[4-[N-(3,4-dimethylphenyl)-4-(hydroxymethyl)anilino]phenyl]methanol | 677032-83-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [4-[N-(3,4-dimethylphenyl)-4-(hydroxymethyl)anilino]phenyl]methanol
• CAS: 677032-83-6
• 化学式: C₂₂H₂₃NO₂
• 分子量: 333.43
• InChiKey: OOIJEAZXYHOVCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  43.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4,4a(2)-[(3,4-Dimethylphenyl)imino]bis[benzaldehyde] 在 sodium hydroxide 、 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以82%的产率得到[4-[N-(3,4-dimethylphenyl)-4-(hydroxymethyl)anilino]phenyl]methanol
  参考文献：
  名称：

  PROCESS FOR THE SYNTHESIS OF HYDROXYL ARYLAMINES

  摘要：

  形成羟基三芳胺化合物的过程包括将卤代芳基醛与醛保护剂反应以形成卤代保护芳基醛化合物，然后在适当催化剂的存在下将卤代保护芳基醛化合物与胺反应，最后还原得到的醛三芳胺以形成羟基三芳胺。

  公开号：

  US20090131720A1

文献信息

• Arylamine compound, charge transport material, electrophotographic photoreceptor, image forming apparatus, and process cartridge
  申请人：Iwasaki Masahiro

  公开号：US20070148571A1

  公开（公告）日：2007-06-28

  An arylamine compound represented by formula (I). Ar 1 represents a phenyl group substituted by a substituted or unsubstituted monovalent polycyclic aromatic hydrocarbon group, and a substituted or unsubstituted monovalent heterocyclic group. Ar 2 represents a substituted or unsubstituted arylene group. R 1 represents a hydrogen atom, a halogen atom, an alkoxy group, or a substituted or unsubstituted alkyl group. R 2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group. R 3 and R 4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, at least one of R 3 and R 4 represents a substituted or unsubstituted aryl group, and R 3 and R 4 may be bound to form a ring via a single bond or a divalent group m represents an integral of from 0 to 4.

  由公式(I)表示的芳胺化合物。Ar1代表一个被取代或未取代的多环芳香烃基团和一个取代或未取代的杂环基团取代的苯基团，Ar2代表一个取代或未取代的芳基团。R1代表氢原子、卤素原子、烷氧基或取代或未取代的烷基团。R2代表氢原子、取代或未取代的烷基团或取代或未取代的芳基团。R3和R4各自独立地代表氢原子、取代或未取代的烷基团或取代或未取代的芳基团，R3和R4中至少一个代表取代或未取代的芳基团，R3和R4可以通过单键或双价基团结合形成环。m的值为0到4的整数。
• Silane-phenol compound, overcoat formulation, and electrophotographic imaging member
  申请人：Qi Yu

  公开号：US20070020540A1

  公开（公告）日：2007-01-25

  Provided are a silane-phenol compound, a crosslinked silxoane-phenolic protective overcoat layer thereof, and an electrophotographic imaging member such as photoreceptor. The silane-phenol compound comprises (i) a phenol group and (ii) a silane group selected from the group consisting of alkoxysilyl, arylalkoxysilyl, aryloxysilyl, alkylaryloxysilyl, and combination thereof. The silicone overcoat is made from a formulation comprising the silane-phenol compound and a hydroxymethylated hole transport compound. The crosslinked siloxane-phenolic overcoat may be used to manufacture an electrophotographic imaging member such as photoreceptor with improved properties such as abrasive resistance, good image quality and cleanability, etc.

  提供了一种硅烷-酚化合物，其交联的硅氧烷-酚保护面层，以及一种电子照相成像元件，例如光感受器。硅烷-酚化合物包括（i）苯酚基和（ii）从羟基烷氧基硅烷，芳基烷氧基硅烷，芳氧基硅烷，烷基芳氧基硅烷和其组合中选择的硅烷基。硅氧烷面层由包含硅烷-酚化合物和羟甲基化的空穴传输化合物的配方制成。交联的硅氧烷-酚保护面层可用于制造电子照相成像元件，如光感受器，具有改善的性能，如耐磨性，良好的图像质量和易于清洁等。
• Phenolic hole transport polymers
  申请人：Xerox Corporation

  公开号：EP1775637A1

  公开（公告）日：2007-04-18

  A polymer having hole transport functionality and antioxidant properties is disclosed. The polymer comprises a phenolic segment and a hole transport segment. The polymer is suitable for use in the charge transport layer of an imaging member. Processes for producing the polymer are also disclosed.

  本发明公开了一种具有空穴传输功能和抗氧化特性的聚合物。该聚合物由酚醛段和空穴传输段组成。该聚合物适用于成像元件的电荷传输层。此外，还公开了生产该聚合物的工艺。
• Photoconductive members, crosslinked phenol resin, an overcoat coating composition, a process for production
  申请人：Xerox Corporation

  公开号：EP1775638A1

  公开（公告）日：2007-04-18

  A photoconductive imaging member including at least a charge generating layer, a charge transport layer, and an overcoat layer. The overcoat layer includes a cured or substantially crosslinked product of at least a phenol compound and a charge transport compound. The charge transport compound is represented by:          A-(L-OR)n wherein A represents a charge transport component, L represents a linkage group, R represents a hydrocarbyl group, and n represents a number of repeating segments or groups. Preferably the charge transport component is a tertiary arylamine, pyrazoline, hydrazone, oxadiazole or stilbene.

  一种光电导成像部件，至少包括电荷产生层、电荷传输层和包覆层。包覆层包括至少一种苯酚化合物和一种电荷传输化合物的固化或基本交联产物。电荷传输化合物的代表物是 A-(L-OR)n 其中 A 代表电荷传输成分，L 代表连接基团，R 代表烃基，n 代表重复段或重复基团的数目。电荷传输元件最好是叔芳基胺、吡唑啉、腙、噁二唑或二苯乙烯。
• Phenolic hole transport polymers, imaging member and method of imaging
  申请人：Xerox Corporation

  公开号：EP1775637B1

  公开（公告）日：2009-11-18