4-Methoxy-2-tert.-octyl-phenol | 2460-62-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-Methoxy-2-tert.-octyl-phenol
• 英文别名: 3-tert.Octyl-4-hydroxy-anisol；2-t-Octyl-4-methoxyphenol；4-methoxy-2-(2,4,4-trimethylpentan-2-yl)phenol
• CAS: 2460-62-0
• 化学式: C₁₅H₂₄O₂
• 分子量: 236.354
• InChiKey: UGJYGWNQFXIHMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(1,1,3,3-四甲基丁基)氢醌 、 硫酸二甲酯 在 sodium hydroxide 、 锌 作用下， 生成 4-Methoxy-2-tert.-octyl-phenol
  参考文献：
  名称：

  Pospisil,J. et al., Collection of Czechoslovak Chemical Communications, 1966, vol. 31, p. 98 - 105

  摘要：

  DOI：

文献信息

• Hydrochinonäther und ein Verfahren zu deren Herstellung
  申请人：CIBA-GEIGY AG

  公开号：EP0098241A1

  公开（公告）日：1984-01-11

  Es werden Hydrochinonäther der Formel I und Salze davon mit Basen oder organischen oder anorganischen Säuren beschrieben, worin p 1 oder 2 und q 0 oder 1 sind, mit der Massgabe, dass p+q 1 oder 2 ist, R einen Rest der Formel II und Q -COOR4, -CON(R4) (R5), -OR7, -OCOR7, -N(R8) (R9), -PO(OR10) ([O]xR11), -SO2R12, -CN, Halogen, -N02 oder -COR15 bedeuten, n eine ganze Zahl von 1 bis 20 und k die Zahl 1 oder 2 bedeuten, und R0, R00, R1 bis R5, R7 bis R12 und R15 die im Patentanspruch 1 angegebene Bedeutung haben. Die Verbindungen der Formel I finden Anwendung in Schichten photographischer Materialien.

  式 I 的氢醌醚及其与碱或有机酸或无机酸的盐 及其与碱或有机酸或无机酸的盐，其中 p 为 1 或 2，q 为 0 或 1，但 p+q 为 1 或 2，R 为式 II 的基团 Q是-COOR4、-CON(R4) (R5)、-OR7、-OCOR7、-N(R8) (R9)、-PO(OR10) ([O]xR11) 、-SO2R12、-CN、卤素、-N02或-COR15，n是1至20的整数，k是数字1或2，R0、R00、R1至R5、R7至R12和R15具有权利要求1中给出的含义。 式 I 的化合物用于感光材料层。
• Multi-layer cover golf ball having a high acid casing layer
  申请人：Acushnet Company

  公开号：US10029151B2

  公开（公告）日：2018-07-24

  A golf ball includes a single core having an outer surface and a geometric center. The core is formed from a substantially homogenous rubber composition. An inner cover layer is disposed about the core, the inner cover including a high-acid ionomer and having a material hardness of about 66 to 75 Shore D. The high-acid ionomer has an acid content of about 16% or greater. An outer cover layer is disposed about the inner cover layer, the outer cover including a polyurethane and having a material hardness of about 38 Shore D to about 56 Shore D. The core surface hardness is from 0 Shore C to 15 Shore C lower than the geometric center hardness to define a hardness gradient.

  高尔夫球包括一个具有外表面和几何中心的球芯。球芯由基本均匀的橡胶成分形成。内包层围绕球芯设置，内包层包括高酸离子聚合物，材料硬度约为 66 至 75 邵氏硬度 D，高酸离子聚合物的酸含量约为 16% 或更高。核心表面硬度比几何中心硬度低 0 至 15 肖氏硬度，从而形成硬度梯度。
• Golf ball incorporating positive hardness gradient thermoset polyurethane outer cover layer
  申请人：Acushnet Company

  公开号：US10252115B2

  公开（公告）日：2019-04-09

  Golf ball comprising a core having a hardness gradient and an outer cover layer having a microhardness gradient and being formed from a thermoset polyurethane material throughout, and having: i) a treated region that is contacted with a thermoset polyurethane microhardness-increasing solution consisting of an isocyanate portion and at least one non-aqueous solvent; and ii) an untreated region that is not contacted with the thermoset polyurethane microhardness-increasing solution. The treated region comprises the isocyanate portion, whereas the untreated region does not comprise the isocyanate portion. Treated region has a microhardness M1 that is greater than microhardness M2 of untreated region to define the outer cover layer positive microhardness gradient ΔM=M1−M2. The treated region may have a depth Dtr that extends inward from the cover outer surface and in some embodiments is less than a thickness of the untreated region. Treated region may alternatively extend from the inner surface toward outer surface.

  高尔夫球，包括一个具有硬度梯度的球芯和一个具有微硬度梯度的外包层，整个外包层由热固性聚氨酯材料形成，并具有：i) 与由异氰酸酯部分和至少一种非水溶剂组成的热固性聚氨酯微硬度增加溶液接触的处理区域；以及 ii) 未与热固性聚氨酯微硬度增加溶液接触的未处理区域。处理区包括异氰酸酯部分，而未处理区不包括异氰酸酯部分。处理区的显微硬度 M1 大于未处理区的显微硬度 M2，以确定外覆盖层的正显微硬度梯度 ΔM=M1-M2。处理区可具有从覆盖层外表面向内延伸的深度 Dtr，在某些实施例中小于未处理区的厚度。处理区也可以从内表面向外表面延伸。
• Golf ball incorporating a mixture of a thermoset and/or thermoplastic composition and a plurality of conductive nanoshelled structures
  申请人：Acushnet Company

  公开号：US10428216B2

  公开（公告）日：2019-10-01

  Golf ball having CoR of at least 0.700 and compression of at least 50 and comprising a layer of a mixture of thermoset or thermoplastic composition and a plurality of conductive nanoshelled structures such as conductive hollow nanoshells and/or nanorice particles. Conductive nanoshelled structures may be included in amount of from about 2 wt % to greater than 50 wt. % of total weight of mixture. Diameter of each conductive nano shelled structure at widest cross-section may be up to 1000 nm. Each conductive hollow nanoshell may have shell thickness to longitudinal diameter ratio of from about 1:3 to about 1:100. Each nanorice particle may have longitudinal diameter of up to 1000 nm. Shell thickness can be from 1 nm to 100 nm and may be controlled. A layer consisting of mixture may have specific gravity that differs from specific gravity of a layer consisting of the thermoset or thermoplastic composition portion of mixture.

  高尔夫球的 CoR 至少为 0.700，压缩率至少为 50，包括一层热固性或热塑性组合物的混合物和多个导电纳米壳结构，如导电中空纳米壳和/或纳米粒子。导电纳米壳结构的含量可占混合物总重量的 2% 至 50%。每个导电纳米壳结构的最宽横截面直径可达 1000 纳米。每个导电中空纳米壳的壳厚度与纵向直径之比可以从约 1:3 到约 1:100。每个纳米粒子的纵向直径可达 1000 纳米。壳厚度可从 1 纳米到 100 纳米，并可加以控制。由混合物组成的层的比重可不同于由混合物的热固性或热塑性成分部分组成的层的比重。
• Method of Treating Rubber Composition with Cure Inhibitor to Create Soft Skin in Golf Ball Core
  申请人：Sullivan Michael J.

  公开号：US20090023865A1

  公开（公告）日：2009-01-22

  A method of making a golf ball comprising the steps of providing a preform comprising an uncured polybutadiene composition; coating the preform with a cure-altering material comprising an organosulfur compound, an inorganic sulfide compound, or a metal-containing organosulfur compound; curing the coated preform at a predetermined temperature to form a crosslinked golf ball core having an outer surface having a first hardness and a geometric center having a second hardness greater than the first to define a negative hardness gradient; and forming a cover layer about the core to form the golf ball.