N-Acetoxy-2-N-acetylaminonaphtalene | 38105-26-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-Acetoxy-2-N-acetylaminonaphtalene
• 英文别名: N-Acetoxy-2-acetamidonaphthalin；N-Acetoxy-2-acetylaminonaphthalin；Hydroxylamine, N,O-diacetyl-N-(2-naphthyl)-；[acetyl(naphthalen-2-yl)amino] acetate
• CAS: 38105-26-9
• 化学式: C₁₄H₁₃NO₃
• 分子量: 243.262
• InChiKey: RLBVXZVYDBANEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-Acetoxy-2-N-acetylaminonaphtalene 在 水 作用下， 以 丙酮 为溶剂， 以100%的产率得到N-羟基-N-萘-2-基乙酰胺
  参考文献：
  名称：

  N-乙酰氧基-1- N-乙酰氨基萘和N-乙酰氧基-2- N-乙酰氨基萘的溶剂分解：发散化学和诱变活性

  摘要：

  在中性的40％丙酮水溶液中溶剂化时，N-乙酰氧基-1- N-和N-乙酰氧基-2- N-乙酰氨基萘显示完全不同的反应方式。前者与氮离子形成反应，而后者经历酰基氧分裂。

  DOI：

  10.1039/c39850000555

文献信息

• The solvolysis of N-acetoxy-2-acetylaminofluorene and N-acetoxy-4-acetylaminobiphenyl: delicate balance between nitrenium ion formation and hydrolysis
  作者：Graham R. Underwood、Robert B. Kirsch

  DOI：10.1039/c39850000136

  日期：——

  The solvolysis of N-acetoxy-2-acetylaminofluorene in aqueous acetone at neutral pH proceeds exclusively with nitrenium ion formation while under the same conditions, the 4-aminobiphenyl analogue exclusive acyl–oxygen scission.

  的溶剂分解ñ -乙酰氧基-2-乙酰氨基芴在中性pH的含水丙酮与nitrenium离子形成只前进而在相同条件下，将4-氨基联苯类似物独家酰氧断裂。
• NONAQUEOUS SECONDARY BATTERY AND FLAME RETARDANT FOR THE SAME
  申请人：UTSUMI Hisayuki

  公开号：US20110256457A1

  公开（公告）日：2011-10-20

  A nonaqueous secondary battery, comprising: a positive electrode; a negative electrode; and a nonaqueous electrolyte solution, the nonaqueous electrolyte solution containing as a flame retardant a compound of the general formula (I): wherein R 1 and R 2 , which are the same or different, each represents a group that is selected from a hydrogen atom, a lower alkyl, lower alkenyl, lower alkoxy, lower alkoxycarbonyl, lower alkylcarbonyl, lower cycloalkyl or aryl group, and that may have a substituent, or R 1 and R 2 taken together are a methylene group that may have a substituent, or R 1 and R 2 taken together form a ring structure containing a nitrogen atom to which R 1 and R 2 are attached, the ring structure being a five-membered or six-membered hydrocarbon ring that may have one or two oxo groups, or a five-membered or six-membered heterocycle that may further contain a nitrogen atom; n is 0 or 1; when n is 0, R 3 is a group that is selected from a hydrogen atom, a halogen atom, a lower alkyl, lower alkenyl, lower alkoxy, lower alkoxycarbonyl, lower alkylcarbonyl, lower cycloalkyl or aryl group, and that may have a substituent; and when n is 1, R 3 and R 4 are as defined for R 1 and R 2 .
• US8592081B2
  申请人：——

  公开号：US8592081B2

  公开（公告）日：2013-11-26
• The solvolysis of N-acetoxy-1-N-acetylaminonaphthalene and N-acetoxy-2-N-acetylaminonaphthalene: divergent chemistry and mutagenic activity
  作者：Graham R. Underwood、Catherine M. Davidson

  DOI：10.1039/c39850000555

  日期：——

  Upon solvolysis in neutral 40% aqueous acetone, N-acetoxy-1-N- and N-acetoxy-2-N-acetylaminonaphthalene exhibit completely different modes of reaction; the former reacts with nitrenium ion formation, while the latter undergoes acyl oxygen scission.

  在中性的40％丙酮水溶液中溶剂化时，N-乙酰氧基-1- N-和N-乙酰氧基-2- N-乙酰氨基萘显示完全不同的反应方式。前者与氮离子形成反应，而后者经历酰基氧分裂。