1,10-bis(1,8-naphthalimido)decane | 58726-68-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 1,10-bis(1,8-naphthalimido)decane
• 英文别名: 2,2'-Decane-1,10-diylbis(1h-benzo[de]isoquinoline-1,3(2h)-dione)；2-[10-(1,3-dioxobenzo[de]isoquinolin-2-yl)decyl]benzo[de]isoquinoline-1,3-dione
• CAS: 58726-68-4
• 化学式: C₃₄H₃₂N₂O₄
• 分子量: 532.639
• InChiKey: KKSPVMLHIRZWCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  40
• 可旋转键数：
  11
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,8-萘二甲酸酐 、 癸二胺 在 Shellsol A 作用下， 反应 3.0h， 以77%的产率得到1,10-bis(1,8-naphthalimido)decane
  参考文献：
  名称：

  Vitrigens. I. Synthesis and Characterization of Low Molecular Weight Organic Glasses

  摘要：

  New low molecular weight organic materials with a strong tendency towards glass formation and glass temperatures above room temperature were synthesized. These materials consist of twin molecules where two bulky groups, i.e. carbazole (Ca), 3,6-dibromocarbazole (DBrCa), 2,3-benzocarbazole (BC), 1,2-benzo-3,4-dihydrocarbazole (BCDH), phenothiazine (Ph), 1,8-naphthalic acid anhydride (NI), and pyrene-l-aldehyde (PY) have been linked by flexible or semiflexible aliphatic or aromatic central units. Their structure-glass temperature relationship and some relations between thermodynamic parameters and amorphous properties are discussed.

  DOI：

  10.1002/(sici)1521-3897(199902)341:2<128::aid-prac128>3.0.co;2-m

文献信息

• Process for producing a film-like and fibrous article of a wholly aromatic polyester
  申请人：TEIJIN LIMITED

  公开号：EP0070539A1

  公开（公告）日：1983-01-26

  A wholly aromatic polyester composition comprising (a) 100 parts by weight of a wholly aromatic polyester containing as a main component at least one compound selected from the group consisting of aromatic dicarboxylic acids, aromatic dihydroxy compounds and aromatic hydroxycarboxylic acids, and (b) from 5 to 300 parts by weight of a low-molecular-weight compound being substantially non-reactive with the wholly aromatic polyester and having a boiling point of at least about 200°C under atmospheric pressure and a molecular weight of not more than 1.000. The wholly aromatic polyester composition is produced advantageously by polycondensing in the molten state the polyester-forming starting mixture in the presence of the low-molecular-weight compound. A film-like or fibrous article of a wholly aromatic polyester may be produced by extracting the low-molecular-weight compound from a film-like or fibrous article of the wholly aromatic polyester composition.

  全芳香族聚酯组合物，包括 (a) 100 份（按重量计）全芳香族聚酯，其主要成分含有至少一种选自芳香族二 羧酸、芳香族二羟基化合物和芳香族羟基羧酸的化合物，以及 (b) 5 至 300 重量份的低分子量化合物，该化合物与全芳香族聚酯基本不发生 反应，在常压下沸点至少约为 200℃，分子量不超过 1.000。 全芳香族聚酯组合物的有利生产方法是在低分子量化合物存在下，在熔融状态下对聚酯形成起始混合物进行缩聚。 全芳香族聚酯的薄膜状或纤维状制品可通过从全芳香族聚酯组合物的薄膜状或纤维状制品中提取低分子量化合物而制成。
• Mixtures of polyamideimides, containing 3,4'-diaminodiphenylether as diamine component, and of a plasticizer.
  申请人：TEIJIN LIMITED

  公开号：EP0210851A2

  公开（公告）日：1987-02-04

  A polyimide capable of forming a self-supporfing film, comprising a unit represented by the following formula (I) and a unit represented by the following formula (II) as main units forming the molecular chains of the polyimide; and an intimate mixture comprising (A) a polyamideimide comprising a unit of the following formula (II) and a unit of the following formula (IV) as main units forming the molecular chains of the polyamideimide, and (B) a plasticizing material for the polyamideimide (A).

  一种能形成自支撑薄膜的聚酰亚胺，由下式（I）代表的单元和下式（II）代表的单元组成 和下式（II）所代表的单元作为构成聚酰亚胺分子链的主单元 作为构成聚酰亚胺分子链的主单元；以及一种亲密混合物，其中包括 (A) 一种聚酰胺酰亚胺，包含下式（II）单元 和下式（IV）的一个单元 (B) 聚酰胺酰亚胺 (A) 的增塑材料。
• Wholly aromatic polyester composition and process for producing it
  申请人：TEIJIN LIMITED

  公开号：EP0156966B1

  公开（公告）日：1988-10-19
• US4416839A
  申请人：——

  公开号：US4416839A

  公开（公告）日：1983-11-22
• Vitrigens. I. Synthesis and Characterization of Low Molecular Weight Organic Glasses
  作者：D. Braun、R. Langendorf

  DOI：10.1002/(sici)1521-3897(199902)341:2<128::aid-prac128>3.0.co;2-m

  日期：1999.2

  New low molecular weight organic materials with a strong tendency towards glass formation and glass temperatures above room temperature were synthesized. These materials consist of twin molecules where two bulky groups, i.e. carbazole (Ca), 3,6-dibromocarbazole (DBrCa), 2,3-benzocarbazole (BC), 1,2-benzo-3,4-dihydrocarbazole (BCDH), phenothiazine (Ph), 1,8-naphthalic acid anhydride (NI), and pyrene-l-aldehyde (PY) have been linked by flexible or semiflexible aliphatic or aromatic central units. Their structure-glass temperature relationship and some relations between thermodynamic parameters and amorphous properties are discussed.