ethyl 2-naphthylimidate hydrochloride | 4278-14-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: ethyl 2-naphthylimidate hydrochloride
• 英文别名: naphthylimidate；ethyl 2-naphthimidate hydrochloride；ethyl naphthalene-2-carboximidate hydrochloride；[2]naphthimidic acid ethyl ester; hydrochloride；ethyl 2-naphthalenecarboximidate hydrochloride；[2]Naphthimidsaeure-aethylester; Hydrochlorid；Ethyl 2-naphthalenecarboximidate hydrochloride；ethyl naphthalene-2-carboximidate;hydrochloride
• CAS: 4278-14-2
• 化学式: C₁₃H₁₃NO*ClH
• 分子量: 235.713
• InChiKey: UGMSGIJIZFVHPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.62
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  33.1
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2925290090

反应信息

• 作为反应物：
  描述：

  ethyl 2-naphthylimidate hydrochloride 在 氨 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 24.0h， 以86%的产率得到2-naphthimidamide hydrochloride
  参考文献：
  名称：

  Facile synthesis of 3,5-diaryl-1,2,4-triazoles via copper-catalyzed domino nucleophilic substitution/oxidative cyclization using amidines or imidates as substrates

  摘要：

  Two methods for the synthesis of 3,5-diaryl-1,2,4-triazoles, both domino reactions, are reported. The first procedure, the Cu(OTf)(2)-catalyzed reaction between two amidines using NaHCO3 as a base, 1,10-phenanthroline as an additive and K-3[Fe(CN)(6)]/atmospheric oxygen as the oxidant, delivers 3,5-diaryl-1,2,4-triazoles with yields up to 68%. The second procedure for the synthesis of 3,5-diaryl-1,2,4-triazoles with yields up to 64% rests on the Cu(OTf)(2)-catalyzed reaction between two imidates and ammonium carbonate. This method features the formation of three bonds in a single synthetic step. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.01.019
• 作为产物：
  描述：

  2-萘甲腈 、 乙醇 在 盐酸 作用下， 反应 11.0h， 生成 ethyl 2-naphthylimidate hydrochloride
  参考文献：
  名称：

  [EN] BENZIMIDAZOLE OR INDOLE AMIDES AS INHIBITORS OF PIN1
  [FR] AMIDES DE BENZIMIDAZOLE OU D'INDOLE EN TANT QU'INHIBITEURS DE PIN1

  摘要：

  这项发明涉及公式（1）的化合物，以及其药学上可接受的盐和溶剂化合物，其中变量在此处定义。该发明还涉及通过给予公式（1）的化合物来治疗哺乳动物中的异常细胞生长的方法，以及用于治疗包含公式（1）化合物的这类疾病的药物组合物。该发明还涉及制备公式（1）化合物的方法。

  公开号：

  WO2006040646A1

文献信息

• Organometallic Complex, Organic Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Inoue Hideko

  公开号：US20120305896A1

  公开（公告）日：2012-12-06

  A novel and highly reliable organometallic complex which has an emission region in the wavelength band of blue to yellow is provided. A light-emitting element using the organometallic complex, a light-emitting device, an electronic device, and a lighting device each using the light-emitting element are provided. An organometallic complex including a structure represented by General Formula (G1) is provided. The organometallic complex including the structure represented by General Formula (G1) is a novel and highly reliable organometallic complex which has an emission region in the wavelength band of blue to yellow. In addition, a light-emitting element using the organometallic complex, a light-emitting device, an electronic device, and a lighting device each including the light-emitting element are provided.

  提供了一种新颖且高度可靠的有机金属配合物，其发射区域在蓝色到黄色波长范围内。提供了一种使用该有机金属配合物的发光元件，以及使用该发光元件的发光装置、电子装置和照明装置。提供了一种包括通式（G1）表示的结构的有机金属配合物。包括通式（G1）表示的结构的有机金属配合物是一种新颖且高度可靠的有机金属配合物，其发射区域在蓝色到黄色波长范围内。此外，还提供了一种使用该有机金属配合物的发光元件，以及包括该发光元件的发光装置、电子装置和照明装置。
• Stereochemistry of the Ph3P-CCl4 mediated cyclization of carboxylic acids and 1,2-amino alcohols (Vorbruggen Method)
  作者：A.I. Meyers、Denton Hoyer

  DOI：10.1016/s0040-4039(00)94924-4

  日期：1985.1

  In contrast to a previous report,β-hydroxy amides formed the Ph3P-CCl4 condensation of acids and amino alcohols, cyclize to oxazolines with complete inversion of the carbinol center.

  与以前的报告相反，β-羟基酰胺形成酸和氨基醇的Ph 3 P-CCl 4缩合，环化成恶唑啉，甲醇中心完全反转。
• 발광 소자, 발광 장치, 전자 기기, 및 조명 장치
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD. 가부시키가이샤 한도오따이 에네루기 켄큐쇼(519980839048)

  公开号：KR102215398B1

  公开（公告）日：2021-02-10

  본 발명은 인광을 발광할 수 있는 유기 화합물을 발광층에 포함하는 발광 소자를 제공한다. 또한, 낮은 구동 전압, 높은 전류 효율, 또는 장수명을 구현할 수 있는 발광 소자를 제공한다. 한 쌍의 전극 사이에 끼워진 발광층을 포함하는 발광 소자에서, 발광층은 유기 화합물을 포함하고 유기 화합물이 1,2,4-트라이아졸 골격과, 페닐 골격과, 아릴렌 골격과, 제 9족 또는 제 10족의 금속을 갖고, 1,2,4-트라이아졸 골격의 4위치의 질소가 제 9족 또는 제 10족의 금속에 배위하며, 1,2,4-트라이아졸 골격의 1위치의 질소가 페닐 골격에 결합하고, 아릴렌 골격이 1,2,4-트라이아졸 골격의 3위치에 결합하며, 제 9족 또는 제 10족의 금속에 결합한다.

  本发明提供了包含有机化合物的发光层的发光器件，该有机化合物能够发出光。此外，本发明还提供了能够实现低驱动电压、高电流效率或长寿命的发光器件。在包含夹在一对电极之间的发光层的发光器件中，发光层包含有机化合物，该有机化合物包括1,2,4-三唑骨架、苯骨架、芳烃骨架、第9族或第10族金属，并且1,2,4-三唑骨架的第4位氮原子位于第9族或第10族金属上，1,2,4-三唑骨架的第1位氮原子与苯骨架结合，芳烃骨架连接在1,2,4-三唑骨架的第3位，然后与第9族或第10族金属结合。
• Light-Emitting Element, Light-Emitting Device, Electronic Appliance, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20140151662A1

  公开（公告）日：2014-06-05

  A light-emitting element in which a light-emitting layer contains an organic compound capable of emitting phosphorescence is provided. A light-emitting element which can have low driving voltage, high current efficiency, or a long lifetime is provided. In a light-emitting element in which a light-emitting layer is interposed between a pair of electrodes, the light-emitting layer contains an organic compound. The organic compound has a 1,2,4-triazole skeleton, a phenyl skeleton, an arylene skeleton, and a Group 9 metal or a Group 10 metal. The nitrogen atom at the 4-position of the 1,2,4-triazole skeleton coordinates to the Group 9 metal or the Group 10 metal. The nitrogen atom at the 1-position of the 1,2,4-triazole skeleton is bonded to a phenyl skeleton. The arylene skeleton is bonded to the 3-position of the 1,2,4-triazole skeleton and the Group 9 metal or the Group 10 metal.

  提供了一种发光元件，其中发光层包含一种能够发出磷光的有机化合物。提供了一种能够具有低驱动电压、高电流效率或长寿命的发光元件。在发光层被夹在一对电极之间的发光元件中，发光层包含有机化合物。该有机化合物具有1,2,4-三唑骨架、苯骨架、芳基骨架和第9族金属或第10族金属。1,2,4-三唑骨架的4位氮原子与第9族金属或第10族金属配位。1,2,4-三唑骨架的1位氮原子与苯骨架键合。芳基骨架与1,2,4-三唑骨架的3位和第9族金属或第10族金属键合。
• Organometallic complex, organic light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Inoue Hideko

  公开号：US09406894B2

  公开（公告）日：2016-08-02

  A novel and highly reliable organometallic complex which has an emission region in the wavelength band of blue to yellow is provided. A light-emitting element using the organometallic complex, a light-emitting device, an electronic device, and a lighting device each using the light-emitting element are provided. An organometallic complex including a structure represented by General Formula (G1) is provided. The organometallic complex including the structure represented by General Formula (G1) is a novel and highly reliable organometallic complex which has an emission region in the wavelength band of blue to yellow. In addition, a light-emitting element using the organometallic complex, a light-emitting device, an electronic device, and a lighting device each including the light-emitting element are provided.

  提供了一种新型且高可靠性的有机金属配合物，其发射波长在蓝色到黄色波段之间。提供了一种使用该有机金属配合物的发光元件，以及使用该发光元件的发光装置、电子设备和照明装置。提供了一种包括通式（G1）所表示的结构的有机金属配合物。该包括通式（G1）所表示的结构的有机金属配合物是一种新型且高可靠性的有机金属配合物，其发射波长在蓝色到黄色波段之间。此外，还提供了一种使用该有机金属配合物的发光元件、发光装置、电子设备和照明装置。