4,4'-bis(triphenylethenyl)-1,1'-biphenyl

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4,4'-bis(triphenylethenyl)-1,1'-biphenyl
• 英文别名: 4,4'-bis(1,2,2-triphenylvinyl)-1,1'-biphenyl；BTPE；4,4'-bis(1,2,2-triphenylethenyl)biphenyl；1-(1,2,2-triphenylethenyl)-4-[4-(1,2,2-triphenylethenyl)phenyl]benzene
• 化学式: C₅₂H₃₈
• 分子量: 662.874
• InChiKey: AYYZYPOAOFTMPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.6
• 重原子数：
  52
• 可旋转键数：
  9
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-(4-溴苯基)-1,2,2-三苯乙烯 在 bis-triphenylphosphine-palladium(II) chloride 、 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以60%的产率得到4,4'-bis(triphenylethenyl)-1,1'-biphenyl
  参考文献：
  名称：

  Aggregation-induced emission, self-assembly, and electroluminescence of 4,4′-bis(1,2,2-triphenylvinyl)biphenyl

  摘要：

  二胜于一：在固态下，由两个四苯基乙烯单元组成的发光体（BTPE）比由一个四苯基乙烯单元组成的发光体的发光效率更高；BTPE分子的自组装产生了结晶微纤维，其荧光效率高达100%，聚合诱导发光（δ±AIE§）的效果最大；基于BTPE的电致发光器件的电流效率高达§¼7.3 cd/A。

  DOI：

  10.1039/b915271g

文献信息

• Dimerization of heavy atom free tetraphenylethylene with aggregation induced emission for boosting photodynamic therapy
  作者：Jianjiao Chen、Zhenyuan Zou、Zhen Ke、Xujing Zhang、Jingfei Feng、Yi Jing、Long Peng、Jie Yang、Yansong Dai、Dengfeng Zou

  DOI：10.1039/d0nj01251c

  日期：——

  Heavy atom free BTPE with enhanced ¹O₂ generation ability have potential in PDT.

  重金属自由的BTPE具有增强的1O2产生能力，在光动力疗法中具有潜在应用价值。
• Solid-state nickel(0)-mediated Yamamoto coupling enabled by mechanochemistry
  作者：Koji Kubota、Naoki Shizukuishi、Shotaro Kubo、Hajime Ito

  DOI：10.1093/chemle/upae056

  日期：2024.3.29

  Herein, we report the first solid-state protocol for nickel(0)-mediated Yamamoto-coupling reactions using ball milling. A variety of aryl halides reacted efficiently in the presence of bis(cyclooctadiene)nickel(0) [Ni(cod)2] and 4,4'-di-tert-butyl-2,2'-bipyridyl under solid-state mechanochemical conditions, affording the corresponding biaryls in high yields. Considering that potentially harmful and

  摘要 在此，我们报告了第一个使用球磨进行镍 (0) 介导的 Yamamoto 偶联反应的固态方案。多种芳基卤化物在双(环辛二烯)镍(0)[Ni(cod)2]和4,4'-二叔丁基-2,2'-联吡啶存在下在固态机械化学条件下有效反应，以高产率提供相应的联芳基。考虑到不需要潜在有害的高沸点有机溶剂，本研究为传统的基于溶液的山本偶联提供了一种更方便、更环保、更可持续的替代方案。还描述了固态山本偶联聚合和催化变体的开发。
• Practical Synthesis of Unsymmetrical Tetraarylethylenes and Their Application for the Preparation of [Triphenylethylene−Spacer−Triphenylethylene] Triads
  作者：Moloy Banerjee、Susanna J. Emond、Sergey V. Lindeman、Rajendra Rathore

  DOI：10.1021/jo701474y

  日期：2007.10.1

  [GRAPHICS]We have demonstrated that reactions of diphenylmethyllithium with a variety of substituted benzophenones produces corresponding tertiary alcohols that are easily dehydrated, without any need for purification, to produce various unsymmetrical and symmetrical tetraarylethylenes in excellent yields. The simplicity of the method allows for the preparation of a variety of ethylenic derivatives in multigram (10-50 g) quantities with great ease. The methodology was successfully employed for the preparation of various triphenylethylene (TPE)-based triads (i.e., TPE-spacer-TPE) containing polyphenylene and fluoranyl-based spacers. The ready availability of various substituted tetraarylethylenes allowed us to shed light on the effect of substituents on the oxidation potentials (E-ox) of various tetraarylethylenes. Moreover, the electronic coupling among the triphenylethylene moieties in various TPE-spacer-TPE triads was briefly probed by electrochemical and optical methods.