12,12-Dimethyltridecan-1-amine;hydrochloride

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 12,12-Dimethyltridecan-1-amine;hydrochloride
• 英文别名: 12,12-dimethyltridecan-1-amine;hydrochloride
• 化学式: C15H34ClN
• 分子量: 263.89
• InChiKey: UGNHKKUMGUXEBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.31
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  2
• 氢受体数：
  1

文献信息

• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Process for preparing n-substituted amine
  申请人：Kao Corporation

  公开号：EP0312253A2

  公开（公告）日：1989-04-19

  An N-substituted amine is produced by reacting an alcohol or aldehyde with ammonia, a primary amine or a secondary amine in the presence of a catalyst comprising: (a) (1) copper, (2) a metal selected from the group consisting of chromium, manganese, iron and zinc and (3) a metal of the platinum VIII group; (b) (1) copper, (2) cobalt and (3) a metal of the platinum VIII group; (c) (1) copper, (2) a metal selected from the group consisting of chromium, manganese, iron, cobalt, nickel and zinc, (3) a metal of the platinum VIII group and (4) a melal selected from the group consisting of alkali metals and alkaline earth metals; or (d) (1) copper, (2) a metal selected from the group consisting of chromium, manganese, iron, cobalt, nickel and zinc, (3) a metal of the platinum VIII group and (4) a metal selected from the group consisting of aluminum, tungsten and molybdenum.

  在催化剂的作用下，醇或醛与氨、伯胺或仲胺反应生成 N-取代胺，催化剂包括 (a) (1)铜；(2)选自铬、锰、铁和锌的金属；(3)铂 VIII 族金属； (b) (1) 铜，(2) 钴和 (3) 铂 VIII 族的一种金属； (c) (1)铜，(2)选自铬、锰、铁、钴、镍和锌组成的组中的一种金属，(3)铂 VIII 族的一种金属和(4)选自碱金属和碱土金属组成的组中的一种金属；或 (d) (1) 铜，(2) 从铬、锰、铁、钴、镍和锌组成的组中选出的金属，(3) 铂 VIII 族金属，(4) 从铝、钨和钼组成的组中选出的金属。
• Process for preparing N-substituted amine
  申请人：KAO CORPORATION

  公开号：EP0485371A1

  公开（公告）日：1992-05-13

  An N-substituted amine is produced by reacting an alcohol or aldehyde with ammonia, a primary amine or a secondary amine in the presence of a catalyst comprising (1) copper, (2) a metal selected from chromium, manganese, iron, cobalt, nickel and zinc, (3) a metal of the platinum VIII group and (4) a metal selected from aluminium, tungsten and molybdenum.

  在催化剂的作用下，醇或醛与氨、伯胺或仲胺反应生成 N-取代胺，催化剂包括：(1) 铜；(2) 选自铬、锰、铁、钴、镍和锌的金属；(3) 铂 VIII 族金属；(4) 选自铝、钨和钼的金属。
• Dimerization process of n-butene
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0488073A1

  公开（公告）日：1992-06-03

  This invention provides a process for the dimerization of n-butene. According to the process, a Ziegler catalyst system composed of a nickel compound and an organoalkylaluminum is added, as a third component, with an amine and/or a quaternary ammonium chloride. The amine can be a primary, secondary or tertiary amine. This process makes it possible to selectively prepare isooctene having a low degree of branching while maintaining high catalytic activity.

  本发明提供了一种正丁烯二聚化工艺。根据该工艺，由镍化合物和有机烷基铝组成的齐格勒催化剂体系作为第三组分加入胺和/或季铵氯化物。胺可以是伯胺、仲胺或叔胺。这种工艺可以在保持高催化活性的同时，选择性地制备具有低分支度的异辛烯。
• COMPOSITION FOR OPTICAL MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1326095A1

  公开（公告）日：2003-07-09

  The present invention relates to a composition for optical materials, comprising (a) a compound having in one molecule at least one structure represented by the following Formula 1: wherein R1 is a C0-10 hydrocarbon group, each of R2, R3 and R4 is a C1-10 hydrocarbon group or hydrogen, Y is O, S, Se or Te, m is 1 to 5, and n is 0 to 5; (b) a compound having in one molecule at least one isocyanate group and/or at least one isothiocyanate group; (c) a compound having in one molecule at least one mercapto group; and (d) an inorganic compound having sulfur atom and/or selenium atom, and also relates to an optical material produced by polymerization curing the composition, a production method thereof, and an optical lens comprising the optical material. The present invention provides a high refractive, high Abbe's number optical material having an improved impact resistance.

  本发明涉及一种光学材料组合物，包括 (a) 在一个分子中至少有一个结构由下式 1 表示的化合物： 其中 R1 为 C0-10 烃基，R2、R3 和 R4 各为 C1-10 烃基或氢，Y 为 O、S、Se 或 Te，m 为 1 至 5，n 为 0 至 5； (b) 在一个分子中至少具有一个异氰酸酯基团和/或至少一个异硫氰酸酯基团的化合物；(c) 在一个分子中具有至少一个巯基的化合物；以及 (d) 具有硫原子和/或硒原子的无机化合物，还涉及通过聚合固化该组合物生产的光学材料、其生产方法以及包含该光学材料的光学透镜。本发明提供了一种高折射率、高阿贝数的光学材料，具有更好的抗冲击性。