Ionothermal Synthesis of Sulfidobismuth
<i>spiro</i>
‐Dicubane Cations
作者:Maximilian Knies、Michael Ruck
DOI:10.1002/open.202100145
日期:2022.2
In an ionothermal synthesis bismuth sulfide reacted to spiro-dicubane cations (Bi7S8)5+, which crystallized in a complex structured salt. Diverse alkali metal cations were incorporated alongside these polycations, hinting at the existence of a structure family, despite stacking faults preventing a full structure elucidation of all compounds.
在离子热合成中,硫化铋与螺二立方烷阳离子 (Bi 7 S 8 ) 5+反应,后者结晶为结构复杂的盐。尽管堆垛层错阻碍了所有化合物的完整结构阐明,但各种碱金属阳离子与这些聚阳离子并入,暗示了结构族的存在。