7-Methyl-10,20-dithiapentacyclo[11.7.0.03,11.04,9.014,19]icosa-1,3(11),4(9),5,7,12,14,16,18-nonaene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 7-Methyl-10,20-dithiapentacyclo[11.7.0.03,11.04,9.014,19]icosa-1,3(11),4(9),5,7,12,14,16,18-nonaene
• 英文别名: 7-methyl-10,20-dithiapentacyclo[11.7.0.03,11.04,9.014,19]icosa-1,3(11),4(9),5,7,12,14,16,18-nonaene
• 化学式: C₁₉H₁₂S₂
• 分子量: 304.4
• InChiKey: YVNOTNYAIPDOQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Semiconducting polymer
  申请人：BASF SE

  公开号：US10815236B2

  公开（公告）日：2020-10-27

  Compounds of formula (I) and polymers comprising at least a structure of formula (II), wherein T1 or T2 are independently of each other a group of Formula (III), Formula (iv) Qa, Qb, Qc, Qd, Qe or Qf are independently of each other O, S or NR1.

  式(I)化合物和至少包含式(II)结构的聚合物，其中 T1 或 T2 独立地互为式(III)基团，式(iv) Qa、Qb、Qc、Qd、Qe 或 Qf 独立地互为 O、S 或 NR1。
• Naphthoindacenodithiophenes and polymers
  申请人：CLAP Co., Ltd.

  公开号：US10793668B2

  公开（公告）日：2020-10-06

  Polymers comprising at least one unit of formula 1 and compounds of the formula 1′ wherein, in formulae 1 and 1′ n is 0, 1, 2, 3 or 4 m is 0, 1, 2, 3 or 4 X is at each occurrence selected from the group consisting of O, S, Se or Te, Q is at each occurrence selected from the group consisting of C, Si or Ge R is at each occurrence selected from the group consisting of hydrogen, C1-30-alkyl, C2-30-alkenyl, C2-30-alkynyl, C5-12-cycloalkyl, C6-18-aryl, R2, R2′, R* are at each occurrence independently selected from the group consisting of hydrogen, C1-30-alkyl, C2-30-alkenyl, C2-30-alkynyl, C5-12-cycloalkyl, C6-18-aryl, 5 to 20 membered hetero-aryl, OR21, OC(O)—R21, C(O)—OR21, C(O)—R21, NR21R22, NR21—C(O)R22, C(O)—NR21R22, N[C(O)R21][C(O)R22], SR21, halogen, CN, SiRSisRSitRSiu and OH, L1 and L2 are independently from each other and at each occurrence selected from the group consisting of C6-30-arylene, 5 to 30 membered heteroarylene.

  包含至少一个式 1 单元的聚合物和式 1′ 的化合物 其中，在式 1 和 1′ 中，n 为 0、1、2、3 或 4 m 为 0、1、2、3 或 4 X 在每次出现时均选自由 O、S、Se 或 Te 组成的组、Q 在每次出现时均选自由 C、Si 或 Ge 组成的组 R 在每次出现时均选自由氢、C1-30-烷基、C2-30-烯基、C2-30-炔基、C5-12-环烷基、C6-18-芳基、R2、R2′、R* 在每次出现时均独立地选自氢、C1-30-烷基、C2-30-烯基、C2-30-炔基、C5-12-环烷基、C6-18-芳基、5 至 20 个成员的杂芳基、OR21、OC(O)-R21、C(O)-OR21、C(O)-R21、NR21R22、NR21-C(O)R22、C(O)-NR21R22、N[C(O)R21][C(O)R22]、SR21、卤素、CN、SiRSisRSitRSiu 和 OH。
• Degradable conjugated polymers
  申请人：The Board of Trustees of the Leland Stanford Junior University of the General Counsel

  公开号：US10889499B2

  公开（公告）日：2021-01-12

  A polymer comprising at least one unit of the formula (1) wherein T1 is a carbon atom or a nitrogen atom, T2 is a carbon atom if T1 is a nitrogen atom, or is a nitrogen atom if T1 is a carbon atom, r is 1, 2, 3 or 4, s is 1, 2, 3, or 4, M1 is preferably selected from the group consisting of M2 is preferably The polymers are prepared by reacting monomers (1a) with monomers (2a) H2N-[-M1-]r-NH2 (1a) OHC-[-M2-]s-CHO (2a) or the step of reacting monomers (1b) with monomers (2b) OHC-[-M1-]r-CHO (1b) H2N-[-M2-]s-NH2 (2b).

  由至少一个式（1）单元组成的聚合物 其中 T1 是碳原子或氮原子，T2 是碳原子（如果 T1 是氮原子）或氮原子（如果 T1 是碳原子），r 是 1、2、3 或 4，s 是 1、2、3 或 4、聚合物是通过单体（1a）与单体（2a）H2N-[-M1-]r-NH2（1a）OHC-[-M2-]s-CHO（2a）反应或单体（1b）与单体（2b）OHC-[-M1-]r-CHO（1b） -[-M2-]s-NH2（2b）反应的步骤制备的。
• Thieno-indeno-monomers and polymers
  申请人：BASF SE

  公开号：US11225489B2

  公开（公告）日：2022-01-18

  Disclosed herein are polymers comprising at least one unit of formulae (1a)-(1f):

  本文公开的聚合物至少包含一个式 (1a)-(1f) 单元：
• Semiconductors
  申请人：CLAP CO., LTD.

  公开号：US11384197B2

  公开（公告）日：2022-07-12

  The present invention relates to polymers comprising a repeating unit of the formula—[Ar3]c—[Ar2]b—[Ar1]a—Y(R1)n1 (R2)n2—[Ar1′]a—[Ar2′]b′—[Ar3′]c′— (I), wherein γ is a bivalent heterocyclic group, or ring system, which may optionally be substituted, Ar1, Ar1′Ar2, Ar2′, Ar3 and Ar3′ are independently of each other a C6-C24 arylen group, which can optionally be substituted, or a C2-C30 heteroarylen group, which can optionally be, Formula (1), substituted; at least one of R1 and R2 is a group of formula (II); and their use as organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes.

  本发明涉及包含式-[Ar3]c-[Ar2]b-[Ar1]a-Y(R1)n1 (R2)n2-[Ar1′]a-[Ar2′]b′-[Ar3′]c′- (I)的重复单元的聚合物，其中γ是二价杂环基团或环系、Ar1、Ar1′Ar2、Ar2′、Ar3 和 Ar3′ 相互独立地为 C6-C24 芳烯基团（可任选被取代）或 C2-C30 杂芳香基团（可任选被取代）；R1和R2中至少有一个是式(II)基团；以及它们在有机器件中作为有机半导体的用途，特别是在有机光伏器件和光电二极管中，或在含有二极管和/或有机场效应晶体管的器件中。本发明的聚合物在有机溶剂中具有极佳的溶解性和出色的成膜性能。此外，在有机场效应晶体管、有机光伏器件和光电二极管中使用本发明的聚合物时，可观察到较高的能量转换效率、出色的场效应迁移率、良好的开/关电流比和/或出色的稳定性。