N-辛基-N'-苯基-1,4-苯二胺 | 1590-80-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-辛基-N'-苯基-1,4-苯二胺
• 英文名称: 1,4-Benzenediamine, N-octyl-N'-phenyl-
• 英文别名: 1-N-octyl-4-N-phenylbenzene-1,4-diamine
• CAS: 1590-80-3；34533-96-5
• 化学式: C₂₀H₂₈N₂
• 分子量: 296.4
• InChiKey: MINNIIWBFAPUKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

文献信息

• Direct alkylation of N-alkyl-N'-phenyl-p-phenylenediamine
  申请人：Wang Jin-Yun

  公开号：US20070173668A1

  公开（公告）日：2007-07-26

  A single-step process is disclosed for the ring alkylation of at least one N-alkyl-N′-phenyl-phenylenediamine with at least one olefin wherein the process comprises heating a mixture of the N-alkyl-N′-phenyl-phenylenediamine(s) and olefin(s) in the presence of a catalytic amount of at least one alkyl aluminum halide at a temperature of from about 50 to about 350° C. in a sealed vessel for from about one to about 30 hours.

  揭示了一种单步过程，用于将至少一种N-烷基-N'-苯基-苯二胺与至少一种烯烃进行环烷化反应，其中该过程包括在密封容器中，在存在至少一种烷基铝卤化物的催化剂作用下，将N-烷基-N'-苯基-苯二胺(s)和烯烃(s)的混合物加热至约50℃至约350℃的温度，反应时间为约1至约30小时。
• Diesel Composition and Method of Increasing Biodiesel Oxidation Stability
  申请人：Lin Jianmin

  公开号：US20120124896A1

  公开（公告）日：2012-05-24

  The present invention discloses a diesel composition, which comprises a base diesel and an additive composition, characterized in that said base diesel comprises biodiesel, and said additive composition comprises component (a) and component (b), wherein said component (a) is an arylamine-type antioxidant, and said component (b) is one or more polyamines or derivatives thereof. The diesel composition of the present invention has a superior oxidation stability.

  本发明揭示了一种柴油组合物，包括基础柴油和添加剂组合物，其特征在于所述基础柴油包括生物柴油，所述添加剂组合物包括组分（a）和组分（b），其中所述组分（a）是芳基胺类抗氧化剂，所述组分（b）是一种或多种聚胺或其衍生物。本发明的柴油组合物具有优异的氧化稳定性。
• Method for curing a curable halogen-containing rubber composition
  申请人：KYOWA CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0097330A1

  公开（公告）日：1984-01-04

  A curable rubber composition composed of a halogen-containing rubber and at least one member selected from the group consisting of a vulcanizing agent and a vulcanization accelerator other than thiazole-type vulcanization accelerators is cured under heat in the presence of, as an acid acceptor, a hydrotalcite compound of the following formulawherein M2+ represents at least one metal element selected from the group consisting of Mg and Zn, An- represents an anion having a valence of n, m represents a positive number, and x and z represent positive numbers satisfying the following expressionsor its calcination product. The cured product has improved water resistance.

  一种由含卤橡胶和至少一种选自硫化剂和硫化促进剂（噻唑类硫化促进剂除外）组的成员组成的可硫化橡胶组合物，在作为酸接受体存在的情况下加热硫化、下式中 M2+ 代表从 Mg 和 Zn 组成的组中选出的至少一种金属元素，An- 代表价数为 n 的阴离子，m 代表正数，x 和 z 代表满足以下表达式的正数的氢铝土矿化合物或其煅烧产物。固化产物具有更好的耐水性。
• Adhesive compositions
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0243956A2

  公开（公告）日：1987-11-04

  An adhesive composition comprising 100 parts by weight of a block copolymer (a) containing of at least one polymer block composed mainly of a vinyl aromatic hydrocarbon and at least one polymer block composed mainly of butadiene in which (i) the vinyl aromatic hydrocarbon content [S] is 10 to 30% by weight, (ii) the 1,2-vinyl content of butadiene portion [V] is 20 to 50%, and (iii) the relationship between said vinyl aromatic hydrocarbon content [S] and said 1,2-vinyl content of butadiene portion [V] satisfies the formula: 40 to 200 parts by weight of a tackifier (b), and, optionally contain various stabilizers; and a process for producing said composition.

  一种粘合剂组合物，包括 100 重量份的嵌段共聚物(a)，其中至少含有一个主要由乙烯基芳香烃组成的聚合物嵌段和至少一个主要由丁二烯组成的聚合物嵌段，其中(i)乙烯基芳香烃含量[S]为 10-30%（重量），(ii)丁二烯部分的 1,2-乙烯基含量[V]为 20-50%，(iii)所述乙烯基芳香烃含量[S]和所述丁二烯部分的 1,2-乙烯基含量[V]之间的关系符合公式： 40 至 200 重量份的增粘剂 (b)，以及可选的各种稳定剂；以及生产所述组合物的工艺。
• Preparation of N-substituted-N'-phenyl-P-phenylenediamines
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0617004A1

  公开（公告）日：1994-09-28

  The present invention relates to a process for the preparation of a N-substituted-N'-phenyl-p-phenylenediamine of the formula: comprising reacting (a) a mixture of (1) N-phenyl-p-quinoneimine of the formula: and (2) p-hydroxydiphenylamine in a mole ratio of N-phenyl-p-quinoneimine to p-hydroxydiphenylamine of from 1.5:1 to 1:1.5 with (b) a primary amine of the formula:         R¹-NH₂ in the presence of methanol wherein R¹ is selected from the group of radicals consisting of alkyls having 1 to 20 carbon atoms, cycloalkyls having 6 to 8 carbon atoms and radicals of the structural formula: wherein R² may be the same or different and is independently selected from the group of radicals consisting of hydrogen and an alkyl having 1 carbon atom, R³ is selected from the group of radicals consisting of an alkyl having 1 to 12 carbon atoms and n is an integer of from 0 to 6.

  本发明涉及一种制备式为 N-取代-N'-苯基-对苯二胺的工艺： 包括使(a)式中的(1)N-苯基-对醌亚胺的混合物与(2)式中的(3)N-苯基-对醌亚胺反应： 和(2)对羟基二苯胺（N-苯基对醌亚胺与对羟基二苯胺的摩尔比为 1.5:1 至 1:1.5）与(b)式中的伯胺的混合物反应： R¹-NH₂ 在甲醇存在下，其中 R¹ 选自由具有 1 至 20 个碳原子的烷基、具有 6 至 8 个碳原子的环烷基和结构式如下的基团组成的基团组： 其中 R² 可以相同或不同，且独立地选自氢和具有 1 个碳原子的烷基组成的基团组，R³ 选自具有 1 至 12 个碳原子的烷基组成的基团组，n 为 0 至 6 的整数。