(ethyloxy)oxo(5,10,15,20-tetraphenylporphinato)molybdenum(V) | 65404-71-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (ethyloxy)oxo(5,10,15,20-tetraphenylporphinato)molybdenum(V)
• 英文别名: (ethoxy)(oxo)(5,10,15,20-tetraphenylporphinato)molybdenum(V)；O=Mo(OEt)TPP；Mo(V)O(tpp)OC2H5；ethoxy-oxo-molybdenum(V) 5,10,15,20-tetraphenylporphyrin；molybdenum tetraphenylporphyrin ethoxide；Mo(V)O(TPP)OEt
• CAS: 65404-71-9
• 化学式: C₄₆H₃₃MoN₄O₂
• 分子量: 769.734
• InChiKey: RVBGGKOANRWROZ-NBICUONBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (ethyloxy)oxo(5,10,15,20-tetraphenylporphinato)molybdenum(V) 以 solid 为溶剂， 生成 (5,10,15,20-meso-tetraphenylporphyrinato)oxomolybdenum(IV)
  参考文献：
  名称：

  Facile Preparation of Manganese(II) Tetraphenylporphyrin by the Pyrolysis of Dimethoxoraanganese(IV) Tetraphenylporphyrin

  摘要：

  在 10-4-10-5 托（1 托≅133.3 帕）条件下，MnIV(tpp)(OCH3)2 在 ≈180 ℃ 热解得到四苯基卟啉锰(II)MnII (tpp)（tpp = 间四苯基卟啉）。在固态下热解 MoVO(tpp)OR（R = CH3，C2H5）得到 MoIVO(tpp)。

  DOI：

  10.1246/cl.1988.257
• 作为产物：
  描述：

  Chloro-oxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V) 在 乙醇 作用下， 以 乙醇 为溶剂， 生成 (ethyloxy)oxo(5,10,15,20-tetraphenylporphinato)molybdenum(V)
  参考文献：
  名称：

  钼（V）四苯基卟啉配合物

  摘要：

  摘要在某些常见溶剂中，制备了四氯化钼（V）四苯基卟啉配合物OMoTPP（Cl）（I），四氧化钼（V）四苯基卟啉氢氧化物（OMoTPP（OH））溶液的制备条件（II），它们各自的盐酸盐，OMoTPP（Cl）·HCl（III）和OMoTPP（OH）（IV），乙醇盐络合物，OMoTPP（OEt）（V）和μ-氧代二聚体，已确定为OMoTPP）2O（VI）。与以前的结果相反，观察到可再现的可见光谱，金属卟啉的特征。两组esr光谱，分别对应于卟啉环系统的4个氮原子的核矩与26Mo同位素的d'-电子的相互作用以及95Mo和96Mo同位素与5 /的d'-电子的相互作用钼的相同同位素的2个核矩，记录了这些解决方案。发现可见光谱结果和esr吸收是相互一致的。

  DOI：

  10.1016/s0020-1693(00)95517-8

文献信息

• Absorption Spectra of New Oxomolybdenum(V) Complexes of Tetraphenylporphyrin with Univalent Ligands
  作者：Taira Imamura、Takayuki Numatatsu、Masashi Terui、Masatoshi Fujimoto

  DOI：10.1246/bcsj.54.170

  日期：1981.1

  New tetraphenylporphyrin complexes, MoO(tpp)X (X=F, Br, BF4, NCO, N3, and NCS), are easily prepared from the complex, MoO(tpp)OC2H5, where TPP denotes meso-tetraphenylporphyrin. The complexes are confirmed to contain a central oxomolybdenum(V) group based on the IR and the ESR measurements. The visible absorption spectra of the complexes in dichloromethane have three main peaks, the Soret band, the

  新的四苯基卟啉复合物 MoO(TPP)X（X=F、Br、BF4、NCO、N3 和 NCS）很容易从复合物 MoO(TPP)OC2H5 中制备，其中 TPP 表示内消旋四苯基卟啉。根据 IR 和 ESR 测量，确认复合物含有中心氧代钼 (V) 基团。该配合物在二氯甲烷中的可​​见吸收光谱具有三个主峰，索雷带、α和β带。发现相应吸收最大值的红移程度按以下顺序增加：X=OC2H5
• Mechanism of the Reactions of Oxomolybdenum(V) Tetraphenylporphyrin Complex with Alcohols in the Presence of Superoxide
  作者：Taira Imamura、Koichi Hasegawa、Tetsuya Tanaka、Wataru Nakajima、Masatoshi Fujimoto

  DOI：10.1246/bcsj.57.194

  日期：1984.1

  orphinato) causes two-step reactions at 25 °C. The products of the first and the second step of the reactions are alcohol complex, [MovO(tpp)(ROH)]Br, and alkoxo complex, MovO(tpp)OR, respectively. In the presence of superoxide ion, O2−, in the dichloromethane solution of MovO(tpp)X (X=Br and NCS) containing alcohol, MovO(tpp)OR is formed through competitive two reaction paths where O2− acts as a proton

  将 ROH（R=CH3 和 C2H5）连续添加到 MovO(tpp)Br (tpp=meso-tetraphenylporphinato) 的二氯甲烷溶液中会在 25 °C 下引起两步反应。反应的第一步和第二步的产物分别是醇络合物 [MovO(tpp)(ROH)]Br 和烷氧基络合物 MovO(tpp)OR。在超氧离子 O2− 的存在下，在含有醇的 MovO(tpp)X (X=Br 和 NCS) 的二氯甲烷溶液中，MovO(tpp)OR 通过竞争性的两条反应路径形成，其中 O2− 作为质子受体和还原剂。通过光学和 ESR 研究证实了两条路径的反应步骤。
• Physicochemical insight into the metal atom effect on magnetocaloric behavior of paramagnetic metalloporphyrins
  作者：T.N. Lomova、V.V. Korolev、A.G. Ramazanova、E.N. Ovchenkova、N.G. Bichan、E.V. Motorina、A.A. Tsaturyan

  DOI：10.1016/j.poly.2023.116384

  日期：2023.5

  and inorganic σπ-ligands on the magnetocaloric properties of metal ions at room temperature, we have synthesized paramagnetic (5,10,15,20-tetraphenylporphinato)cobalt(II), (chloro)(2,3,7,8,12,13,17,18-octaethylporphinato))manganese(III), their coordination complexes with 1-methyl-2-(pyridin-4'-yl)-3,4-fullero[60]pyrrolidine (1:3 and 1:2, respectively), and (ethoxy)(oxo)(5,10,15,20-tetraphenylporphinato)molybdenum(V)

  为了揭示配位有机和无机 σπ-配体对室温下金属离子磁热特性的影响，我们合成了顺磁性（5,10,15,20-四苯基卟啉基）钴（II），（氯）（2,3） ,7,8,12,13,17,18-octaethylporphinato))MAnganese(III), 它们与 1-methyl-2-(pyridin-4'-yl)-3,4-fullero[60]pyrrolidine ( 1:3 和 1:2，分别）和（乙氧基）（氧代）（5,10,15,20-四苯基卟啉基）钼（V），并通过 UV-vis、IR、1H NMR、MALDI TOF 光谱方法。利用直接微量热法和 DSC，我们分别获得了在 0 到 1 T 的磁场中，在 285 – 338 K 的温度范围内磁化过程中的磁热效应、热量、焓/熵变化和比热容合成顺磁体的零场温度范围为 270 至 400 К。涉及DFT计算的结果，我们已经表明中心金属原子
• Photochemically-induced ligand exchange reactions of ethoxy-oxo-molybdenum(V) tetraphenylporphyrin in chlorinated solvents
  作者：Antonios M. Douvas、Panagiotis Argitis、Andrea Maldotti、Athanassios G. Coutsolelos

  DOI：10.1016/j.poly.2006.06.027

  日期：2006.12

  Photochemically-induced ligand exchange reactions of ethoxy-oxo-molybdenum(V) 5,10,15,20-tetraphenylporphyrin, Mo(V)O(TPP)-OEt, under irradiation at the Soret band region, were investigated. The reactions were performed in chlorinated solvents and followed with ultraviolet-visible (UV-vis) spectroscopy, whereas the products were analyzed with Fourier transformed infrared (FTIR) spectroscopy, electron spin resonance (ESR) spectroscopy and gas chromatography (GC). The chloro-oxo(TPP)Mo(V) complex was obtained as the final product, where the chlorine came from the solvent. Nevertheless, these reactions were not photocatalytic, due to the photochemical inertness of the formed chloro-oxo complex, and an excess of ethanol could not initiate a new photocatalytic cycle unless water was added as well, resulting in the formation of a biphasic system. On the other hand, addition of ethanol, water and NaOH to the reaction medium led to the formation of the corresponding oxo Mo(IV) complex. The studied photoassisted reactions of oxo Mo(V) porphyrins appear attractive for possible applications in the detection of chlorinated pollutants in sensing devices, but also for the dechlorination of pollutants upon suitable optimization of processing conditions. (c) 2006 Elsevier Ltd. All rights reserved.
• Imamura, Taira; Terui, Masashi; Takahashi, Yasuo, Chemistry Letters, 1980, p. 89 - 92
  作者：Imamura, Taira、Terui, Masashi、Takahashi, Yasuo、Numatatsu, Takayuki、Fujimoto, Masatoshi

  DOI：——

  日期：——