2-trimethylsilylethane phosphonic acid | 18135-12-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: 2-trimethylsilylethane phosphonic acid
• 英文别名: 2-Trimethylsilylethylphosphonic acid
• CAS: 18135-12-1
• 化学式: C₅H₁₅O₃PSi
• 分子量: 182.232
• InChiKey: TWYZOTWUURULIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  57.5
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-Trimethylsilyl-aethan-phosphonsaeure-(1)-dibutylester 在 盐酸 作用下， 生成 2-trimethylsilylethane phosphonic acid
  参考文献：
  名称：

  Synthesis and Hydrolytic Stability of Some Organosilicon Phosphonate Esters

  摘要：

  DOI：

  10.1021/jo01077a030

文献信息

• Radical Additions of Bis(trimethylsilyl)phosphite to Vinyltimethylsilane and Vinyltriethoxysilane: Crystal Structure of 2-Trimethylsilylethane-phosphonic Acid
  作者：Amir H. Mahmoudkhani、Vratislav Langer、Oliver Lindqvist

  DOI：10.1080/713744570

  日期：2003.10.1

  Organosilicon-phosphonate compounds with the general formula (R)(n)(RO)(3)-Si-n(CH2)(m)P(O)(OSiR'(3))(2) are designed for application as novel materials for surface treatments and modifications. A solvothermal method based on the reaction of bis(trimethylsilyl)phosphite with vinyltrimethylsilane and vinyltriethoxysilane in the presence of a peroxide in benzene solvent was used to synthesize the silyl-substituted esters of organosilicon-phosphonate compounds. 2-Trimethylsilylethanephosphonic acid was prepared from its bis(trimethylsilyl) ester by alcoholysis. The crystal structure of the acid consists of two-dimensional arrays built up from the (P-)O-H...O-P hydrogen bonds.
• Haegele, Gerhard; Boenigk, Winfried; Dickopp, Heinz, Phosphorus and Sulfur and the Related Elements, 1986, vol. 26, p. 253 - 256
  作者：Haegele, Gerhard、Boenigk, Winfried、Dickopp, Heinz、Wendisch, Detlef

  DOI：——

  日期：——
• Synthesis and Hydrolytic Stability of Some Organosilicon Phosphonate Esters
  作者：GARRETT H. BARNES、MARY P. DAVID

  DOI：10.1021/jo01077a030

  日期：1960.7