cycloheptatrienecarbonitrile | 19052-79-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: cycloheptatrienecarbonitrile
• 英文别名: Cyanocycloheptatriene；cyclohepta-1,3,5-triene-1-carbonitrile
• CAS: 19052-79-0
• 化学式: C₈H₇N
• 分子量: 117.15
• InChiKey: XYQCLFLUKMPQKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  diazoacetonitrile 、 苯 生成 2,4,6-环庚三烯-1-甲腈 、 3-氰基环庚三烯 、 2-氰基环庚三烯 、 cycloheptatrienecarbonitrile
  参考文献：
  名称：

  Thermolysis and photolysis of 4-diazo-1,2,3-triazoles in benzenoid solvents, systems which reveal decomposition of diazo compounds to carbenes to diazo compounds to carbenes.

  摘要：

  DOI：

  10.1016/s0040-4039(00)85773-1

文献信息

• Process for synthesizing anhydroecgonine derivative
  申请人：——

  公开号：US20010020096A1

  公开（公告）日：2001-09-06

  The present invention relates to a process for synthesizing an anhydroecgonine derivative without using cocaine as a starting material, and a process for synthesizing a phenyltropane derivative by using said anhydroecgonine derivative as an intermediate for the synthesis. The present invention provides a process for synthesizing an anhydroecgonine derivative which comprises reacting a cycloheptatriene derivative represented by the formula (1): 1 with a primary amine, a salt thereof or ammonia in the presence of a base to obtain an anhydroecgonine derivative, and a process for synthesizing a phenyltropane derivative by using said anhydroecgonine derivative. In the formula (1), n is an integer of 0 or 1; and R 1 is a cyano group in the case of n being 0, and R 1 is selected from an alkyl group and an aralkyl group in the case of n being 1.

  本发明涉及一种无需使用可卡因作为起始物质合成一种无水异可卡因衍生物的方法，以及一种利用所述无水异可卡因衍生物作为合成中间体合成苯基曲马多衍生物的方法。本发明提供了一种合成无水异可卡因衍生物的方法，该方法包括在碱的存在下，将由式（1）表示的环庚三烯衍生物与一种主要胺、其盐或氨反应，以得到一种无水异可卡因衍生物；以及一种利用所述无水异可卡因衍生物合成苯基曲马多衍生物的方法。在式（1）中，n是0或1的整数；当n为0时，R1为氰基；当n为1时，R1选自烷基和芳基烷基。
• AN ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING A SUBSTRATE, AN ANODE LAYER AND A CATHODE LAYER, AT LEAST ONE LIGHT EMITTING LAYER, AND AT LEAST ONE SEMICONDUCTOR LAYER THAT COMPRISES AT LEAST ONE METAL COMPOUND OF A METAL AND AT LEAST ONE LIGAND
  申请人：Novaled GmbH

  公开号：EP4105201A1

  公开（公告）日：2022-12-21

  The present invention relates to an organic electroluminescent device comprising a substrate, an anode layer and a cathode layer, at least one light emitting layer, and at least one semiconductor layer or more, wherein the at least one semiconductor layer comprises at least one metal compound, wherein the metal compound comprises a metal M and at least one ligand L.

  本发明涉及一种有机电致发光器件，包括基板、阳极层和阴极层、至少一个发光层和至少一个或多个半导体层，其中至少一个半导体层包括至少一种金属化合物，金属化合物包括金属 M 和至少一种配体 L。
• US6596868B2
  申请人：——

  公开号：US6596868B2

  公开（公告）日：2003-07-22
• US6660863B2
  申请人：——

  公开号：US6660863B2

  公开（公告）日：2003-12-09