| 54635-28-8

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• CAS: 54635-28-8
• 化学式: HKrO
• 分子量: 100.807
• InChiKey: BLFGRAPYWDMQLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.56
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  乙醛肟 、 氪气 以 neat (no solvent, gas phase) 为溶剂， 生成
  参考文献：
  名称：

  Detection and spectroscopic studies of gas-phase hydroxyl-krypton by laser-induced fluorescence

  摘要：

  The van der Waals complex OH-Kr has been detected in a free jet expansion by laser-induced fluorescence (LIF) near the (1,0) band of the A2-SIGMA+ <-- X2-PI(i) transition of uncomplexed OH. The excitation spectrum reveals a progression of vibrational bands which have been assigned to the stretching motion of the complex. A Birge-Sponer plot of this progression yields a fundamental frequency of omega(e)' = 196 +/- 8 cm-1 and an anharmonicity constant of omega(e)'chi(c)' = 7.4 +/- 0.7 cm-1 for the A2-SIGMA+ excited state. The lower limit of the binding energy of thc complex is measured as D0'(nu'=1) greater-than-or-equal-to 1131 cm-1. These results are compared to those obtained from recent gas-phase LIF studies on the OH-Ne and OH-Ar complexes near the A2-SIGMA+ <-- X2-PI(i) (0,0) and (1,0) bands of OH, respectively, and those from a matrix LIF study on the OH-Kr complex near the (2,0) band of OH,

  DOI：

  10.1021/j100191a019