Aluminum;copper(1+);tetrachloride | 27803-79-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属盐
• 英文名称: Aluminum;copper(1+);tetrachloride
• CAS: 27803-79-8
• 化学式: AlCl₄*Cu
• 分子量: 232.34
• InChiKey: UIDNQWNGUOWPCG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  2.37
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Aluminum;copper(1+);tetrachloride 、 一氧化碳 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  CuMCl4(M = Al和Ga)在小分子结合和CO和乙烯的竞争结合上的吸附重建

  摘要：

  CuMCl(4) 的羰基加合物（M = Al 和 Ga）已通过单晶和/或粉末 X 射线衍射、红外和漫反射紫外/可见光谱进行表征。高达两当量的一氧化碳（相对于 stp 大约为 200 cm(3)/g）在室温下被吸附，平衡结合压力低于 0.5 atm 的 CO。羰基键合被证明是非经典的，暗示了sigma-bonding 和没有 pi-back-bonding。母相和加合物相的晶体结构分析提供了吸附重建反应的原子图。比较 CO 和乙烯与这些 CuMCl(4) 材料以及其他具有经典和非经典键合模式的卤化铜 (I) 化合物的反应性，

  DOI：

  10.1021/ja063172q
• 作为产物：
  描述：

  三氯化铝 、 copper(l) chloride 以 neat (no solvent) 为溶剂， 生成 Aluminum;copper(1+);tetrachloride
  参考文献：
  名称：

  An Illuminating Framework:  Understanding the Photoluminescence of α-CuAlCl₄

  摘要：

  CuAlCl4 exemplifies a new class of phosphors based on metal halide analogues of aluminophosphates. The alpha- and beta-CuAlCl4 phases show brilliant blue to blue-green luminescence. The electronic structure of the CuAlCl4 corner sharing tetrahedral frameworks has been explored by fluorimetric and diffuse reflectance measurements on the isomorphous series alpha-CuAlBrxCl4-x (x = 0-4). The photoluminescence is demonstrated to be a bulk property of the electronically isolated CuCl4/2 tetrahedra within the framework matrix. Remarkably, the structural framework is flexible such that at least 1 mol of small molecule gases per CuAlCl4 formula unit can be reversibly sorbed. The sorption/desorption of small molecule gases further results in the reversible quenching of the photoluminescence.

  DOI：

  10.1021/ja9925204
• 作为试剂：
  描述：

  2-丁烯 、 异丁烷 在 1-(n-butyl)-3-methylimidazolium tetrachloroaluminate 、 Aluminum;copper(1+);tetrachloride 作用下， 9.84 ℃ 、400.01 kPa 条件下， 反应 0.5h， 生成 异辛烷
  参考文献：
  名称：

  Effects of catalyst composition on the ionic liquid catalyzed isobutane/2-butene alkylation

  摘要：

  Ionic liquid catalyzed isobutane/2-butene alkylation modified with metal compounds was studied. The effect of catalyst composition on the alkylation selectivity was investigated. Al-27 NMR, ESI-MS, and FTIR spectra reveal that the catalytic selectivity of the modified ionic liquid is probably determined by the catalyst composition rather than by the acid strength. The complexation of transition metal with 2-butene can increase the internal isobutane-to-olefin ratio of feed during the alkylation reaction, which results in the better selectivity of the modified ionic liquid. The best ionic liquid catalysts were those containing CuAlCl4 complexes, giving the alkylate with 87.5 wt% trimethylpentanes and a calculated research octane number (RON) of 100.5. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2014.11.020

文献信息

• POLYMERIZATION OF BENZENE WITH Cu(AlCl₄)₂
  作者：Nobumasa Kitajima、Yoshiaki Hakone、Yoshio Ono

  DOI：10.1246/cl.1982.871

  日期：1982.6.5

  Cu(AlCl4)2 reacts with benzene to give poly(1,4-phenylene). When 2.5 mmol of benzene was reacted with 2.5 mmol of Cu(AlCl4)2 at 20°C for 2 h, poly(1,4-phenylene) was obtained in 92 % yield, which is higher than that obtained with the conventional system, AlCl3–CuCl2 mixture, under the same conditions.

  Cu(AlCl4)2 与苯反应生成聚(1,4-亚苯基)。当 2.5 毫摩尔苯与 2.5 毫摩尔 Cu(AlCl4)2在 20°C 下反应 2 小时后，得到的聚(1,4-亚苯基)产率为 92%，高于在相同条件下用传统体系 AlCl3-CuCl2 混合物得到的产率。
• HIRAI, HIDEFUMI, FRONT. MACROMOL. SCI., OXFORD ETC.,(1989) C. 239-244
  作者：HIRAI, HIDEFUMI

  DOI：——

  日期：——
• WALKER, D. G.
  作者：WALKER, D. G.

  DOI：——

  日期：——
• Effects of catalyst composition on the ionic liquid catalyzed isobutane/2-butene alkylation
  作者：Ying Liu、Rui Li、Hongjuan Sun、Ruisheng Hu

  DOI：10.1016/j.molcata.2014.11.020

  日期：2015.3

  Ionic liquid catalyzed isobutane/2-butene alkylation modified with metal compounds was studied. The effect of catalyst composition on the alkylation selectivity was investigated. Al-27 NMR, ESI-MS, and FTIR spectra reveal that the catalytic selectivity of the modified ionic liquid is probably determined by the catalyst composition rather than by the acid strength. The complexation of transition metal with 2-butene can increase the internal isobutane-to-olefin ratio of feed during the alkylation reaction, which results in the better selectivity of the modified ionic liquid. The best ionic liquid catalysts were those containing CuAlCl4 complexes, giving the alkylate with 87.5 wt% trimethylpentanes and a calculated research octane number (RON) of 100.5. (C) 2014 Elsevier B.V. All rights reserved.
• An Illuminating Framework:  Understanding the Photoluminescence of α-CuAlCl₄
  作者：Roger M. Sullivan、James D. Martin

  DOI：10.1021/ja9925204

  日期：1999.11.1

  CuAlCl4 exemplifies a new class of phosphors based on metal halide analogues of aluminophosphates. The alpha- and beta-CuAlCl4 phases show brilliant blue to blue-green luminescence. The electronic structure of the CuAlCl4 corner sharing tetrahedral frameworks has been explored by fluorimetric and diffuse reflectance measurements on the isomorphous series alpha-CuAlBrxCl4-x (x = 0-4). The photoluminescence is demonstrated to be a bulk property of the electronically isolated CuCl4/2 tetrahedra within the framework matrix. Remarkably, the structural framework is flexible such that at least 1 mol of small molecule gases per CuAlCl4 formula unit can be reversibly sorbed. The sorption/desorption of small molecule gases further results in the reversible quenching of the photoluminescence.