carbonic acid 1,6-hexanediyl ester | 4437-87-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: carbonic acid 1,6-hexanediyl ester
• 英文别名: carbonic acid hexamethylene ester；carbonic acid hexanediyl ester；1,6-hexamethylene carbonate；(1,6-hexylene) carbonate；1,3-dioxacyclononanone；hexamethylene-carbonat；hexamethylenecarbonate；hexylene carbonate；oxaoctanelactone；Hexylencarbonat；1,3-Dioxonan-2-one
• CAS: 4437-87-0
• 化学式: C₇H₁₂O₃
• 分子量: 144.17
• InChiKey: ANLVEXKNRYNLDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二氧化碳 、 氧化环己烯 在 六氟-2-(对甲苯基)异丙醇 、 四丁基溴化铵 作用下， 60.0 ℃ 、2.0 MPa 条件下， 反应 5.0h， 生成 carbonic acid 1,6-hexanediyl ester
  参考文献：
  名称：

  Organocatalytic promoted coupling of carbon dioxide with epoxides: a rational investigation of the cocatalytic activity of various hydrogen bond donors

  摘要：

  对一系列商业可获得的氢键供体（HBDs）进行理性研究，用于在温和条件下从CO₂和环氧化物合成环状碳酸酯的协催活性。

  DOI：

  10.1039/c5cy00891c

文献信息

• METHOD FOR PRODUCING CARBONATE COMPOUND
  申请人：Asahi Glass Company, Limited

  公开号：US20150284314A1

  公开（公告）日：2015-10-08

  The present invention relates to a production process capable of selectively producing various kinds of carbonate compounds without restraint in high yields without using toxic compounds such as phosgene and crown ethers, without producing corrosive gases such as hydrogen chloride as a by-product, and without necessity of removing the chloroform as a by-product by distillation, and to a method for producing a carbonate compound, containing reacting compound (1) with a compound having an OH group in the presence of a metal salt and 0.2 to 4.0 mol of compound (2) per mol of the metal salt to obtain a carbonate compound, in which m is an integer of 1-10, Q is an alkylene group having 1 to 4 carbon atoms, etc, and R 10 and R 11 are alkyl groups having 1 to 5 carbon atoms, etc.

  本发明涉及一种生产过程，能够在高产率下有选择地生产各种碳酸盐化合物，而不使用像光气和冠醚这样的有毒化合物，也不产生像氯化氢这样的腐蚀性气体作为副产品，也不需要通过蒸馏去除氯仿作为副产品，以及一种制备碳酸盐化合物的方法，其中包括在金属盐和化合物（1）的存在下，将化合物（1）与具有羟基的化合物反应，每摩尔金属盐添加0.2到4.0摩尔的化合物（2），以获得碳酸盐化合物，其中m是1-10的整数，Q是具有1到4个碳原子的烷基基团，R10和R11是具有1到5个碳原子的烷基基团等。
• [EN] CARBONATE-LINKED SURFACE MODIFYING MACROMOLECULES<br/>[FR] MACROMOLÉCULES MODIFICATRICES DE SURFACE À LIAISON CARBONATE
  申请人：INTERFACE BIOLOGICS INC

  公开号：WO2019169500A1

  公开（公告）日：2019-09-12

  The invention relates to carbonate-linked surface modifying macromolecules and admixtures thereof. The macromolecules comprise surface active polyfluoroorgano groups, polyalkylene oxide groups and a soft segment. The groups and segments are joined through carbonate linkages. The admixtures can be used in industrial and medical applications where enhanced surface properties are desirable (e.g. surface properties reducing or preventing biofouling, immobilization of biomolecules, or denaturation of certain biomolecules).

  本发明涉及碳酸酯连接表面改性大分子及其混合物。该大分子包括表面活性聚氟有机基团、聚烷基氧基团和软段。这些基团和段通过碳酸酯键连接。混合物可用于需要增强表面性能的工业和医疗应用中（例如，减少或防止生物污垢的表面性能、生物分子的固定化或某些生物分子的变性）。
• [EN] HEXAARYLBIIMIDAZOLE COMPOUNDS AND PHOTOPOLYMERIZATION INITIATOR COMPOSITIONS CONTAINING THE SAME<br/>[FR] COMPOSES A BASE D'HEXAARYL-BIIMIDAZOLE, ET COMPOSITIONS INITIATRICES DE PHOTOPOLYMERISATION CONTENANT CE COMPOSE
  申请人：SHOWA DENKO KK

  公开号：WO2004035546A1

  公开（公告）日：2004-04-29

  The present invention provides a novel hexaarylbiimidazole compound of the following formula (1): wherein each R1 represents a halogen, and each R2 represents an optionally substituted C1-4 alkyl group. The hexaarylbiimidazole compound of the present invention is useful as photoradical generators in photopolymerizable compositions used as resists and is characterized by low sublimating thermal decomposition products. The photopolymerizable compositions may be suitably used as resists or as color filters for color liquid crystal display elements, cameras and the like.

  本发明提供了一种新型的六芳基联双咪唑化合物，其化学式为（1），其中每个R1代表卤素，每个R2代表可选取代的C1-4烷基基团。本发明的六芳基联双咪唑化合物可用作光致自由基发生剂，用于光聚合组合物中作为抗蚀剂，并具有低升华热分解产物的特点。光聚合组合物可适当地用作抗蚀剂或彩色液晶显示元件、相机等的彩色滤光片。
• [EN] CYCLIC KETONE PEROXIDE FORMULATIONS<br/>[FR] FORMULATIONS DE PEROXYDES DE CETONES CYCLIQUES
  申请人：AKZO NOBEL NV

  公开号：WO2004052877A1

  公开（公告）日：2004-06-24

  The present invention relates to a cyclic ketone peroxide formulation comprising one or more crystallizing cyclic ketone peroxides, one or more co-crystallizing compounds which solidify in said cyclic ketone peroxide formulation at a temperature above the crystallization temperature of the crystallizing cyclic ketone peroxide, and, optionally, one or more conventional phlegmatizers (diluents). These formulations show improved safety and storage stability compared to conventional cyclic ketone peroxide formulations. The invention also pertains to the use of these formulations in (co)polymerization and (co)polymer modification processes.

  本发明涉及一种环状酮过氧化物配方，包括一个或多个结晶的环状酮过氧化物、一个或多个共结晶化合物，它们在高于结晶温度的温度下在所述环状酮过氧化物配方中固化，并且，可选地，一个或多个传统的稀释剂（稀释剂）。与传统的环状酮过氧化物配方相比，这些配方表现出更好的安全性和储存稳定性。本发明还涉及在（共）聚合和（共）聚合改性过程中使用这些配方的用途。
• Color filter black matrix resist composition and carbon black dispersion composition used for the composition
  申请人：Kamata Hirotoshi

  公开号：US20060041053A1

  公开（公告）日：2006-02-23

  The present invention provides a carbon black dispersion composition for a color filter black matrix resist composition, containing (A) a carbon black having specified physical properties (average primary particle diameter, concentration of surface carboxyl groups), (B) a copolymer having an amino group and/or its quaternary ammonium salt, and (C) an organic solvent, and a color filter black matrix resist composition that contains the above-mentioned dispersion composition, (D) a binder resin having a carboxyl group, (E) an ethylenically unsaturated monomer, (F) a photopolymerization initiator, and (G) specified multifunctional thiol compound and can easily form a thin film or pattern having high light-shielding property by photolithographic method pattern, has excellent storage stability, and exhibits sufficient sensitivity and resolution.

  本发明提供一种用于彩色滤光片黑色基体抗蚀剂组合物的碳黑分散组合物，包含（A）具有特定物理特性的碳黑（平均一次粒径，表面羧基浓度），（B）具有氨基和/或其季铵盐的共聚物，和（C）有机溶剂，并且包含上述分散组合物的彩色滤光片黑色基体抗蚀剂组合物，（D）具有羧基的粘合剂树脂，（E）乙烯基不饱和单体，（F）光聚合引发剂和（G）指定的多功能硫醇化合物，可以通过光刻法形成具有高遮光性的薄膜或图案，具有优异的储存稳定性，并展现出足够的敏感度和分辨率。