申请人:Clariant GmbH
公开号:US20010013196A1
公开(公告)日:2001-08-16
The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising
A) 5-95% by weight of at least one oil-soluble amphiphile of the formulae
1
in which R
1
is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR
3
, O or S, y is 1, 2, 3 or 4, R
2
is an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R
3
is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or a C
1
-C
20
-alkyl radical, and
B) 5 to 95% by weight of a terpolymer of ethylene, the vinyl ester of one or more aliphatic, linear or branched monocarboxylic acids which contain 2 to 20 carbon atoms in the molecule and a C
5
-C
7
-olefin containing from 9 to 18 mol % of vinyl ester and from 0.5 to 5 mol % of olefin (based in each case on the terpolymer), having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.
本发明涉及用于改善燃料油冷流和润滑性能的添加剂,包括
A) 5-95% (按重量计)的至少一种油溶性双亲化合物,其式为
1
其中 R
1
是具有 1 至 50 个碳原子的烷基、烯基、羟基烷基或芳香基,X 是 NH、NR
3
、O 或 S,y 为 1、2、3 或 4,R
2
是含有羟基且具有 2 至 10 个碳原子的烷基,R
3
是含有氮和/或羟基且具有 2 至 10 个碳原子的烷基,或 C
1
-C
20
-烷基,以及
B) 5%至 95%(按重量计)的乙烯三元共聚物,乙烯基是一种或多种脂肪族、直链或支链单 羧酸的乙烯基酯,分子中含有 2 至 20 个碳原子和一个 C1 -C20 烷基。
5
-C
7
-烯烃,其中乙烯基酯的含量为 9 至 18 摩尔%,烯烃的含量为 0.5 至 5 摩尔%(在每种情况下均以三元共聚物为基准),在 140 摄氏度下测得的熔融粘度为 20 至 10,000 mPas。