guanidine picrate | 4336-48-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: guanidine picrate
• 英文别名: guanidinium picrate；picric acid ; guanidine picrate；Picrinsaeure; Guanidin-picrat；Guanidin; Guanidinpikrat；guanidine, compd. with 2,4,6-trinitrophenol；carbamimidoylazanium;2,4,6-trinitrophenolate
• CAS: 4336-48-5
• 化学式: CH₅N₃*C₆H₃N₃O₇
• 分子量: 288.177
• InChiKey: GARCJIQFHZTIFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.04
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  234
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  胍 生成 guanidine picrate
  参考文献：
  名称：

  Über einen Fall von wahrscheinlicher Stereoisomerie beim Guanidin

  摘要：

  DOI：

  10.1007/bf01526151

文献信息

• Explosive composition containing guanidinium picrate
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US04094710A1

  公开（公告）日：1978-06-13

  An explosive composition with enhanced thermal stability and decreased imt sensitivity comprising an explosive material completely surrounded by a layer of guanidinium picrate.

  一种具有增强热稳定性和降低感度的爆炸组合物，包括一个完全被一层胍基硝酸盐包围的爆炸物质。
• 2-(2-Hydroxybiphenyl-3-yl)-1H-Benzoimidazole-5-Carboxamidine Derivatives as Factor VIIA Inhibitors
  申请人：KOLESNIKOV Aleksandr

  公开号：US20090054432A1

  公开（公告）日：2009-02-26

  The present invention relates to novel inhibitors of Factors VIIa, IXa, Xa, XIa, in particular Factor VIIa, pharmaceutical compositions comprising these inhibitors, and methods for using these inhibitors for treating or preventing thromboembolic disorders, cancer or rheumatoid arthritis. Processes for preparing these inhibitors are also disclosed.

  本发明涉及新型 VIIa、IXa、Xa、XIa 因子的抑制剂，特别是 VIIa 因子的抑制剂，包括这些抑制剂的药物组合物，以及使用这些抑制剂治疗或预防血栓栓塞性疾病、癌症或类风湿关节炎的方法。本发明还公开了制备这些抑制剂的方法。
• Halogen exchange reactions and catalysts therefor
  申请人：——

  公开号：US20030163000A1

  公开（公告）日：2003-08-28

  An essentially anhydrous agitated mixture of (i) finely-divided essentially anhydrous alkali metal fluoride (e.g., KF), (ii) haloaromatic compound having at least one halogen atom of atomic number greater than 9 on an aromatic ring (e.g., C 6 Cl 6 ), and (iii) an organo guanidinium salt catalyst (e.g., [(Et 2 N) 2 CNEt 2 ]Br), is heated at a temperature at which fluorine replaces one or more of the ring halogen atoms of the haloaromatic compound. A new synthetic route to hexahydrocarbyl guanidinium salts is also described.

  本发明涉及一种基本无水的搅拌混合物，包括（i）细分粉末的基本无水碱金属氟化物（例如KF），（ii）在芳香环上具有原子序数大于9的至少一个卤素原子的卤代芳香化合物（例如C6Cl6），以及（iii）一种有机胍盐催化剂（例如（Et2N）2CNEt2Br），在氟原子取代卤代芳香化合物的一个或多个环卤素原子的温度下加热。本发明还描述了一种新的合成六氢烷基胍盐的方法。
• Process for the preparation of organo guanidinium salts
  申请人：Chordip Ltd.

  公开号：EP1288196A1

  公开（公告）日：2003-03-05

  A process for the preparation of monovalent or divalent organo guanidinium salts is described. If the product is a monovalent organo guanidinium salt, the process comprises mixing together a halohydrocarbon, an inorganic base, and a salt of unsubstituted guanidine. If the product is a divalent organo guanidinium compound, the process comprises mixing together a first halohydrocarbon, an inorganic base, and a salt of unsubstituted guanidine, followed by mixing of a second halohydrocarbon with the mixture so formed; this is followed by the mixing of a third halohydrocarbon with the mixture formed from the mixing of the second halohydrocarbon. Both processes do not require the absence of water; the use of an organic solvent is optional.

  描述了一种制备一价或二价有机胍盐的工艺。如果产物是一价有机胍盐，该工艺包括将卤代烃、无机碱和未取代胍盐混合在一起。如果产物是二价有机胍化合物，则工艺包括将第一卤代烃、无机碱和未取代的胍盐混合在一起，然后将第二卤代烃与这样形成的混合物混合；接着将第三卤代烃与第二卤代烃混合形成的混合物混合。这两种工艺都不要求没有水；有机溶剂的使用是可选的。
• Pyrotechnic agent
  申请人：Bley Ulrich

  公开号：US10968147B2

  公开（公告）日：2021-04-06

  The invention relates to a pyrotechnic agent containing at least one azotetrazolate as a component thereof.

  本发明涉及一种含有至少一种偶氮四唑醇成分的烟火剂。