(3-氯丙基)三乙烯基硅烷 | 954114-17-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: (3-氯丙基)三乙烯基硅烷
• 英文名称: (3-chloropropyl)trivinylsilane
• 英文别名: trivinyl(3-chloropropyl)silane；3-chloropropyl-tris(ethenyl)silane
• CAS: 954114-17-1
• 化学式: C₉H₁₅ClSi
• 分子量: 186.757
• InChiKey: RBWZIIUHDNSCNS-UHFFFAOYSA-N

物化性质

• 沸点：
  203.6±32.0 °C(Predicted)
• 密度：
  0.891±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.24
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (3-氯丙基)三乙烯基硅烷 在 sodium iodide 作用下， 以 丙酮 为溶剂， 反应 48.0h， 生成 trivinyl(3-iodopropyl)silane
  参考文献：
  名称：

  Nanoparticle - Biocide Treatment of Biofilms

  摘要：

  本文介绍了一种稳定的金属纳米颗粒体系，其中包括涂有与儿茶酚基配体反应的亲水性聚合物的金属纳米颗粒。同时还介绍了稳定的金属纳米颗粒，可以单独使用或与杀菌剂、抗生素或其他处理系统一起使用，以破坏生物膜并促进其从表面上去除。纳米颗粒可以是金属，如铂、银、铁（II，III）氧化物（Fe3O4）和金。纳米颗粒可以被立体稳定，例如用聚合物，或者被电荷稳定，例如用柠檬酸盐，从而产生具有改性表面的纳米颗粒。这种表面修饰被认为可以增强纳米颗粒的稳定性并降低它们聚集的可能性，进而增强它们破坏和分散现有生物膜的能力。

  公开号：

  US20140093550A1
• 作为产物：
  描述：

  3-氯丙基三氯硅烷 、 乙烯基氯化镁 以 四氢呋喃 为溶剂， 反应 24.0h， 生成 (3-氯丙基)三乙烯基硅烷
  参考文献：
  名称：

  Nanoparticle - Biocide Treatment of Biofilms

  摘要：

  本文介绍了一种稳定的金属纳米颗粒体系，其中包括涂有与儿茶酚基配体反应的亲水性聚合物的金属纳米颗粒。同时还介绍了稳定的金属纳米颗粒，可以单独使用或与杀菌剂、抗生素或其他处理系统一起使用，以破坏生物膜并促进其从表面上去除。纳米颗粒可以是金属，如铂、银、铁（II，III）氧化物（Fe3O4）和金。纳米颗粒可以被立体稳定，例如用聚合物，或者被电荷稳定，例如用柠檬酸盐，从而产生具有改性表面的纳米颗粒。这种表面修饰被认为可以增强纳米颗粒的稳定性并降低它们聚集的可能性，进而增强它们破坏和分散现有生物膜的能力。

  公开号：

  US20140093550A1

文献信息

• Surface Modified Organic Inorganic Hybrid Glass, Protecting Group Induced Alcohol or Its Derivative and Producing Method Thereof
  申请人：Jun Chul-Ho

  公开号：US20090274910A1

  公开（公告）日：2009-11-05

  Disclosed are a protected alcohol or derivative thereof, a surface-modified organic-inorganic hybrid glass, and preparation methods thereof. More specifically, disclosed are a protected alcohol or derivative thereof and a surface-modified organic-inorganic hybrid glass, which are prepared by allowing a silane compound, having vinyl or a vinyl derivative, to react with an alcohol or derivative thereof or with an organic-inorganic hybrid glass, in the presence of an acid catalyst, a transition metal catalyst and an organic solvent, so as to introduce an organic group thereto even at room temperature, as well as preparation methods thereof. The disclosed invention allows a functional group to be effectively introduced into alcohol or a derivative thereof or into an organic-inorganic hybrid glass, not only high temperatures but also room temperature, and thus is highly effective in introducing compounds having a thermally sensitive functional group, for example, natural compounds or proteins. Also, the invention makes it possible to introduce various organic groups and to separate and purify organic macromolecule-bonded organosilane compounds using a silica gel column so as to effectively introduce large organic functional groups to inorganic materials. Accordingly, the invention is highly useful in the chemical industry.

  本发明涉及一种受保护的醇或其衍生物、表面改性的有机-无机杂化玻璃及其制备方法。具体而言，本发明涉及通过在酸催化剂、过渡金属催化剂和有机溶剂的存在下，让具有乙烯基或乙烯衍生物的硅烷化合物与醇或其衍生物或有机-无机杂化玻璃反应，以便在室温下引入有机基团的受保护醇或其衍生物和表面改性的有机-无机杂化玻璃，以及其制备方法。本发明允许在高温和室温下有效地将功能基团引入到醇或其衍生物或有机-无机杂化玻璃中，因此在引入具有热敏功能基团的化合物（例如天然化合物或蛋白质）时非常有效。此外，本发明还可以引入各种有机基团，并使用硅胶柱分离和纯化有机大分子键合的有机硅烷化合物，以便将大有机功能基团有效地引入到无机材料中。因此，本发明在化学工业中具有极高的实用价值。
• ORGANIC SILICONE COMPOUND
  申请人：Koike Noriyuki

  公开号：US20100160588A1

  公开（公告）日：2010-06-24

  The purpose of the present invention is to provide an organic silicon compound which has a vinyl group more reactive than those of the conventional organic silicon compounds and can be bonded with another compound. The present organic silicon compound is represented by the following formula (1), wherein R 1 is, independently of each other, a vinyl group or an alkyl group having 1 to 4 carbon atoms, R 2 is an alkylene group having 3 to 6 carbon atoms, and R 3 is, independently of each other, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and optionally substituted with one or more fluorine atoms.

  本发明的目的是提供一种有机硅化合物，其具有比传统有机硅化合物更具反应性的乙烯基，并且可以与另一种化合物结合。本有机硅化合物由以下式（1）表示，其中R1分别是乙烯基或具有1至4个碳原子的烷基基团，R2是具有3至6个碳原子的烷基基团，R3分别是氢原子或具有1至4个碳原子的烷基基团，并且可以选择地被一个或多个氟原子取代。
• Surface modified organic inorganic hybrid glass, protecting group induced alcohol or its derivative and producing method thereof
  申请人：Industry-Academic Cooperation Foundation Yonsei University

  公开号：US08197903B2

  公开（公告）日：2012-06-12

  Disclosed are a protected alcohol or derivative thereof, a surface-modified organic-inorganic hybrid glass, and preparation methods thereof. More specifically, disclosed are a protected alcohol or derivative thereof and a surface-modified organic-inorganic hybrid glass, which are prepared by allowing a silane compound, having vinyl or a vinyl derivative, to react with an alcohol or derivative thereof or with an organic-inorganic hybrid glass, in the presence of an acid catalyst, a transition metal catalyst and an organic solvent, so as to introduce an organic group thereto even at room temperature, as well as preparation methods thereof. The disclosed invention allows a functional group to be effectively introduced into alcohol or a derivative thereof or into an organic-inorganic hybrid glass, not only high temperatures but also room temperature, and thus is highly effective in introducing compounds having a thermally sensitive functional group, for example, natural compounds or proteins. Also, the invention makes it possible to introduce various organic groups and to separate and purify organic macromolecule-bonded organosilane compounds using a silica gel column so as to effectively introduce large organic functional groups to inorganic materials. Accordingly, the invention is highly useful in the chemical industry.

  本发明涉及一种保护的醇或其衍生物、表面改性的有机-无机杂化玻璃及其制备方法。具体而言，本发明涉及一种通过在酸催化剂、过渡金属催化剂和有机溶剂的存在下，让具有乙烯或乙烯衍生物的硅烷化合物与醇或其衍生物或有机-无机杂化玻璃反应，以便即使在室温下引入有机基团的保护醇或其衍生物或有机-无机杂化玻璃以及其制备方法。本发明不仅可以在高温下，而且可以在室温下有效地引入功能基团到醇或其衍生物或有机-无机杂化玻璃中，因此在引入具有热敏功能基团的化合物，例如天然化合物或蛋白质时具有高效性。此外，本发明使得引入各种有机基团成为可能，并且可以使用硅胶柱分离和纯化有机大分子键合的有机硅烷化合物，以便将大的有机功能基团有效地引入无机材料中。因此，本发明在化学工业中具有高度的实用性。
• Organic silicone compound
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US08143359B2

  公开（公告）日：2012-03-27

  The purpose of the present invention is to provide an organic silicon compound which has a vinyl group more reactive than those of the conventional organic silicon compounds and can be bonded with another compound. The present organic silicon compound is represented by the following formula (1), wherein R1 is, independently of each other, a vinyl group or an alkyl group having 1 to 4 carbon atoms, R2 is an alkylene group having 3 to 6 carbon atoms, and R3 is, independently of each other, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and optionally substituted with one or more fluorine atoms.

  本发明的目的是提供一种有机硅化合物，其具有比传统有机硅化合物更具反应性的乙烯基，并且可以与另一化合物结合。该有机硅化合物由以下公式（1）表示，其中R1独立地表示乙烯基或具有1至4个碳原子的烷基，R2表示具有3至6个碳原子的烷基，而R3独立地表示氢原子或具有1至4个碳原子并可选择地取代一个或多个氟原子的烷基。
• WO2007/120014
  申请人：——

  公开号：——

  公开（公告）日：——