[3,7-二(二乙基氨基)吩恶嗪-10-基]-苯基甲酮 | 37060-36-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 中文名称: [3,7-二(二乙基氨基)吩恶嗪-10-基]-苯基甲酮
• 英文名称: 10-benzoyl-tetra-N-ethyl-10H-phenoxazine-3,7-diamine
• 英文别名: 10-benzoyl-N,N,N',N'-tetraethyl-10H-phenoxazine-3,7-diamine；10H-Phenoxazine-3,7-diamine, 10-benzoyl-N,N,N',N'-tetraethyl-；[3,7-bis(diethylamino)phenoxazin-10-yl]-phenylmethanone
• CAS: 37060-36-9
• 化学式: C₂₇H₃₁N₃O₂
• 分子量: 429.562
• InChiKey: RWPXSXGJVDDPFE-UHFFFAOYSA-N

物化性质

• 沸点：
  595.0±50.0 °C(Predicted)
• 密度：
  1.169±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  36
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2934999090

反应信息

• 作为反应物：
  描述：

  [3,7-二(二乙基氨基)吩恶嗪-10-基]-苯基甲酮 、 盐酸 生成 [7-(diethylazaniumyl)-10H-phenoxazin-10-ium-3-yl]-diethylazanium;trichloride
  参考文献：
  名称：

  VOGEL, KIM M.;MADER, ROGER A.

  摘要：

  DOI：
• 作为产物：
  描述：

  碱性蓝 3 在 sodium hydroxide 、 sodium dithionite 作用下， 以 sodium hydroxide 、 水 为溶剂， 生成 [3,7-二(二乙基氨基)吩恶嗪-10-基]-苯基甲酮
  参考文献：
  名称：

  Ayyangar, N. R.; Khanna, I. K., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1981, vol. 20, # 9, p. 763 - 766

  摘要：

  DOI：

文献信息

• NON-RESONANT TWO-PHOTON ABSORPTION RECORDING MATERIAL AND NON-RESONANT TWO-PHOTON ABSORPTION COMPOUND
  申请人：Takahashi Eri

  公开号：US20120319059A1

  公开（公告）日：2012-12-20

  A non-resonant two-photon absorption recording material containing at least (a) a non-resonant two-photon absorption compound, and (b) a recording component in which at least either a refractive index or fluorescence intensity changes, wherein the non-resonant two-photon absorption compound (a) is a compound having a structure represented by formula (1) as described.

  一种非共振双光子吸收记录材料，包含至少（a）非共振双光子吸收化合物，和（b）至少其中一个折射率或荧光强度发生变化的记录组分，其中非共振双光子吸收化合物（a）是具有由式（1）表示的结构的化合物。
• Record material
  申请人：The Wiggins Teape Group Limited

  公开号：EP0129380A1

  公开（公告）日：1984-12-27

  Record material of the type in which the colour forming reaction is between an electron donating chromogenic material and an electron accepting colour developer uses one or more oximes as the colour developer. Preferred oximes are monoximes, especially salicylaldoxime and its ring substituted derivatives, and dioximes such as dimethylglyoxime and mioxime.

  这种记录材料的成色反应是在供电子的成色材料和受电子的显色剂之间进行的，使用一 种或多种肟作为显色剂。 首选的肟是单肟，特别是水杨醛肟及其环取代衍生物，以及二氧肟，如二甲基乙二肟和二甲基丙二肟。
• New phthalide derivatives
  申请人：KANZAKI PAPER MANUFACTURING CO., LTD

  公开号：EP0188377A1

  公开（公告）日：1986-07-23

  A new phthalide derivative useful as a colorless chromogenic material has the following formula: wherein A is R is an alkyl group having 1 to 4 carbon atoms or a propylene group which may form jullolidine ring together with the adjacent benzene ring, and n is 0 or an integer of 1 to 4 when A is but m is an integer of 1 to 3 when A is

  一种可用作无色变色材料的新邻苯二甲酸酯衍生物具有下式： 其中 A 是 R 是具有 1 至 4 个碳原子的烷基或丙烯基，可与邻近的苯环一起形成鸦胆子环，当 A 是 R 时，n 是 0 或 1 至 4 的整数，但当 A 是 R 时，m 是 1 至 3 的整数。
• Phthalide derivatives and recording system utilizing the same
  申请人：KANZAKI PAPER MANUFACTURING CO., LTD

  公开号：EP0209259A2

  公开（公告）日：1987-01-21

  A new phthalide derivative useful as a colorless chromogenic material has the following formula: wherein R1, R2, R3, R4, R5 and R6 have the same meaning as defined hereinbefore

  一种可用作无色致色材料的新邻苯二甲酸酯衍生物具有下式： 其中 R1、R2、R3、R4、R5 和 R6 的含义与前文定义相同
• CHROMOGENIC COMPOSITION, PLANOGRAPHIC PRINTING ORIGINAL PLATE, METHOD FOR PRODUCING PLANOGRAPHIC PRINTING PLATE, AND CHROMOGENIC COMPOUND
  申请人：FUJIFILM Corporation

  公开号：EP3418332A1

  公开（公告）日：2018-12-26

  An object of the present invention is to provide a color developing composition which has excellent color developability and does not significantly discolor after aged using a color developing composition containing a compound represented by Formula (1) (in the formula, individual reference signs are as described in the specification) and a lithographic printing plate precursor containing the color developing composition in an image-recording layer. In addition, it is possible to provide a lithographic printing plate precursor which has excellent visibility by means of color development, is capable of maintaining excellent visibility even after aged, exhibits favorable on-machine developability, has excellent white light stability, and is also favorable in terms of printing resistance and tone reproducibility and a method for producing a lithographic printing plate in which the lithographic printing plate precursor is used. Furthermore, it is possible to provide a color developing compound which has excellent color developability and does not significantly discolor after aged. The compound represented by Formula 1 has at least one of groups represented by Formulae (2) to (4) (in the formula, individual reference signs are as described in the specification) as R4 or R5 or in R1, Ar1, or Ar2.

  本发明的目的是提供一种显色组合物，该组合物具有优异的显色性，并且使用含有式（1）表示的化合物的显色组合物（式中，各参考符号如说明书所述）和在图像记录层中含有该显色组合物的平版印刷板前体，在老化后不会明显褪色。此外，还可以提供一种平版印刷板前体，该前体通过显色具有优异的可见性，即使老化后也能保持优异的可见性，具有良好的机上显影性，具有优异的白光稳定性，在耐印刷性和色调再现性方面也很好，还可以提供一种使用该平版印刷板前体的平版印刷板的生产方法。此外，还可以提供一种显色性极佳且老化后不会明显褪色的显色化合物。 式 1 所代表的化合物至少有一个由式 (2) 至 (4) 所代表的基团（在式中，各个参考符号如说明书中所述）作为 R4 或 R5 或在 R1、Ar1 或 Ar2 中。