4-tert-butyl-naphthalene-2-carbonitrile

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-tert-butyl-naphthalene-2-carbonitrile
• 英文别名: 4-Tert-butylnaphthalene-2-carbonitrile；4-tert-butylnaphthalene-2-carbonitrile
• 化学式: C₁₅H₁₅N
• 分子量: 209.291
• InChiKey: CWULYBVJEUUGJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-tert-butyl-naphthalene-2-carbonitrile 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以36%的产率得到(4-(tert-butyl)naphthalen-2-yl)methanamine
  参考文献：
  名称：

  ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

  摘要：

  披露了一种化合物，其包括公式I的配体LA，其中G具有以下结构。在配体LA中，环C为5元环或6元环；K是直接键，O或S；当K为O或S时，X6为C；RA、RB和RC中的每一个都是H或取代基，并且可以连接在一起形成环；X1到X6中的每一个都是独立的C或N；如果X1连接到环C，则X1为C；至少两个相邻的X2到X5的RB取代基连接在一起形成环；并且配体LA通过两个指示的破折号线与Ir络合形成5元螯合环。还披露了含有该化合物的有机发光器件、消费品、配方和化学结构。

  公开号：

  US20220045284A1
• 作为产物：
  描述：

  4-(tert-butyl)naphthalen-2-yl trifluoromethanesulfonate 在 四(三苯基膦)钯 作用下， 生成 4-tert-butyl-naphthalene-2-carbonitrile
  参考文献：
  名称：

  ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

  摘要：

  Provided are phenylthienothiazole containing compounds. The compound of the present invention comprises a first phenylthienothiazole-derived ligand L A according to Formula I as described herein which is coordinated to Ir to form a 5-membered chelate ring. Also provided are formulations comprising these compounds. Further provided are OLEDs and related consumer products that utilize these compounds.

  公开号：

  US20220135605A1

文献信息

• PYRENE-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DIODE COMPRISING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20140183468A1

  公开（公告）日：2014-07-03

  A pyrene-based compound and an organic light-emitting diode including the pyrene-based compound are provided. The pyrene-based compound of Formula 1 above may emit blue light having high color purity. For example, an organic light-emitting diode including the pyrene-based compounds of the invention may emit blue light having a y coordinate with a color purity of 0.1 or less, for example, a color purity of 0.09 or less, which is near to the NTSC or sRGB specification. A thin film including the pyrene-based compounds of the invention may be highly amorphous, and thus may have improved electrical stability. Accordingly, an organic light-emitting diode including the pyrene-based compounds of the invention may have improved lifetime characteristics.
• US9905776B2
  申请人：——

  公开号：US9905776B2

  公开（公告）日：2018-02-27