三硫代碳酸丁酯钠盐 | 64773-45-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 三硫代碳酸丁酯钠盐
• 英文名称: butyl-trithiocarbonate de sodium
• 英文别名: Sodium n-butyl trithiocarbonate；trithiocarbonic acid monobutyl ester; sodium-salt；Trithiokohlensaeure-monobutylester; Natrium-Salz；Sodium butyl trithiocarbonate；sodium;butylsulfanylmethanedithioate
• CAS: 64773-45-1
• 化学式: C₅H₉S₃*Na
• 分子量: 188.314
• InChiKey: LZIRVILXUYTMFW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.64
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  58.4
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  三硫代碳酸丁酯钠盐 、 肉桂基氯 以 N,N-二甲基甲酰胺 为溶剂， 以90%的产率得到S-cinnamyl butyl trithiocarbonate
  参考文献：
  名称：

  S-cinnamyl esters of thiocarbonic acids as additives to lubricating oils

  摘要：

  A series of cinnamul esters of xanthic, trithiocarbonic, and dithiocarbamic acids were prepared. The optimal conditions of their synthesis were found. The cinnamyl esters were studied by thermal analysis, and the dependence of their lubricating power on the composition and structure was revealed. The tribological properties of lubricating oils with additions of cinnamyl esters of thiocarbonic acids were studied. A correlation between the structure of the esters synthesized and their antiscuff properties was found.

  DOI：

  10.1134/s1070427208090085
• 作为产物：
  描述：

  二硫化碳 、 丁硫醇 以50%的产率得到
  参考文献：
  名称：

  RASHEED K.; WARKENTIN J. D., J. ORG. CHEM., 1980, 45, NO 20, 4041.4044

  摘要：

  DOI：

文献信息

• Cyclization of dinitrophenyl tert-butyl trithiocarbonates. A novel synthesis of nitro-1,3-benzodithiole-2-thiones
  作者：Khalid Rasheed、James D. Warkentin

  DOI：10.1021/jo01308a020

  日期：1980.9
• Reactivite de perfluorohalogenoalcanes (RFI) en presence de couple metallique. Reaction dans le dimethylsulfoxyde en presence d'alcoyl-trithiocarbonate de sodium.
  作者：H. Blancou、A. Commeyras

  DOI：10.1016/s0022-1139(00)82215-0

  日期：1982.4
• RASHEED K.; WARKENTIN J. D., J. ORG. CHEM., 1980, 45, NO 20, 4041.4044
  作者：RASHEED K.、 WARKENTIN J. D.

  DOI：——

  日期：——
• KULIEV, A. M.;KULIEVA, M. A.;GASYMOVA, G. A.;XALILOV, F. S.
  作者：KULIEV, A. M.、KULIEVA, M. A.、GASYMOVA, G. A.、XALILOV, F. S.

  DOI：——

  日期：——
• S-cinnamyl esters of thiocarbonic acids as additives to lubricating oils
  作者：N. P. Mustafaev、M. A. Kulieva、Yu. B. Ramazanova、K. N. Mustafaev、N. N. Novotorzhina

  DOI：10.1134/s1070427208090085

  日期：2008.9

  A series of cinnamul esters of xanthic, trithiocarbonic, and dithiocarbamic acids were prepared. The optimal conditions of their synthesis were found. The cinnamyl esters were studied by thermal analysis, and the dependence of their lubricating power on the composition and structure was revealed. The tribological properties of lubricating oils with additions of cinnamyl esters of thiocarbonic acids were studied. A correlation between the structure of the esters synthesized and their antiscuff properties was found.