04709039A1

  公开（公告）日：1987-11-24

  This invention relates to new organic compounds, including 2-(2-allyloxy-1-methylethyl)-2-oxazoline and 2-(vinylbenzyloxy-1-methylethyl)-2-oxazoline. Its method of preparation comprises condensing 2-(3-hydroxy-2-propyl)-2-oxazoline with allyl chloride and vinylbenzyl chloride, respectively, in a phase transfer process. The invention is also directed to a method of copolymerizing 2-ethyloxazoline with such compounds.

  本发明涉及一种新的有机化合物，包括2-(2-烯丙氧基-1-甲基乙基)-2-噁唑啉和2-(乙烯基苄氧基-1-甲基乙基)-2-噁唑啉。其制备方法包括在相转移过程中，将2-(3-羟基-2-丙基)-2-噁唑啉分别与烯丙基氯和乙烯基苄氯缩合。该发明还涉及一种与这些化合物共聚合2-乙氧噁唑啉的方法。