potassium(II) sulfoxylate | 106992-37-4

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• 英文名称: potassium(II) sulfoxylate
• CAS: 106992-37-4
• 化学式: KO₂S
• 分子量: 103.163
• InChiKey: ZCVWLKINFRVLJY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氢化钾 在 SO₂ 作用下， 以 neat (no solvent, gas phase) 为溶剂， 生成 potassium(II) sulfoxylate
  参考文献：
  名称：

  Investigation of the gas-phase kinetics of the reaction potassium + sulfur dioxide + argon

  摘要：

  The recombination of atomic potassium, K(4(2)S), With SO2 has been investigated at about 863 K, in a bath of Ar at pressures from 20 to 690 mbar. K was generated by flash photolysis of KI vapor and monitored by time-resolved resonance absorption of a D-line at 766 nm under pseudo-first-order conditions. The measured pseudo-second-order rate constants lie in the low-pressure and falloff regions and were fitted with an empirical RRKM expression to yield k0 = 5.9 X 10(-29) cm6 s-1 and k(infinity) = 6.2 X 10(-10) cm3 s-1. Error limits are discussed in the text. The KSO2 adduct was characterized by ab initio methods. An RRKM analysis of k0, together with a lower limit to the equilibrium constant, yielded a K-SO2 bond strength of 190 +/- 10 kJ mol-1. k(infinity) was shown to be consistent with a simple harpoon model for electron transfer.

  DOI：

  10.1021/j100122a020