申请人:Sugahara Yoshiyuki
公开号:US20090036687A1
公开(公告)日:2009-02-05
A multinuclear complex comprising a plurality of metal atoms and a ligand L coordinating to the metal atoms, and satisfying the following conditions (i), (ii), (iii) and (iv):
(i) The ligand L has a monovalent group represented by the following general formula (1) and/or a divalent group represented by the following general formula (2),
(ii) The ligand L has at least 5 coordination atoms bonding to the metal atom,
(iii) At least one of the coordination atoms bonds to two of the metal atoms, or the minimum number of covalent bonds between any two selected coordination atoms is 1-5, and
(iv) The ligand L is soluble in the solvent.
由多个金属原子和配位到金属原子的配体L组成的多核复合物,满足以下条件(i)、(ii)、(iii)和(iv):(i)配体L具有以下通式(1)表示的一价基团和/或以下通式(2)表示的二价基团,(ii)配体L至少有5个配位原子与金属原子配位,(iii)至少有一个配位原子与两个金属原子配位,或任选两个配位原子之间的最小共价键数为1-5,(iv)配体L在溶剂中可溶。