[3-Methyl-4-[4-(6-prop-2-enoyloxyhexanoyloxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexanoyloxy)benzoate | 951768-70-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [3-Methyl-4-[4-(6-prop-2-enoyloxyhexanoyloxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexanoyloxy)benzoate
• CAS: 951768-70-0
• 化学式: C₃₉H₄₀O₁₂
• 分子量: 700.739
• InChiKey: ZECOCQOVGHMDLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  51
• 可旋转键数：
  26
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  158
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  甲基氢醌 在 2,6-二叔丁基-4-甲基苯酚 、 四丁基碘化铵 、 potassium hydrogencarbonate 、 对甲苯磺酸 、 三乙胺 作用下， 以 四氢呋喃 、 xylenes 为溶剂， 反应 30.0h， 生成 [3-Methyl-4-[4-(6-prop-2-enoyloxyhexanoyloxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexanoyloxy)benzoate
  参考文献：
  名称：

  Liquid crystal compositions, polymer networks derived therefrom and process for making the same

  摘要：

  该发明涉及公式（I）的化合物。该发明还涉及包含公式（I）化合物的液晶组合物；进一步包含一种或多种手性化合物的组合物；以及由液晶组合物的聚合物化得到的聚合物网络。另一种实施方式涉及提供公式（I）化合物的方法。

  公开号：

  US08344175B2

文献信息

• Liquid crystal compositions
  申请人：E.I. du Pont de Nemours and Company

  公开号：US08044228B2

  公开（公告）日：2011-10-25

  This invention relates to liquid crystal compositions, and polymer networks and articles comprising the compositions. The compositions comprise at least one compound of the group of compounds represented by the structures of each of the following Formulas (IV), (V) and (VI), as defined herein. A process for making the composition is also provided.

  这项发明涉及液晶组合物、聚合物网络和包括该组合物的制品。该组合物包括至少一种属于以下各式（IV）、（V）和（VI）所代表的化合物群的化合物，如本文所定义。还提供了一种制备该组合物的方法。
• Liquid crystal compositions and polymer networks derived therefrom
  申请人：Goldfinger B. Marc

  公开号：US20070267599A1

  公开（公告）日：2007-11-22

  The invention relates to compounds of formula (I): wherein R 1 and R 2 are each independently selected from the group: H, F, Cl and CH 3 ; n1 and n2 are each independently integers 3 to 20; q and r are each independently integers 0, 1 or 2, with the proviso that q+r is ≧1; D is a divalent chiral radical selected from the group: wherein R 3 is a C1 to C6 straight or branched chain alkyl group; and each B 1 and B 2 is a divalent radical independently selected from the group: R 4 -substituted-1,4-phenyl, wherein R 4 is H, —CH 3 or —OCH 3 ; 2,6-naphthyl; and 4,4′-biphenyl; with the provisos that when q+r=3, at least one of B 1 and B 2 is R 4 -substituted-1,4-phenyl; and when q+r=4, at least two of B 1 and B 2 are R 4 -substituted-1,4-phenyl. The invention further relates to liquid crystal compositions comprising compounds of formula (I) and polymer networks derived from the polymerization of the liquid crystal compositions.

  本发明涉及化合物的公式(I)：其中，R1和R2各自独立地选自组：H、F、Cl和CH3；n1和n2各自独立地为整数3至20；q和r各自独立地为整数0、1或2，但须满足q+r≧1；D是从组中选择的二价手性基团：其中，R3是C1至C6直链或支链烷基；每个B1和B2是从组中独立选择的二价基团：R4-取代-1,4-苯基，其中R4为H、— 或—O ；2,6-萘基；和4,4'-联苯基；但须满足当q+r=3时，至少一个B1和B2是R4-取代-1,4-苯基；当q+r=4时，至少两个B1和B2是R4-取代-1,4-苯基。本发明还涉及包含公式(I)化合物的液晶组合物和由液晶组合物聚合得到的聚合物网络。
• CHIRAL COMPOUNDS, LIQUID CRYSTAL COMPOSITIONS AND POLYMER NETWORKS DERIVED THEREFROM
  申请人：Goldfinger Marc B.

  公开号：US20110042614A1

  公开（公告）日：2011-02-24

  Isomannide-based compounds having chiral properties are provided, in addition to liquid crystal compositions and polymer networks derived therefrom.

  提供了具有手性性质的异麦芽酰胺基化合物，以及由此衍生的液晶组合物和聚合物网络。
• CHIRAL COMPOUNDS AND LIQUID CRYSTAL COMPOSITIONS AND POLYMER NETWORKS DERIVED THEREFROM
  申请人：GOLDFINGER Marc B.

  公开号：US20110163267A1

  公开（公告）日：2011-07-07

  The invention relates to compounds of formula (I): wherein R 1 and R 2 are each independently selected from the group: H, F, Cl and CH 3 ; n1 and n2 are each independently integers 3 to 20; q and r are each independently integers 0, 1 or 2, with the proviso that q+r is ≧1; D is a divalent chiral radical selected from the group: wherein R 3 is a C1 to C6 straight or branched chain alkyl group; and each B 1 and B 2 is a divalent radical independently selected from the group: R 4 -substituted-1,4-phenyl, wherein R 4 is H, —CH 3 or —OCH 3 ; 2,6-naphthyl; and 4,4′-biphenyl; with the provisos that when q+r=3, at least one of B 1 and B 2 is R 4 -substituted-1,4-phenyl; and when q+r=4, at least two of B 1 and B 2 are R 4 -substituted-1,4-phenyl. The invention further relates to liquid crystal compositions comprising compounds of formula (I) and polymer networks derived from the polymerization of the liquid crystal compositions.

  本发明涉及式（I）的化合物：其中R1和R2各自独立地选自以下组：H，F，Cl和CH3; n1和n2各自独立地为3至20的整数; q和r各自独立地为0、1或2的整数，但需满足q+r≧1; D是选自以下组的二价手性基团：其中R3是C1至C6的直链或支链烷基; 每个B1和B2是独立地选自以下组的二价基团：R4-取代-1,4-苯基，其中R4是H，— 或—O ; 2,6-萘基; 和4,4'-联苯基; 但需满足当q+r=3时，至少有一个B1和B2是R4-取代-1,4-苯基; 当q+r=4时，至少有两个B1和B2是R4-取代-1,4-苯基。本发明还涉及包含式（I）的液晶组分和由液晶组分的聚合物网络衍生的聚合物网络。
• LIQUID CRYSTAL COMPOSITIONS, POLYMER NETWORKS DERIVED THEREFROM AND PROCESS FOR MAKING THE SAME
  申请人：GOLDFINGER MARC B.

  公开号：US20110114885A1

  公开（公告）日：2011-05-19

  The invention relates to compounds of Formula (I): The invention further relates to liquid crystal compositions comprising compounds of Formula (I); compositions further comprising one or more chiral compounds; and polymer networks derived from the polymerization of the liquid crystal compositions. Another embodiment relates to processes for providing compounds of Formula (I).

  本发明涉及公式（I）的化合物。本发明还涉及包括公式（I）化合物的液晶组合物；进一步包括一个或多个手性化合物的组合物；以及由液晶组合物的聚合所得的聚合物网络。另一个实施例涉及提供公式（I）化合物的过程。