tetrakis(2-sulfanylethyl) silicate | 1429129-56-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: tetrakis(2-sulfanylethyl) silicate
• 英文别名: tetrakis(2-sulfanylethyloxy)silane；Tetrakis(2-sulfanylethyl) silicate
• CAS: 1429129-56-5
• 化学式: C₈H₂₀O₄S₄Si
• 分子量: 336.594
• InChiKey: PEECBHQEYHLRKP-UHFFFAOYSA-N

物化性质

• 沸点：
  353.1±42.0 °C(Predicted)
• 密度：
  1.210±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.21
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.9
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  甲基乙烯基二氯硅烷 、 tetrakis(2-sulfanylethyl) silicate 在 二苯甲酮 作用下， 以 乙醚 为溶剂， 反应 4.0h， 以100%的产率得到tetrakis[2-[2-[dichloro(methyl)silyl]ethylsulfanyl]ethyl] silicate
  参考文献：
  名称：

  Orthogonal reactivity of thiols toward chlorovinylsilanes: selective thiol-ene chemistry

  摘要：

  A variety of new chlorosilanes were synthesized by the selective thiol-ene reactions of various thiols (ethanethiol, 1,2-ethanedithiol, benzenethiol, and tetrakis(2-sulfanylethyl)silicate) with chlorovinylsilanes (chlorodimethylvinylsilane, dichloromethylvinylsilane, and trichlorovinylsilane). No silylthioester products were observed. All products were obtained in quantitatime or near quantitative yields and were characterized using multinuclear NMR (H-1, C-13, Si-29) spectroscopy. The products required no further purification. An example is presented which highlights the potential use of these compounds for future applications. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.09.113
• 作为产物：
  描述：

  2-巯基乙醇 在 四氯化硅 、 三乙胺 作用下， 以 乙醚 为溶剂， 以60%的产率得到tetrakis(2-sulfanylethyl) silicate
  参考文献：
  名称：

  巯基醇与氯硅烷的高度选择性反应产生的多功能硫醇。

  摘要：

  通过氯硅烷与巯基醇的选择性反应合成了多官能硫醇。没有观察到巯基醇通过巯基的反应。利用这种方法，制备了具有不同结构多样性的硫醇。

  DOI：

  10.1039/c3cc39152c

文献信息

• Degradable, silyl ether thiol–ene networks
  作者：Taylor Ware、Abby R. Jennings、Zahra S. Bassampour、Dustin Simon、David Y. Son、Walter Voit

  DOI：10.1039/c4ra06997h

  日期：——

  The polymerization of silyl ether containing thiols and alkenes results in tunable, degradable thermosets with potential in implantable electronics.

  含有硫醇和烯烃的硅醚聚合物可以制备出具有可调节性和可降解性的热固性材料，具有在可植入电子器件中的潜在应用价值。
• Orthogonal reactivity of thiols toward chlorovinylsilanes: selective thiol-ene chemistry
  作者：Abby R. Jennings、Zahra S. Bassampour、Anish G. Patel、David Y. Son

  DOI：10.1016/j.tetlet.2014.09.113

  日期：2014.12

  A variety of new chlorosilanes were synthesized by the selective thiol-ene reactions of various thiols (ethanethiol, 1,2-ethanedithiol, benzenethiol, and tetrakis(2-sulfanylethyl)silicate) with chlorovinylsilanes (chlorodimethylvinylsilane, dichloromethylvinylsilane, and trichlorovinylsilane). No silylthioester products were observed. All products were obtained in quantitatime or near quantitative yields and were characterized using multinuclear NMR (H-1, C-13, Si-29) spectroscopy. The products required no further purification. An example is presented which highlights the potential use of these compounds for future applications. (C) 2014 Elsevier Ltd. All rights reserved.
• Multifunctional thiols from the highly selective reaction of mercaptoalcohols with chlorosilanes
  作者：Abby R. Jennings、David Y. Son

  DOI：10.1039/c3cc39152c

  日期：——

  Multifunctional thiols were synthesized by the selective reaction of chlorosilanes with mercaptoalcohols. Reaction of the mercaptoalcohols through the thiol group was not observed. Utilizing this method, thiols of varying structural diversity were prepared.

  通过氯硅烷与巯基醇的选择性反应合成了多官能硫醇。没有观察到巯基醇通过巯基的反应。利用这种方法，制备了具有不同结构多样性的硫醇。