1,3-bis(1,8-naphthalimido)propane | 94887-61-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 1,3-bis(1,8-naphthalimido)propane
• 英文别名: 2-[3-(1,3-Dioxobenzo[de]isoquinolin-2-yl)propyl]benzo[de]isoquinoline-1,3-dione
• CAS: 94887-61-3
• 化学式: C₂₇H₁₈N₂O₄
• 分子量: 434.451
• InChiKey: KRSDXSWORJBKDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,8-萘二甲酸酐 、 1,3-丙二胺 在 Shellsol A 作用下， 反应 3.0h， 以58%的产率得到1,3-bis(1,8-naphthalimido)propane
  参考文献：
  名称：

  Vitrigens. I. Synthesis and Characterization of Low Molecular Weight Organic Glasses

  摘要：

  New low molecular weight organic materials with a strong tendency towards glass formation and glass temperatures above room temperature were synthesized. These materials consist of twin molecules where two bulky groups, i.e. carbazole (Ca), 3,6-dibromocarbazole (DBrCa), 2,3-benzocarbazole (BC), 1,2-benzo-3,4-dihydrocarbazole (BCDH), phenothiazine (Ph), 1,8-naphthalic acid anhydride (NI), and pyrene-l-aldehyde (PY) have been linked by flexible or semiflexible aliphatic or aromatic central units. Their structure-glass temperature relationship and some relations between thermodynamic parameters and amorphous properties are discussed.

  DOI：

  10.1002/(sici)1521-3897(199902)341:2<128::aid-prac128>3.0.co;2-m

文献信息

• Electron impact mass spectrometry of some unsubstituted and chlorine-substituted bisnaphthalimides and related synthons
  作者：L. Krotz、R. Seraglia、P. Traldi、F. Guidugli、J. Kavka、C. Gaozza

  DOI：10.1002/oms.1210261011

  日期：1991.10

  AbstractThe electron impact induced fragmentations of some unsubstituted and chlorine‐substituted naphthalimides and bisnaphthalimides are discussed in detail with the aid of B/E and B2/E linked‐scans for metastable ion analysis and collisional activation experiments. In the case of bisnaphthalimides the more important primary decomposition routes are related to cleavages of the alkyl chain.