Phloxin | 6441-77-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: Phloxin
• 英文别名: dipotassium;2',4',5',7'-tetrabromo-4,7-dichloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate
• CAS: 6441-77-6
• 化学式: C20H4Br4Cl2K2O5
• 分子量: 793.0
• InChiKey: JBBPTUVOZCXCSU-UHFFFAOYSA-L

物化性质

• LogP：
  7.891 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  0.77
• 重原子数：
  33
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  81.6
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 危险品标志：
  Xi
• 海关编码：
  3206500000
• 安全说明：
  S22,S24/25,S26,S37/39

制备方法与用途

用途：用作生物染色剂等。

文献信息

• Sunscreen compositions comprising colour pigments
  申请人：BASF SE

  公开号：EP2710996A2

  公开（公告）日：2014-03-26

  Disclosed are cosmetic formulation comprising (a) particulates having an absorption in the range of 400 to 800nm; and (b) UV filters selected from (b1) particulate organic UV-filters; and (b2) soluble organic UV filters.

  所公开的化妆品配方包括 (a) 吸收波长范围为 400 至 800 纳米的微粒；以及 (b) 紫外线过滤剂，选自 (b1) 颗粒有机紫外线过滤器；和 (b2) 可溶性有机紫外线过滤剂。
• HAIR DYEING COMPOSITION
  申请人：BASF SE

  公开号：EP3459520A1

  公开（公告）日：2019-03-27

  Disclosed is a hair dyeing composition comprising (a) a dye of formula (b) at least one dye selected from the compounds of formulae wherein D is the radical of a diazo component of the formula (2a) K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; and a radical of a heterocyclic coupling component; X is -O-; -S-; or-N(R8)-; Y is -CH=; -CR15=; or -N=; R1, R2, R3 and R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH-, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or-dialkylamino-substituted C1-C4alkyl; R8 is hydrogen; or C1-C4alkyl; R10 is hydrogen; C1-C4alkyl; or CN; R11 is unsubstituted or OH- or CN-substituted C1-C4alkyl; R12 is hydrogen; or C1-C4alkyl; R13 and R14 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; or R13 and R14 together with the nitrogen and carbon atoms joining them together form a 5- or 6-membered ring; R15 is hydrogen; or C1-C4alkyl; and An1-is a colorless anion; and (c) a quaternary ammonium salt.

  本发明公开了一种染发组合物，其中包括 (a) 式中的染料 (b) 至少一种选自式化合物的染料 其中 D 是式 (2a) 中重氮组分的基团 K 是偶联组分的基团，选自苯胺衍生物、苯酚衍生物和杂环偶联组分的基团； X 是-O-；-S-；或-N(R8)-； Y 是-CH=；-CR15=；或-N=； R1、R2、R3 和 R4 相互独立地为氢；或 C1-C4 烷基； R5 和 R6 各自独立地为氢、C1-C4 烷基或 C1-C4 烷氧基； R7和R9各自独立地为未取代的或OH-、C1-C4烷氧基-、卤素-、氨基-、C1-C4-单烷基或二烷基氨基-取代的C1-C4烷基； R8 是氢；或 C1-C4 烷基； R10 是氢；或 C1-C4 烷基；或 CN； R11是未取代的或OH-或CN-取代的C1-C4烷基； R12 是氢；或 C1-C4 烷基； R13和R14彼此独立地为氢、C1-C4烷基或C1-C4烷氧基；或 R13 和 R14 与连接它们的氮原子和碳原子一起形成 5 或 6 元环； R15 是氢；或 C1-C4 烷基；和 An1- 是无色阴离子；以及 (c) 季铵盐。
• COMPOSITIONS WITH IMPROVED UREASE-INHIBITING EFFECT COMPRISING AMINES, OR COLORANTS, AND AN ADDUCT OF THE THREE COMPOUNDS N-(N-BUTYL) THIOPHOSPHORIC ACID TRIAMIDE (NBPT), UREA, AND FORMALDEHYDE
  申请人：BASF SE

  公开号：EP3725756A2

  公开（公告）日：2020-10-21

  A composition comprising: (A) an adduct of the three compounds N-(n-butyl) thiophosphoric acid triamide (NBPT), urea, and formaldehyde and (L1) at least one amine selected from the group consisting of (L10), (L11), (L12), (L13), (L14), (L15), (L16), (L17), (L18), (L19), (L20), (L21), (L22), (L23), (L24), and (L29).

  一种组合物，包括 (A) N-（正丁基）硫代磷酸三酰胺（NBPT）、尿素和甲醛这三种化合物的加合物 和 (L1) 至少一种选自 (L10)、(L11)、(L12)、(L13)、(L14)、(L15)、(L16)、(L17)、(L18)、(L19)、(L20)、(L21)、(L22)、(L23)、(L24) 和 (L29) 组的胺。
• COMPOSITIONS WITH IMPROVED UREASE-INHIBITING EFFECT COMPRISING (THIO)PHOSPHORIC ACID TRIAMIDE AND FURTHER COMPOUNDS SUCH AS AMINES AND COLORANTS
  申请人：BASF SE

  公开号：EP3763691A1

  公开（公告）日：2021-01-13

  A composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)          R1R2N-P(X)(NH2)2, wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further het-eroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (L1) at least one amine selected from the group consisting of (L14) and (L15).

  一种组合物，包括 (A) 包含至少一种通式（I）的（硫代）磷酸三酰胺的混合物 R1R2N-P(X)(NH2)2、 其中 X 是氧或硫； R1 是 C1 至 C20 烷基、C3 至 C20 环烷基、C6 至 C20 芳基或二烷基氨基羰基； R2 是 H，或 R1 和 R2 连同连接它们的氮原子定义了一个 5 或 6 元饱和或不饱和杂环基，该杂环基可选择包括 1 或 2 个选自氮、氧和硫组成的组的其他氦原子、 和 (L1) 至少一种选自 (L14) 和 (L15) 组的胺。
• Compositions with improved urease-inhibiting effect comprising (thio)phosphoric acid triamide and further compounds such as amines and colorants
  申请人：BASF SE

  公开号：US10577290B2

  公开（公告）日：2020-03-03

  A composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R1R2N—P(X)(NH2)2, wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (L1) at least one amine selected from the group consisting of (L10), (L11), (L12), (L13), (L14), (L15), (L16), (L17), (L18), (L19), (L20), (L21), (L22), (L23), (L24), and (L29).

  一种组合物，包括(A) 包含至少一种通式为(I)R1R2N-P(X)(NH2)2 的(硫)磷酸三酰胺的混合物，其中 X 为氧或硫；R1 为 C1 至 C20 烷基、C3 至 C20 环烷基、C6 至 C20 芳基或二烷基氨基羰基；R2 是 H，或 R1 和 R2 连同连接它们的氮原子定义了一个 5 或 6 元饱和或不饱和杂环基，该杂环基可选择包括 1 或 2 个杂原子，这些杂原子选自氮、氧和硫组成的组、(L1) 至少一种胺，选自由 (L10)、(L11)、(L12)、(L13)、(L14)、(L15)、(L16)、(L17)、(L18)、(L19)、(L20)、(L21)、(L22)、(L23)、(L24) 和 (L29) 组成的组。