(1,4,8,11,15,18,22,25-octaheptylphthalocyaninato)cobalt(II) | 165285-37-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: (1,4,8,11,15,18,22,25-octaheptylphthalocyaninato)cobalt(II)
• 英文别名: cobalt(2+);5,8,14,17,23,26,32,35-octaheptyl-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene
• CAS: 165285-37-0
• 化学式: C₈₈H₁₂₈CoN₈
• 分子量: 1357.03
• InChiKey: JXYBTEGDUOIPLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium cyanide 、 (1,4,8,11,15,18,22,25-octaheptylphthalocyaninato)cobalt(II) 在 air 作用下， 以 乙醇 为溶剂， 以84%的产率得到sodium dicyano(1,4,8,11,15,18,22,25-octa-n-heptylphthalocyaninato)cobalt(III)
  参考文献：
  名称：

  Reaction of Cyanogen with Cobalt Phthalocyanines

  摘要：

  The soluble (phthalocyaninato)- and (2,3-naphthalocyaninato)cobalt(II) complexes (t-Bu)(4)PcCo, 2,3,9,10,16,17,23,24-(C7H15)(8)PcCo, 1,4,8,11,15,18,22,25-(C7H15)(8)PcCo, and (t-Bu)(4)2,3-NcCo react with cyanogen with formation of cyano-bridged oligomers of the type ([MacCo(CN)](n)). The same products are also prepared via an earlier developed method by reaction of the (phthalocyaninato)cobalt(II) compounds with KCN via K[MacCo(CN)(2)] complexes and treatment with water. The conductivities of the obtained cyano-bridged systems ([MacCo(CN)](n)) are measured, and [(t-Bu)(4)-2,3-NcCo(CN)](n) shows a remarkable conductivity of 8 x 10(-2) S/cm.

  DOI：

  10.1021/ic00118a009
• 作为产物：
  描述：

  3,6-diheptylphthalonitrile 、 氯化高钴 以 乙二醇 为溶剂， 以58%的产率得到(1,4,8,11,15,18,22,25-octaheptylphthalocyaninato)cobalt(II)
  参考文献：
  名称：

  Reaction of Cyanogen with Cobalt Phthalocyanines

  摘要：

  The soluble (phthalocyaninato)- and (2,3-naphthalocyaninato)cobalt(II) complexes (t-Bu)(4)PcCo, 2,3,9,10,16,17,23,24-(C7H15)(8)PcCo, 1,4,8,11,15,18,22,25-(C7H15)(8)PcCo, and (t-Bu)(4)2,3-NcCo react with cyanogen with formation of cyano-bridged oligomers of the type ([MacCo(CN)](n)). The same products are also prepared via an earlier developed method by reaction of the (phthalocyaninato)cobalt(II) compounds with KCN via K[MacCo(CN)(2)] complexes and treatment with water. The conductivities of the obtained cyano-bridged systems ([MacCo(CN)](n)) are measured, and [(t-Bu)(4)-2,3-NcCo(CN)](n) shows a remarkable conductivity of 8 x 10(-2) S/cm.

  DOI：

  10.1021/ic00118a009