1-naphthyltin trichloride | 108343-70-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-naphthyltin trichloride
• 英文别名: 1-naphthyltinCl3；Naphthalen-1-yltin(3+);trichloride
• CAS: 108343-70-0
• 化学式: C₁₀H₇Cl₃Sn
• 分子量: 352.235
• InChiKey: HQHPCOQLJMHORX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-naphthyltin trichloride 在 苯基溴化镁 作用下， 以73.9%的产率得到[1]萘基-三苯基锡烷
  参考文献：
  名称：

  Pikina, J. I.; Talalaeva, T. V.; Kocheshkov, K. A., Zhurnal Obshchei Khimii, 1938, vol. 8, p. 1844 - 1849

  摘要：

  DOI：
• 作为产物：
  描述：

  Sn(1-naphthyl)4 、 四氯化锡 反应 2.0h， 以51%的产率得到1-naphthyltin trichloride
  参考文献：
  名称：

  Aryltin chlorides and hydrides: Preparation, detailed NMR studies and DFT calculations

  摘要：

  A series of novel tin chlorides RnSnCl4-n and respective hydrides RnSnH4-n were synthesized displaying a range of substituted phenyl residues, as well as naphthyl moieties (R = Ph, o-tolyl, 2,4-xylyl, 2,6-xylyl, p-biphenyl, 1-naphthyl, 2-naphthyl). These compounds were characterized using H-1, C-13 and Sn-119 NMR spectroscopy. In addition, X-ray diffraction was employed to elucidate the molecular structure of all solid aryltin chlorides (8-10, 14, 15). In each case, the tin is in a distorted tetrahedral environment. All naphthyl containing derivatives exhibit displaced pi-pi stacking. DFT calculations were carried out to compare experimental NMR data with calculated C-13 and Sn-119 shifts, as well as C-13-Sn-119 coupling constants. (C) 2013 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.03.012

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.15.8, page 418 - 422
  作者：

  DOI：——

  日期：——
• Berwe, Hermann; Haas, Alois, Chemische Berichte, 1987, vol. 120, p. 1175 - 1182
  作者：Berwe, Hermann、Haas, Alois

  DOI：——

  日期：——
• Haas, Alois, Pure and Applied Chemistry, 1991, vol. 63, p. 1577 - 1590
  作者：Haas, Alois

  DOI：——

  日期：——
• BERWE H.; HAAS A., CHEM. BER., 120,(1987) N 7, 1175-1182
  作者：BERWE H.、 HAAS A.

  DOI：——

  日期：——
• Pikina, J. I.; Talalaeva, T. V.; Kocheshkov, K. A., Zhurnal Obshchei Khimii, 1938, vol. 8, p. 1844 - 1849
  作者：Pikina, J. I.、Talalaeva, T. V.、Kocheshkov, K. A.

  DOI：——

  日期：——