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Tin(II) tetrafluoroborate | 13814-97-6

中文名称
——
中文别名
——
英文名称
Tin(II) tetrafluoroborate
英文别名
tin(2+);ditetrafluoroborate
Tin(II) tetrafluoroborate化学式
CAS
13814-97-6
化学式
B2F8Sn
mdl
——
分子量
292.32
InChiKey
JPZSNSDMGTYJIW-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 熔点:
    >130°C (dec.)
  • 密度:
    1.67 g/mL at 25 °C
  • 暴露限值:
    ACGIH: TWA 2 mg/m3; TWA 2.5 mg/m3NIOSH: IDLH 100 mg/m3; IDLH 250 mg/m3; TWA 2 mg/m3
  • 稳定性/保质期:
    1. 在常温常压下稳定。 避免与碱、水溶液及碱金属、碱土金属等物质接触,也应避免与许多有机和无机的活性化学药品(如某些酸和氧化物)接触。 2. 水溶液中含有一定游离酸时呈酸性,而纯品则略带微碱性。受热或遇水易分解或发生水解反应。长期暴露在空气中会容易被氧化。

计算性质

  • 辛醇/水分配系数(LogP):
    2.22
  • 重原子数:
    11
  • 可旋转键数:
    0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    0
  • 氢给体数:
    0
  • 氢受体数:
    10

ADMET

代谢
尽管锡金属的吸收非常差,但锡化合物可以通过口服、吸入或皮肤途径被吸收,有机锡化合物的吸收速度比无机锡化合物要快得多。锡可能进入血液并绑定到血红蛋白上,在体内分布并在肾脏、肝脏、肺和骨骼中积累。锡及其代谢物主要通过尿液和粪便排出体外。(L308)
Though tin metal is very poorly absorbed, tin compounds may be absorbed via oral, inhalation, or dermal routes, with organotin compounds being much more readily absorbed than inorganic tin compounds. Tin may enter the bloodstream and bind to hemoglobin, where it is distributed and accumulates mainly in the kidney, liver, lung, and bone. Tin and its metabolites are excreted mainly in the urine and feces. (L308)
来源:Toxin and Toxin Target Database (T3DB)
毒理性
  • 毒性总结
无机和有机锡化合物是酒精脱氢酶的弱抑制剂。
Inorganic and organic tin compounds are weak inhibitors of alcohol dehydrogenase. (A183)
来源:Toxin and Toxin Target Database (T3DB)
毒理性
  • 致癌物分类
对人类不具有致癌性(未被国际癌症研究机构IARC列名)。
No indication of carcinogenicity to humans (not listed by IARC).
来源:Toxin and Toxin Target Database (T3DB)
毒理性
  • 健康影响
摄入大量无机锡化合物可能会导致腹痛、贫血以及肝脏和肾脏问题。
Ingestion of large amounts of inorganic tin compounds can cause stomachache, anemia, and liver and kidney problems. (L307, L308)
来源:Toxin and Toxin Target Database (T3DB)
毒理性
  • 暴露途径
口服(L308);吸入(L308);皮肤给药(L308)
Oral (L308) ; inhalation (L308) ; dermal (L308)
来源:Toxin and Toxin Target Database (T3DB)
毒理性
  • 症状
无机或有机锡化合物放置在皮肤上或进入眼睛中可能会引起皮肤和眼睛的刺激。
Inorganic or organic tin compounds placed on the skin or in the eyes can produce skin and eye irritation. (L308)
来源:Toxin and Toxin Target Database (T3DB)

安全信息

  • TSCA:
    Yes
  • 危险等级:
    8
  • 危险品标志:
    C
  • 安全说明:
    S26,S27,S36/37/39,S45
  • 危险类别码:
    R34
  • WGK Germany:
    3
  • 包装等级:
    III
  • 危险类别:
    8
  • 危险性防范说明:
    P280,P301+P312,P303+P361+P353,P304+P340,P305+P351+P338,P310
  • 危险品运输编号:
    3264
  • 危险性描述:
    H302,H314,H319

SDS

SDS:ad580c17d923c5062201e63304265478
查看
Name: Tin(II) tetrafluoroborate 50% solution Material Safety Data Sheet
Synonym:
CAS: 13814-97-6
Section 1 - Chemical Product MSDS Name:Tin(II) tetrafluoroborate 50% solution Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13814-97-6 Tin(II) tetrafluoroborate 50% 237-487-6
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13814-97-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: 4.5 - 6.5
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.670
Molecular Formula: B2F8Sn
Molecular Weight: 292.2972

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
High temperatures, incompatible materials.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Hydrogen fluoride gas, boron oxides.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13814-97-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tin(II) tetrafluoroborate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13814-97-6: No information available.
Canada
CAS# 13814-97-6 is listed on Canada's DSL List.
CAS# 13814-97-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13814-97-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A



制备方法与用途

化学性质
这是一种无色透明的液体,固体为白色。纯品略呈微碱性。

用途
主要用于电镀行业的铜丝高速镀锡、制备锡或锡合金电镀液等。

生产方法
采用金属锡氟硼酸法。首先将锡锭切割成小块,在电炉上加热至熔融状态,然后迅速倒入冷水中形成锡花,捞出后倒入反应器中,再加入氟硼酸并通入压缩空气(如Chemicalbook所示)使其充分反应。反应后的液体经过滤去除杂质,最终制得氟硼酸亚锡成品。其化学反应方程式如下: [ 2\text{Sn} + \text{O}_2 \rightarrow 2\text{SnOS} ] [ \text{SnO} + 2\text{HBF}_4 \rightarrow \text{Sn(BF}_4\text{)}_2 + \text{H}_2\text{O} ]

反应信息

  • 作为反应物:
    参考文献:
    名称:
    ILANGOVAN, R.;GOVINDARAJAN, G.;RAMAMURTHI, S.;PARTHASARADHY, N. V., TRANS. SAEST, 24,(1989) N, C. 181-185
    摘要:
    DOI:
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文献信息

  • RUF, ERICH
    作者:RUF, ERICH
    DOI:——
    日期:——
  • ILANGOVAN, R.;GOVINDARAJAN, G.;RAMAMURTHI, S.;PARTHASARADHY, N. V., TRANS. SAEST, 24,(1989) N, C. 181-185
    作者:ILANGOVAN, R.、GOVINDARAJAN, G.、RAMAMURTHI, S.、PARTHASARADHY, N. V.
    DOI:——
    日期:——
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