1-butyl-3-methylimidazolium heptafluorobutanoate | 174899-99-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1-butyl-3-methylimidazolium heptafluorobutanoate
• 英文别名: 1-butyl-3-methylimidazol-3-ium;2,2,3,3,4,4,4-heptafluorobutanoate
• CAS: 174899-99-1
• 化学式: C₄F₇O₂*C₈H₁₅N₂
• 分子量: 352.252
• InChiKey: MDJAMFZRTDMREK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.68
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  48.9
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  trans-bis(triphenylphosphine)palladium dichloride 、 1-butyl-3-methylimidazolium heptafluorobutanoate 以 四氢呋喃 、 甲醇 为溶剂， 生成
  参考文献：
  名称：

  具有各种阴离子的咪唑鎓盐作为电荷载体，用于在电喷雾电离质谱法中检测中性双（三苯基膦）钯（II）二氯化物。

  摘要：

  理由尽管电喷雾电离是用于质量分析的一种流行技术，但是如果没有带电物质，它是无效的。再加上溶剂的限制，阻碍了有机金属配合物的分析。检测其溶解度仅限于非常规溶剂的中性物质是可以通过使用正确的电荷载体克服的问题，本研究对此进行了描述。方法通过电喷雾电离四极杆离子阱质谱法合成和分析离子液体。还使用相同的方法和仪器，使用不同的咪唑鎓盐作为电荷载体，分析了中性钯配合物。还使用高斯09在密度泛函理论水平上进行了理论补充，使用B3LYP泛函和用于几何优化的6-31 g（d，p）基础集。结果甲醇中的低浓度咪唑鎓盐表现出离子液体的聚集行为，其中以正模式观察到阳离子峰和[阳离子]（n + 1）[阴离子] n峰，而[阳离子] n [阴离子]（n +1）峰以负模出现。在THF中，除了与SCN阴离子形成的盐以外，在所有的负模光谱中均观察到未结合的阴离子。PdCl2（PPh3）2和少量离子液体在THF中的溶液显示，每种

  DOI：

  10.1002/rcm.6653

文献信息

• Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet and surface protecting film
  申请人：NITTO DENKO CORPORATION

  公开号：EP1602698A1

  公开（公告）日：2005-12-07

  The present invention provides a pressure-sensitive adhesive which can prevent electrification of a non-electrification-prevented adherend upon peeling, suppresses occurrence of peeling off even with time or via treatment under a high temperature, and is excellent in adhesion reliance, as well as an antistatic pressure-sensitive adhesive sheet, and surface protecting film using this. The pressure-sensitive adhesive composition of the present invention contains an ionic liquid, and a polymer having a glass transition temperature of Tg of 0°C or lower as a base polymer, as well as an ethylene oxide group-containing compound and/or a surfactant.

  本发明提供了一种在剥离时可防止非防静电粘合剂带电，即使经过一段时间或高温处理也可抑制剥离的发生，且粘合可靠性极佳的压敏粘合剂，以及使用该压敏粘合剂的防静电压敏胶片和表面保护膜。本发明的压敏胶组合物含有离子液体、玻璃化温度 Tg 为 0°C 或更低的聚合物作为基体聚合物，以及含环氧乙烷基团的化合物和/或表面活性剂。
• Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets, and surface protecting film
  申请人：NITTO DENKO CORPORATION

  公开号：EP1621596A2

  公开（公告）日：2006-02-01

  An object of the present invention is to provide a pressure-sensitive adhesive composition which is excellent in antistatic property of a non-electrification-prevented adherend (subject to be protected) upon peeling, and has reduced stainability in an adherend and is excellent in adhesion reliance, and electrification preventing pressure-sensitive adhesive sheets using the same. There is provided a pressure-sensitive composition comprising an ionic liquid, and a (meth)acryl-based polymer containing, as a monomer component, 0.1 to 100% by weight of a (meth)acrylic acid alkylene oxide. In addition, there is provided a pressure-sensitive composition comprising an ionic liquid, and a polymer containing, as a monomer component, 0.5 to 30 % by weight of a nitrogen-containing monomer and having a glass transition temperature Tg of no higher than 0°C. Furthermore, there is provided a pressure-sensitive composition comprising an ionic liquid, and a (meth)acryl-based polymer containing, as a monomer component, 0.01 to 20% by weight of a reactive surfactant.

  本发明的目的是提供一种压敏粘合剂组合物，该组合物在剥离非防触电被粘物（被保护对象）时具有优异的抗静电性能，并降低了被粘物的可沾污性，具有优异的粘附可靠性，以及使用该组合物的防触电压敏粘合片。提供了一种压敏组合物，该组合物由离子液体和(甲基)丙烯酸基聚合物组成，其中(甲基)丙烯酸基聚合物含有 0.1 至 100%（按重量计）的(甲基)丙烯酸氧化烯。此外，还提供了一种压敏组合物，该组合物包含一种离子液体，以及一种聚合物，该聚合物作为单体成分，含有 0.5%至 30%（按重量计）的含氮单体，其玻璃化转变温度 Tg 不高于 0°C。此外，还提供了一种压敏组合物，该组合物包含一种离子液体和一种（甲基）丙烯酰基聚合物，该聚合物的单体成分中含有 0.01% 至 20% （重量百分比）的活性表面活性剂。
• Pressure-sensitive adhesive compositions, pressure-sensitive adhesive sheets, and double-sided pressure-sensitive adhesive tapes
  申请人：NITTO DENKO CORPORATION

  公开号：EP1693430A2

  公开（公告）日：2006-08-23

  An object of the present invention is to provide a pressure-sensitive adhesive composition which is excellent in antistatic property of a pressure-sensitive adhesive tapes when separators are peeled off, and has reduced stainability in an adherend, and excellent in transparency, and prevention of occurrence of peeling off and separation, and an antistatic pressure-sensitive adhesive sheet and a double-sided pressure-sensitive adhesive tape using the same. There is provided a pressure-sensitive composition comprising an ionic liquid, a (meth)acryl-based oligomer of weight-average molecular weight of 1,000 to 50,000, and a (meth)acryl-based polymer of glass transition temperature (Tg) of 0°C or less as base polymer.

  本发明的目的是提供一种压敏胶组合物，该组合物在压敏胶带的分隔物剥离时抗静电性能优异，在被粘物中的沾污性降低，透明度优异，可防止剥离和分隔现象的发生，并提供使用该组合物的抗静电压敏胶片和双面压敏胶带。提供了一种压敏组合物，该组合物由离子液体、重量平均分子量为 1,000 至 50,000 的（甲基）丙烯酰基低聚物和玻璃化转变温度（Tg）为 0°C 或以下的（甲基）丙烯酰基聚合物作为基础聚合物组成。
• Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets and surface protecting film
  申请人：NITTO DENKO CORPORATION

  公开号：EP1889889A2

  公开（公告）日：2008-02-20

  The present invention provides a pressure-sensitive composition comprising an ionic liquid and a polymer having a glass transition temperature Tg of 0°C or lower as a base polymer as a pressure-sensitive adhesive composition in which electrification of a pressure-sensitive adhesive sheet can be prevented upon peeling, and staining property on an adherend can be reduced, and an antistatic pressure-sensitive sheet and surface protecting film using the pressure-sensitive adhesive composition.

  本发明提供了一种压敏胶组合物，该组合物由离子液体和玻璃化转变温度 Tg 为 0°C 或更低的聚合物作为基础聚合物组成，作为压敏胶组合物，可以防止压敏胶片在剥离时发生电化，并减少粘附物上的沾污特性，还提供了使用该压敏胶组合物的抗静电压敏胶片和表面保护膜。
• ADHESIVE COMPOSITION, ADHESIVE SHEET, AND SURFACE PROTECTIVE FILM
  申请人：NITTO DENKO CORPORATION

  公开号：EP1939263A1

  公开（公告）日：2008-07-02

  Disclosed is a pressure sensitive adhesive composition characterized by containing an ionic liquid and a polymer which contains, as a monomer unit, 0.1-10% by weight of a (meth)acrylate with a hydroxyalkyl group having 3-12 carbon atoms. The present invention provides a pressure sensitive adhesive composition which is excellent in antistatic property of a no-electrification-prevented adherend upon peeling, and has reduced staining of an adherend and is excellent in adhesion reliance. Also disclosed is an antistatic pressure sensitive adhesive sheet or surface-protecting film prepared using the composition. Also disclosed is an antistatic pressure sensitive adhesive sheet or surface-protecting film prepared using the composition.

  本发明公开了一种压敏型粘合剂组合物，其特征在于含有离子液体和聚合物，其中聚合物的单体单元含有重量百分比为 0.1-10%的具有 3-12 个碳原子的羟基烷基的（甲基）丙烯酸酯。本发明提供了一种压敏型粘合剂组合物，它在剥离时可防止被粘物的无电化，抗静电性能优异，并可减少被粘物的沾污，粘附性极佳。还公开了一种使用该组合物制备的抗静电压敏胶片或表面保护膜。还公开了一种使用该组合物制备的抗静电压敏胶片或表面保护膜。