palladium ethoxide

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: palladium ethoxide
• 化学式: 2C₂H₅O*Pd
• 分子量: 196.542
• InChiKey: AQZUHSNEOFHQAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.64
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.06
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  palladium ethoxide 在 2,2'-联吡啶 、 氢气 、 氧气 作用下， 生成
  参考文献：
  名称：

  一种新型的巨型钯簇

  摘要：

  电子显微镜，电子衍射，EXAFS和超速离心数据表明，在L = 1,10-菲咯啉或2,2'-联吡啶的存在下，H 2还原Pd（OAc）2可以制备新的催化活性簇， ，其次是O 2处理，包含一个密堆积金属核（570个±30钯原子）轴承60±3协调L和180±10 OAC -在集群的外球。

  DOI：

  10.1039/c39850000937
• 作为产物：
  描述：

  palladium (II) fluoride 、 sodium ethanolate 以 正己烷 为溶剂， 反应 7.0h， 以2.1 g的产率得到palladium ethoxide
  参考文献：
  名称：

  烷氧基金属粉末及制备方法与应用

  摘要：

  本发明涉及一种烷氧基金属粉末的制备方法与应用，应用于烯烃聚合催化剂烷氧基金属载体的制备。烷氧基金属载体的各组份是:金属卤化物、醇钠或醇钾、或溶剂。所述制备烷氧基金属化合物的各组份的摩尔比是：金属卤化物：醇钠或醇钾＝1:(0.001–30)；其中，所述金属卤化物是金属氯化物、金属溴化物、金属氟化物或金属碘化物；其中，所述金属是主族金属、副族金属或VIII族。由该载体制备的催化剂用于制备烯烃聚合催化剂，催化剂活性高、氢调性能好、共聚性能好、聚合物粉末含量低、蜡含量低、颗粒形态好；催化剂用于乙烯均聚合、乙烯与α‑烯烃共聚合或乙烯与极性烯类单体共聚合，丙烯均聚合、丙烯与α‑烯烃共聚合或丙烯与极性烯类单体共聚合。

  公开号：

  CN110483247A

文献信息

• Isostructural [Au₆Pd₆(Pd₆_-<i>x</i>Ni<i>_x</i>)Ni₂₀(CO)₄₄]⁶^- and [Au₆Ni₃₂(CO)₄₄]⁶^- Clusters Containing Corresponding Nonstoichiometric Au₆Pd₆(Pd₆_-<i>x</i>Ni<i>_x</i>)Ni₂₀ and Stoichiometric Au₆Ni₃₂ Nanosized Cores:  Substitutional Pd/Ni Crystal Disorder (Coloring Problem) at Only Six Specific Nonadjacent Pseudoequivalent Metal Sites in the 38-Atom Trimetallic Close-Packed Framework
  作者：Nguyet T. Tran、Masaki Kawano、Douglas R. Powell、Randy K. Hayashi、Charles F. Campana、Lawrence F. Dahl

  DOI：10.1021/ja982637c

  日期：1999.6.1

  Efforts to obtain large trimetallic Au-Pd-Ni carbonyl clusters have given rise to the first reported high-nuclearity trimetallic carbonyl cluster [Au6Pd6(Pd6-xNix)Ni-20(CO)(44)](6-) (1). The centrosymmetric architecture of its 38-atom core ideally consists of the hcp stacking of two inner Au3M3Ni6 and two outer Pd-3 layers along with two Pds-capped and six AuNi2-capped Ni atoms. The resulting octahedral-like Aug kernel is antiprismatically capped on opposite triangular faces by the two Pd3 triangles. The microscopic nature of its nonstoichiometric composition was unequivocally established from complete X-ray diffraction analyses via a SMART CCD system of seven crystals of its [PPh4](+) Salt from different samples. A substitutional Pd/Ni crystal disorder was found at only six specific nonadjacent atomic M sites (three crystallographically independent); for the composite six-site crystal disorder of the (6-x) Pd/x Ni atoms, x was determined for the seven crystals to range from 2.1 (65% Pd, 35% Ni) to 5.5 (8% Pd, 92% Ni). The overall geometry of 1 including the 44 CO ligands (in the crystal-averaged unit cell) ideally has trigonal D-3d((3) over bar 2/m) symmetry. A structure/bonding analysis as to why this particular Pd/Ni substitutional crystal disorder is found in 1 provides a striking illustration that the occurrence of a bimetallic substitutional crystal disorder at only certain crystallographic sites (coloring problem) in a heterometallic carbonyl cluster is critically dependent upon the extent of dissimilarity in the composite relative bond-energy effects of metal-metal/metal-CO interactions. 1 was obtained as a major product (35-40% yields) from reactions of [Ni-6(CO)(12)](2-) With Pd(OAc)(2)/Au(PPh3)Cl mixtures in DMSO. Our desire to obtain the hypothetical isostructural [Au6Ni32(CO)(44)](6-) (2), in which all Pd atoms are replaced with Ni ones, led to the designed synthesis and structural determination of 2, which in turn provided an "operational test" of our "coloring-problem" analysis of 1. The maximum metal-core diameters in 1 and 2 are ca. 1.1 nm parallel and 0.8 nm perpendicular to the principal 3-fold axis.
• 烷氧基金属粉末及制备方法与应用
  申请人：北京国达恒泰科贸有限责任公司

  公开号：CN110483247A

  公开（公告）日：2019-11-22

  本发明涉及一种烷氧基金属粉末的制备方法与应用，应用于烯烃聚合催化剂烷氧基金属载体的制备。烷氧基金属载体的各组份是:金属卤化物、醇钠或醇钾、或溶剂。所述制备烷氧基金属化合物的各组份的摩尔比是：金属卤化物：醇钠或醇钾＝1:(0.001–30)；其中，所述金属卤化物是金属氯化物、金属溴化物、金属氟化物或金属碘化物；其中，所述金属是主族金属、副族金属或VIII族。由该载体制备的催化剂用于制备烯烃聚合催化剂，催化剂活性高、氢调性能好、共聚性能好、聚合物粉末含量低、蜡含量低、颗粒形态好；催化剂用于乙烯均聚合、乙烯与α‑烯烃共聚合或乙烯与极性烯类单体共聚合，丙烯均聚合、丙烯与α‑烯烃共聚合或丙烯与极性烯类单体共聚合。
• A novel giant palladium cluster
  作者：Michail N. Vargaftik、Victor P. Zagorodnikov、Igor P. Stolyarov、Ilya I. Moiseev、Vladimir A. Likholobov、Dmitry I. Kochubey、Andrew L. Chuvilin、Valdimir I. Zaikovsky、Kirill I. Zamaraev、Galina I. Timofeeva

  DOI：10.1039/c39850000937

  日期：——

  and ultracentrifuging data show that a new catalytically active cluster prepared by reduction of Pd(OAc)2 by H2 in the presence of L = 1,10-phenanthroline, or 2,2′-bipyridine, followed by O2 treatment, contains a close-packed metal nucleus (570 ± 30 Pd atoms) bearing 60 ± 3 co-ordinated L and 180 ± 10 OAc– in the outer sphere of the cluster.

  电子显微镜，电子衍射，EXAFS和超速离心数据表明，在L = 1,10-菲咯啉或2,2'-联吡啶的存在下，H 2还原Pd（OAc）2可以制备新的催化活性簇， ，其次是O 2处理，包含一个密堆积金属核（570个±30钯原子）轴承60±3协调L和180±10 OAC -在集群的外球。