oplopanone 10-O-β-D-(5-O-syringoyl)apiofuranosyl-(1->2)-β-D-glucopyranoside

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 单宁
• 英文名称: oplopanone 10-O-β-D-(5-O-syringoyl)apiofuranosyl-(1->2)-β-D-glucopyranoside
• 英文别名: [(3S,4S,5S)-5-[(2S,3R,4S,5S,6R)-2-[[(1S,3aR,4R,7S,7aS)-1-acetyl-4-methyl-7-propan-2-yl-1,2,3,3a,5,6,7,7a-octahydroinden-4-yl]oxy]-4,5-dihydroxy-6-(hydroxymethyl)oxan-3-yl]oxy-3,4-dihydroxyoxolan-3-yl]methyl 4-hydroxy-3,5-dimethoxybenzoate
• 化学式: C₃₅H₅₂O₁₅
• 分子量: 712.789
• InChiKey: BEOUIBOLEYQSSU-XLOYSLMFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  50
• 可旋转键数：
  13
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  220
• 氢给体数：
  6
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  oplopanone 10-O-β-D-(5-O-syringoyl)apiofuranosyl-(1->2)-β-D-glucopyranoside 在 盐酸 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 2.0h， 生成 D-apiose 、 葡萄糖
  参考文献：
  名称：

  Chemical constituents from the leaves of Aglaia perviridis

  摘要：

  A new cinnamic acid-derived bisamide 1 and a new oplopanone-type sesquiterpenoid diglycoside 2, together with 11 known compounds, were isolated from the 95% ethanolic extract of the leaves of Aglaia perviridis. Their structures were elucidated by chemical and spectroscopic methods.

  DOI：

  10.1080/10286020903565226

文献信息

• Chemical constituents from the leaves of <i>Aglaia perviridis</i>
  作者：Ling Zhang、Jian-Hui Zhang、Shu-Ming Yang、Chang-Heng Tan、Hong-Feng Luo、Da-Yuan Zhu

  DOI：10.1080/10286020903565226

  日期：2010.3.1

  A new cinnamic acid-derived bisamide 1 and a new oplopanone-type sesquiterpenoid diglycoside 2, together with 11 known compounds, were isolated from the 95% ethanolic extract of the leaves of Aglaia perviridis. Their structures were elucidated by chemical and spectroscopic methods.