| 78899-79-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 78899-79-3
• 化学式: C14H22NaO
• 分子量: 229.31
• InChiKey: RYQYPDKUNORTPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.91
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Textile materials, methods of manufacture and compositions for use therein
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0241127A2

  公开（公告）日：1987-10-14

  Textile materials having improved physical properties comprise woven and/or non-woven fiber assemblies, the fibers of which are bound to a polymer composition containing polymerized carboxylic acid ester monomers and pendant functional groups attached to a polymer backbone and having the formula: in which R1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano. Such polymers markedly increase wet and dry strengths and shape retention of textile materials, and they improve other physical properties without the necessity of employing formaldehyde-releasing monomers, such as the N-methylolamides, or cross-linking agents. Methods for producing such textile materials by applying solutions or dispersions of the described polymers to fiber assemblies are also provided. Aqueous dispersions of these polymers are particularly useful forthe manufacture of loose-weaves, knits and non-wovens.

  具有更好物理性能的纺织材料包括机织和/或无纺布纤维组件，其纤维与聚合物组合物结合，该聚合物组合物含有聚合羧酸酯单体和连接到聚合物主干上的悬垂官能团，其结构式如下： 其中 R1 是长度至少为 3 个原子的二价有机基，X 是有机酰基或氰基。这种聚合物能显著提高纺织材料的干湿强度和形状保持力，并能改善其他物理性能，而无需使用释放甲醛的单体（如 N-甲基酰胺）或交联剂。此外，还提供了通过将所述聚合物的溶液或分散体应用于纤维组件来生产此类纺织材料的方法。这些聚合物的水性分散体尤其适用于生产松织、针织和无纺布。
• Pressure sensitive adhesives and manufactured articles
  申请人：UNION OIL COMPANY OF CALIFORNIA

  公开号：EP0244997A2

  公开（公告）日：1987-11-11

  Normally tacky, pressure sensitive adhesive compositions comprise one or more polymers having a Tg of about 0° C. or less containing at least about 40 weight percent polymerized, olefinically unsaturated carboxylic acid esters monomers and pendant functional groups attached to a polymer backbone and having the formula: in which R₁ is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano. Such polymers have markedly improved cohesive strength (shear holding value) with little or no detriment to adhesive tack or adhesion (peel resistance), and these improvements are realized without the necessity of incorporating cross-linking monomers such as N-methylol­amides or other cross-linking agents. Pressure sensitive adhesives, water-based emulsions containing such polymers and adhesive articles having at least a portion of one surface thereof coated with such adhesive are also provided.

  通常具有粘性的压敏粘合剂组合物由一种或多种聚合物组成，其 Tg 约为 0°C 或更低，含有至少约 40 重量百分比的聚合烯烃不饱和羧酸酯单体和连接到聚合物骨架上的悬挂官能团，并具有以下式子： 其中 R₁ 是长度至少为 3 个原子的二价有机基，X 是有机酰基或氰基。这种聚合物的内聚强度（剪切保持值）显著提高，而对粘合剂的粘性或附着力（抗剥离性）几乎没有影响，而且无需加入交联单体（如 N-甲基酰胺或其他交联剂）即可实现这些改进。此外，还提供了压敏型粘合剂、含有此类聚合物的水基乳液以及至少有一部分表面涂有此类粘合剂的粘合物品。
• Mastic and caulking compositions and composite articles
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0258988A2

  公开（公告）日：1988-03-09

  Permanently flexible and non-tacky coating mastic and caulking compositions contain one or more polymers having a Tg of about -50° C. to about -10° C. and pendant functional groups attached to the polymer backbone of the formula: in which R1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano. The mastics and caulks typically have total non-volatile matter concentrations of about 60 to about 90 weight percent of which about 15 to about 75 weight percent comprises the described polymers and about 25 to about 85 weight percent is non-volatile solid matter other than the polymer such as pigments, fillers, etc. The liquid portion of the mastics and caulks may be a polymer solvent, aqueous polymer dispersant, or other material, and the cured compositions exhibit exceptionally good adhesion to architectural structural materials, such as foamed polyurethane roof insulation and smooth surfaced elastomers and plastics.

  永久柔韧且不粘腻的涂料胶泥和填缝剂组合物含有一种或多种聚合物，其 Tg 约为 -50°C 至约 -10°C ，并含有连接到聚合物主链上的如下式所示的悬挂官能团： 其中 R1 是长度至少为 3 个原子的二价有机基，X 是有机酰基或氰基。胶粘剂和填缝剂的非挥发性物质总浓度通常约为 60% 至 90%，其中约 15% 至 75% 为所述聚合物，约 25% 至 85% 为聚合物以外的非挥发性固体物质，如颜料、填料等。胶粘剂和填缝剂的液体部分可以是聚合物溶剂、水性聚合物分散剂或其他材料，固化后的组合物与建筑结构材料（如发泡聚氨酯屋顶隔热材料和表面光滑的弹性体和塑料）的粘附性特别好。
• Pressure sensitive adhesives and adhesive articles
  申请人：UNION OIL COMPANY OF CALIFORNIA

  公开号：EP0296286A1

  公开（公告）日：1988-12-28

  Normally tacky, pressure sensitive adhesive compositions comprise one or more polymers containing pendant functional groups attached to a polymer backbone and having the formula: in which R, is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano, and wherein said polymer is selected from (1) conjugated diolefin polymers comprising at least about 30 weight percent of one or more conjugated diene monomers having 4 to about 8 carbon atoms and 0 to about 70 weight percent of one or more alkenyl-substituted monoaromatic monomers, (2) olefin ester interpolymers comprising at least about 1 weight percent of a monoolefin monomer having up to about 4 carbon atoms and at least about 40 weight percent of an alkenyl or alkenol ester of a saturated carboxylic acid, (3) olefinically unsaturated carboxylic acid ester polymers comprising at least about 40 weight percent polymerized olefinically unsaturated carboxytic acid ester monomers, (4) alkenyl ether polymers comprising at least about 30 weight percent alkenyl ether monomer units, and (5) combinations thereof. Such polymers have improved cohesive strength with little or no detriment to adhesive tack or adhesion, and these improvements are realized without the necessity of incorporating crosslinking monomers such as N-methylolamides or other crosslinking agents. Pressure sensitive adhesive, water-based emulsions, hot melts and solutions containing such polymers and adhesive articles having at least a portion of one surface thereof coated with such adhesives are also provided.

  通常具有粘性的压敏粘合剂组合物由一种或多种聚合物组成，这些聚合物含有连接到聚合物主链上的挂接官能团，其结构式如下： 其中 R 是长度至少为 3 个原子的二价有机基，X 是有机酰基或氰基，且所述聚合物选自以下各项 (1) 共轭二烯烃聚合物，包含至少约 30 重量百分比的一种或多种具有 4 至约 8 个碳原子的共轭二烯单体和 0 至约 70 重量百分比的一种或多种烯基取代的单芳香族单体、 (2) 烯烃酯间聚合物，包括至少约 1 重量百分比的具有最多约 4 个碳原子的单烯烃单体和至少约 40 重量百分比的饱和羧酸的烯基或烯醇酯、 (3) 烯烃不饱和羧酸酯聚合物，包括至少约 40%重量百分比的聚合烯烃不饱和羧酸酯单体、 (4) 烯基醚聚合物，包括至少约 30%重量百分比的烯基醚单体单元，以及 (5) 它们的组合。 此类聚合物具有更高的内聚强度，对粘合剂的粘性或附着力几乎没有损害，而且无需加入交联单体（如 N-甲基酰胺或其他交联剂）即可实现这些改进。此外，还提供了含有此类聚合物的压敏粘合剂、水基乳液、热熔胶和溶液，以及至少有一部分表面涂有此类粘合剂的粘合物品。
• Extended polymer compositions and textile materials manufactured therewith
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0357287A1

  公开（公告）日：1990-03-07

  Extended polymer compositions are provided which comprise polymers containing pendant functional groups of the formula: extended, i.e. admixed with, a chalcogenide having the empirical formula wherein R1 is a divalent organic radical at least 3 atoms in length, X is organoacyl or cyano, A is a chalcogen, each of R9 and R10 is independently selected from hydrogen, NR11R12, NR13 and monovalent organic radicals, at least one of Rg and R10 being NR11R12 or NR13, each of R11 and R12 is independently selected from hydrogen and monovalent organic radicals, and R13 is a divalent organic radical. These compositions can be extended with significant proportions of the described chalcogenides with corresponding reductions in polymer concentration without significant loss of physical properties. The resulting combinations are particularly useful as binders and coatings.

  本发明提供了扩展聚合物组合物，该组合物包括含有式......的悬垂官能团的聚合物： 扩展的，即与具有经验式的卤化铝混合的聚合物 其中 R1 是长度至少为 3 个原子的二价有机基，X 是有机酰基或氰基，A 是卤代烃，R9 和 R10 各自独立选自氢、NR11R12、NR13 和一价有机基，Rg 和 R10 中至少有一个是 NR11R12 或 NR13，R11 和 R12 各自独立选自氢和一价有机基，R13 是二价有机基。这些组合物可以在不明显降低物理性质的情况下，使用相当比例的所述卤化铝，并相应降低聚合物浓度。由此产生的组合物特别适合用作粘合剂和涂料。