申请人:Goldfinger B. Marc
公开号:US20070267599A1
公开(公告)日:2007-11-22
The invention relates to compounds of formula (I):
wherein R
1
and R
2
are each independently selected from the group: H, F, Cl and CH
3
; n1 and n2 are each independently integers 3 to 20; q and r are each independently integers 0, 1 or 2, with the proviso that q+r is ≧1; D is a divalent chiral radical selected from the group:
wherein R
3
is a C1 to C6 straight or branched chain alkyl group; and each B
1
and B
2
is a divalent radical independently selected from the group: R
4
-substituted-1,4-phenyl, wherein R
4
is H, —CH
3
or —OCH
3
; 2,6-naphthyl; and 4,4′-biphenyl; with the provisos that when q+r=3, at least one of B
1
and B
2
is R
4
-substituted-1,4-phenyl; and when q+r=4, at least two of B
1
and B
2
are R
4
-substituted-1,4-phenyl. The invention further relates to liquid crystal compositions comprising compounds of formula (I) and polymer networks derived from the polymerization of the liquid crystal compositions.
本发明涉及化合物的公式(I):其中,R1和R2各自独立地选自组:H、F、Cl和CH3;n1和n2各自独立地为整数3至20;q和r各自独立地为整数0、1或2,但须满足q+r≧1;D是从组中选择的二价手性基团:其中,R3是C1至C6直链或支链烷基;每个B1和B2是从组中独立选择的二价基团:R4-取代-1,4-苯基,其中R4为H、—CH3或—OCH3;2,6-萘基;和4,4'-联苯基;但须满足当q+r=3时,至少一个B1和B2是R4-取代-1,4-苯基;当q+r=4时,至少两个B1和B2是R4-取代-1,4-苯基。本发明还涉及包含公式(I)化合物的液晶组合物和由液晶组合物聚合得到的聚合物网络。