cyanic fluoride hydrofluoride | 142482-00-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: cyanic fluoride hydrofluoride
• CAS: 142482-00-6
• 化学式: CFN*FH
• 分子量: 65.0224
• InChiKey: LLJJEHRICZGPKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.59
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.79
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  difluoromethanimine 反应 3.0h， 生成 cyanic fluoride hydrofluoride
  参考文献：
  名称：

  Fourier transform infrared spectra of the complexes XCN.cntdot..cntdot..cntdot.HF (X = F, CF3, SF5) isolated in an argon matrix

  摘要：

  Complexes of nitriles XCN (X = F, CF3, SF5) with HF (DF) isolated in an argon matrix have been studied by FTIR spectroscopy. The linear complexes XCN...HF were formed by mixing the components in the gas phase and condensing the mixtures on the matrix support. The frequencies of the stretching vibrations (nu(s)) of the HF (DF) submolecule were found to be 3662 (2694), 3733 (2742), and 3728 (2739) cm-1 for FCN, CF3CN, and SF5CN, respectively. This sequence correlates with the frequencies for the librational modes nu(l), being 554 (408), 493 (369), and 486 (358) cm-1. Photolysis of matrix-isolated CF2NH produced thc complex FCN...HF in a high yield enabling the measurement of the vibrational mode of thc hydrogen bond (nu(sigma)) at 171 cm-1. Furthermore, the complexes of ClCN, BrCN, and NCCN with HF (DF) have been reinvestigated.

  DOI：

  10.1021/j100193a026

文献信息

• Hunt, Rodney D.; Andrews, Lester, Inorganic Chemistry, 1987, vol. 26, # 18, p. 3051 - 3054
  作者：Hunt, Rodney D.、Andrews, Lester

  DOI：——

  日期：——
• Fourier transform infrared spectra of the complexes XCN.cntdot..cntdot..cntdot.HF (X = F, CF3, SF5) isolated in an argon matrix
  作者：Juergen Jacobs、Helge Willner、Gottfried Pawelke

  DOI：10.1021/j100193a026

  日期：1992.7

  Complexes of nitriles XCN (X = F, CF3, SF5) with HF (DF) isolated in an argon matrix have been studied by FTIR spectroscopy. The linear complexes XCN...HF were formed by mixing the components in the gas phase and condensing the mixtures on the matrix support. The frequencies of the stretching vibrations (nu(s)) of the HF (DF) submolecule were found to be 3662 (2694), 3733 (2742), and 3728 (2739) cm-1 for FCN, CF3CN, and SF5CN, respectively. This sequence correlates with the frequencies for the librational modes nu(l), being 554 (408), 493 (369), and 486 (358) cm-1. Photolysis of matrix-isolated CF2NH produced thc complex FCN...HF in a high yield enabling the measurement of the vibrational mode of thc hydrogen bond (nu(sigma)) at 171 cm-1. Furthermore, the complexes of ClCN, BrCN, and NCCN with HF (DF) have been reinvestigated.