N-(1-naphthylmethyl)acrylamide | 89919-19-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-(1-naphthylmethyl)acrylamide
• 英文别名: N-1-naphthylmethylacrylamide；N-(naphthalen-1-ylmethyl)prop-2-enamide
• CAS: 89919-19-7
• 化学式: C₁₄H₁₃NO
• 分子量: 211.263
• InChiKey: ZULHSPFNEOHFAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-萘甲基胺 、 丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以81%的产率得到N-(1-naphthylmethyl)acrylamide
  参考文献：
  名称：

  Macroscopic Observations of Molecular Recognition: Discrimination of the Substituted Position on the Naphthyl Group by Polyacrylamide Gel Modified with β-Cyclodextrin

  摘要：

  Macroscopic molecular recognition observations were realized using polyacrylamide-based gels modified with alpha-cyclodextrin (alpha-CD), beta-cyclodextrin (beta-CD), 1-naphthylmethyl (1Np), and 2-naphthylmethyl (2Np) moieties, which are denoted as alpha CD(x)-gel, beta CD(x)-gel, 1Np(y)-gel, and 2Np(y)-gel, where x and y indicate the mol % of CD and Np moieties, respectively. The alpha CD(5)-gel did not adhere to either the 1Np(5)-gel or 2Np(5)-gel, whereas the beta CD (5)-gel interacted with both to form alternating or checkered assemblies. Although the difference in the association constants of beta-CD for the model polymers was small, the beta CD(x)-gel successfully discriminated between 1Np(y)-gel and 2Np(y)-gel at the appropriate x and y.

  DOI：

  10.1021/la2034142

文献信息

• GEL WITH SELF-RESTORABILITY AND SHAPE-MEMORY PROPERTY AND PROCESS FOR PRODUCING SAME
  申请人：Osaka University

  公开号：US20150073091A1

  公开（公告）日：2015-03-12

  The present invention provides a gel formed by a host-guest interaction and having self-healing and shape-memory properties, and a process for producing the gel. A monomer containing a host group, a monomer containing a guest group, and an acrylic type monomer were dissolved in an aqueous solvent, and these monomers were subsequently copolymerized to produce a gel obtained from these monomers.

  本发明提供了一种通过主客体相互作用形成的具有自愈和形状记忆性质的凝胶，以及制备该凝胶的方法。将含有主体基团的单体、含有客体基团的单体和丙烯酸类单体溶解在水性溶剂中，然后共聚合这些单体以产生从这些单体中获得的凝胶。
• Water soluble fluors
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0087639A2

  公开（公告）日：1983-09-07

  Water soluble fluors useful in enhancing images obtained in autoradiography have the general formula: F is a moiety which acts as a fluor, e.g., a dehydro derivative of a compound which is a fluor; preferred examples include 4-(2,5-diphenyloxazolyl), 1-naphthyl-methyl, 2-naphthyl, and 4-[5-(2-phenyloxazolyl)]phenyl. S is a surfactant moiety which makes the molecule hydrophilic, e.g., dehydro derivatives of surfactants; preferred examples include polyethylene glycol derivatives, sulfonic acids or salts thereof, aryl sulfonates, amines and quaternary ammonium compounds. B is a binding moiety which chemically binds the fluor moiety F with the surfactant S, and may be a chemical bond, or a disubstituted moiety such as an alkylene, e.g., methylene group. The variables x, y and z are integers which can generally vary from 1 to 10. A number of such compounds are disclosed, as well as methods of using such compounds, as well as compositions and products for fluorographic analysis in connection with chromatography, electrophoresis etc.

  可用于增强自动射线照相术图像的水溶性荧光剂具有以下通式： F 是起荧光剂作用的分子，如荧光剂化合物的脱氢衍生物；首选的例子包括 4-(2,5-二苯基恶唑基)、1-萘甲基、2-萘基和 4-[5-(2-苯基恶唑基)]苯基。S 是使分子亲水的表面活性剂分子，如表面活性剂的脱氢衍生物；首选的例子包括聚乙二醇衍生物、磺酸或其盐、芳基磺酸盐、胺和季铵化合物。B 是将氟分子 F 与表面活性剂 S 化学结合的结合基，可以是化学键，也可以是二取代基，如亚 烷基，如亚甲基。变量 x、y 和 z 是整数，一般可在 1 到 10 之间变化。本发明公开了许多此类化合物、使用此类化合物的方法以及与色谱法、电泳法等有关的荧光分析组合物和产品。
• Graft copolymer and process for producing the same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0490269A1

  公开（公告）日：1992-06-17

  There is provided a process for producing a styrenic graft copolymer which comprises coplymerizing a styrenic monomer and a styrenic monomer having a hydrocarbon radical with an unsaturated bond in the presence of a catalyst comprising as primary ingredient (A) a transition metal compound and (B) a contact product of an organoaluminum compound and a condensation agent or (C) a compound which produces an ionic complex by reacting with the above-mentioned transition metal compound and subsequently graft polymerizing an ethylenically unsaturated monomer onto the resultant styrenic copolymer. The above-described styrenic graft copolymer is greatly improved in terms of compatibility, adhesivity, coatability and wettability while preserving heat resistance and chemical resistance thereof, and thus effective as a variety of constructional materials and compatibilizing agents. Furthermore, the composition or multi-layer material comprising the above-mentioned styrenic graft copolymer is widely utilized in a variety of application field including film, sheet, especially stampable sheet, container, packaging material, automobile parts, electrical and electronic parts, etc.

  提供了一种生产苯乙烯接枝共聚物的工艺，该工艺包括在催化剂存在下，使苯乙烯单体和具有不饱和键烃基的苯乙烯单体共聚，催化剂的主要成分包括(A)过渡金属化合物和(B)有机铝化合物与缩合剂的接触产物或(C)通过与上述过渡金属化合物反应产生离子络合物的化合物，然后将乙烯基不饱和单体接枝聚合到生成的苯乙烯共聚物上。上述过渡金属化合物反应生成离子络合物的化合物，然后将乙烯不饱和单体接枝聚合到生成的苯乙烯共聚物上。 上述苯乙烯接枝共聚物在保持其耐热性和耐化学性的同时，在相容性、粘合性、涂覆性和润湿性方面得到了极大的改善，因此可以有效地用作各种建筑材料和相容剂。此外，由上述苯乙烯接枝共聚物组成的组合物或多层材料可广泛应用于各种应用领域，包括薄膜、片材，尤其是可冲压片材、容器、包装材料、汽车零件、电子电气零件等。
• NEGATIVE PHOTOSENSITIVE COMPOSITION AND NEGATIVE PHOTOSENSITIVE LITHOGRAPHY PLATE
  申请人：Kodak Polychrome Graphics Japan Ltd.

  公开号：EP1757982A1

  公开（公告）日：2007-02-28

  Disclosed is a negative working photosensitive composition comprising (A) an infrared absorber, (B) an organic boron compound, (C) a compound having a polymerizable unsaturated group, and (D) a binder resin having a sulfonamide or active imino group.

  本发明公开了一种阴性工作光敏组合物，该组合物包括：(A) 红外线吸收剂；(B) 有机硼化合物；(C) 具有可聚合不饱和基团的化合物；(D) 具有磺酰胺或活性亚氨基的粘合剂树脂。
• Polymerizable composition, light-shielding color filter, black curable composition, light-shielding color filter for solid-state image pickup device and method of producing the same, and solid-state image pickup device
  申请人：FUJIFILM Corporation

  公开号：EP2112182A1

  公开（公告）日：2009-10-28

  A polymerizable composition includes a titanium black dispersion containing titanium black and an alkali-soluble resin having at least one unsaturated double bond, a polymerizable compound, and a photopolymerization initiator. A black curable composition includes titanium black, an alkali-soluble resin having a weight average molecular weight of from 2000 to less than 20,000 or a weight average molecular weight of 20,000 to 100,000, a solvent, a photopolymerization initiator, and a compound having an ethylenic unsaturated double bond. A light-shielding color filter having a colored region is formed using the polymerizable composition or the black curable composition. A solid-state image pickup device has the light-shielding color filter.

  一种可聚合组合物包括含有钛黑和至少有一个不饱和双键的碱溶性树脂的钛黑分散体、一种可聚合化合物和一种光聚合引发剂。一种黑色固化组合物包括钛黑、重量平均分子量为 2000 至小于 20000 或重量平均分子量为 20000 至 100000 的碱溶性树脂、溶剂、光聚合引发剂和具有乙烯不饱和双键的化合物。利用可聚合组合物或黑色固化组合物形成具有彩色区域的遮光彩色滤光片。固态图像拾取装置具有该遮光彩色滤光片。