2-tert-butyl-5-(5-tert-butyl-2-hydroxyphenyl)-5H-naphtho[2,3-c]phenoxazine-8,13-dione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 英文名称: 2-tert-butyl-5-(5-tert-butyl-2-hydroxyphenyl)-5H-naphtho[2,3-c]phenoxazine-8,13-dione
• 英文别名: 2-Tert-butyl-5-(5-tert-butyl-2-hydroxyphenyl)naphtho[2,3-c]phenoxazine-8,13-dione；2-tert-butyl-5-(5-tert-butyl-2-hydroxyphenyl)naphtho[2,3-c]phenoxazine-8,13-dione
• 化学式: C₃₄H₃₁NO₄
• 分子量: 517.624
• InChiKey: AWMBYFLCMCNHDZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  39
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  66.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  1-(p-tert-butylphenoxy)-2-azidoanthraquinone 以52%的产率得到2-tert-butyl-5H-naphtho[2,3-c]phenoxazine-8,13-dione
  参考文献：
  名称：

  Solid-state photochemical reactions of 1-aryloxy(1-arylthio)-9,10-anthraquinone derivatives

  摘要：

  The photochemistry of derivatives of 1-aryloxy-2(4)-benzoylamino-9,10-anthraquinones and 1-aryloxy(1-arylthio)-2-azido-9,10-anthraquinones in a solid phase differs from that upon irradiation in a benzene solution.

  DOI：

  10.1070/mc2006v016n04abeh002294

文献信息

• Photocyclization of 2-azido-1-(4-tert-butylphenoxy)-9,10-anthraquinone in the presence of substituted phenols
  作者：L. S. Klimenko、I. A. Os’kina、V. M. Vlasov、I. Yu. Bagryanskaya、Yu. V. Gatilov

  DOI：10.1007/s11172-007-0171-4

  日期：2007.6

  New types of phototransformations in the quinone series, viz., photocyclizations of 1-aryloxy-2-azido-9,10-anthraquinone in the presence of phenols, were studied. The photolysis affords mainly 5H-naphtho[2,3-c]phenoxazine-8,13-diones, in which the nitrogen atom is covalently bound to the phenyl ring of the attached phenol. As a result, complex polycyclic derivatives of phenoxazines were prepared in high yields in one step.

  研究了醌系列的新型光转化，即 1-芳氧基-2-叠氮-9,10-蒽醌在苯酚存在下的光环化。光解主要产生 5H-萘并[2,3-c]吩嗪-8,13-二酮，其中的氮原子与所附苯酚的苯基环共价结合。因此，只需一步就能以高产率制备出复杂的吩噁嗪多环衍生物。
• Solid-state photochemical reactions of 1-aryloxy(1-arylthio)-9,10-anthraquinone derivatives
  作者：Lyubov S. Klimenko、Soltan Z. Kusov、Vladislav M. Vlasov、Elena N. Tchabueva、Vladimir V. Boldyrev

  DOI：10.1070/mc2006v016n04abeh002294

  日期：2006.1

  The photochemistry of derivatives of 1-aryloxy-2(4)-benzoylamino-9,10-anthraquinones and 1-aryloxy(1-arylthio)-2-azido-9,10-anthraquinones in a solid phase differs from that upon irradiation in a benzene solution.