PROCESS FOR PRODUCING RESIN COMPOSITION WITH PARTIAL-DISCHARGE RESISTANCE, RESIN COMPOSITION WITH PARTIAL-DISCHARGE RESISTANCE, AND INSULATING MATERIAL WITH PARTIAL-DISCHARGE RESISTANCE
申请人:Kabushiki Kaisha Toshiba
公开号:EP2248855A1
公开(公告)日:2010-11-10
Fabricating a partial discharge resistant resin composite with an excellent partial discharge resistance with a small density, in a simplified manner. Using an ion exchange treatment for intercalating an organic compound between layers of a layer clay mineral thereby providing the layer clay mineral with a swellability to at least one of a polar solvent and a non-polar solvent, having the layer clay mineral as provided with a swellability swollen in a swelling solvent comprising the polar solvent or the non-polar solvent, followed by mixing an epoxy resin and kneading, making a removal of the swelling solvent from an obtained mixture including the swelling solvent, the layer clay mineral, and the epoxy resin, adding a hardener for epoxy resin to the mixture including the layer clay mineral and the epoxy resin, and mixing the mixture. In a partial discharge resistant insulation material comprising a hardened material of a partial discharge resistant resin composite thus fabricated, there is a network of molecular chains (1) of the epoxy resin constituting a cross-linked structure, with a system of inorganic nanoparticles (2) comprising the layer clay mineral and precisely and evenly dispersed therein.
以简化的方式制造出一种具有优异的抗局部放电性能且密度较小的抗局部放电树脂复合材料。使用离子交换处理,在层状粘土矿物的层间夹层有机化合物,从而使层状粘土矿物对极性溶剂和非极性溶剂中的至少一种溶剂具有溶胀性,使层状粘土矿物在由极性溶剂或非极性溶剂组成的溶胀溶剂中溶胀、然后混合环氧树脂并揉捏,从得到的混合物(包括膨胀溶剂、层状粘土矿物和环氧树脂)中去除膨胀溶剂,向混合物(包括层状粘土矿物和环氧树脂)中添加环氧树脂固化剂,并混合混合物。在由这样制成的耐局部放电树脂复合材料的硬化材料组成的耐局部放电绝缘材料中,环氧树脂的分子链网络(1)构成了交联结构,由层粘土矿物组成的无机纳米颗粒系统(2)精确而均匀地分散在其中。