(2Z,2'Z)-2,2'-(1,4-phenylene)bis(3-(biphenyl-4-yl)acrylonitrile)

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (2Z,2'Z)-2,2'-(1,4-phenylene)bis(3-(biphenyl-4-yl)acrylonitrile)
• 英文别名: (Z)-2-[4-[(Z)-1-cyano-2-(4-phenylphenyl)ethenyl]phenyl]-3-(4-phenylphenyl)prop-2-enenitrile
• 化学式: C₃₆H₂₄N₂
• 分子量: 484.6
• InChiKey: BEXOXMOAFLBNNI-VJTPSNAYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  38
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,4-苯二乙腈 、 对苯基苯甲醛 在 potassium tert-butylate 作用下， 以 N-甲基吡咯烷酮 、 水 、 乙二醇 为溶剂， 反应 24.0h， 生成 (2Z,2'Z)-2,2'-(1,4-phenylene)bis(3-(biphenyl-4-yl)acrylonitrile)
  参考文献：
  名称：

  使用反应性喷墨印刷方法原位合成刺激响应的发光有机材料†

  摘要：

  我们已经使用反应性喷墨打印系统制备了发光有机材料。通过印刷醛，苯二乙腈和叔丁醇钾，很容易产生刺激（蒸汽/热）响应性荧光染料以及发光共轭聚合物。

  DOI：

  10.1039/c5tc00334b

文献信息

• PHOTOSENSITIVE PLANOGRAPHIC PRINTING PLATE MATERIAL
  申请人：Matsumura Toshiyuki

  公开号：US20090197202A1

  公开（公告）日：2009-08-06

  Disclosed is a photosensitive surface printing plate material which is suitable for the exposure to a laser beam having a light emission wavelength ranging from 350 to 450 nm, is highly sensitive, and has excellent storage stability. The material has a substrate and a photosensitive layer provided on the substrate, wherein the photosensitive layer comprise a polymerization initiator (A), a polymerizable compound (B) having an ethylenic double bond, a sensitizing dye (C), and a polymeric binder (D). In the photosensitive layer, the polymerizable compound (B) comprises a product of the reaction among (a) a compound represented by the general formula (1), (b) a diisocyanate compound and (c) a (methacrylate compound having a hydroxyl group in the molecule. General formula (1): HO—(CH 2 ) n —NH—CHR 1 R 2 wherein R 1 and R 2 independently represent an alkyl group or an aralkyl group, provided that R 1 and R 2 may together form a ring; and n is an integer of 1 to 10.
• In situ synthesis of stimulus-responsive luminescent organic materials using a reactive inkjet printing approach
  作者：Seongho Jeon、Jong Pil Lee、Jong-Man Kim

  DOI：10.1039/c5tc00334b

  日期：——

  We have prepared luminescent organic materials using a reactive inkjet printing system. A stimulus (vapour/heat)-responsive fluorescent dye as well as a luminescent conjugated polymer were readily generated by printing of an aldehyde, a phenylenediacetonitrile, and potassium t-butoxide.

  我们已经使用反应性喷墨打印系统制备了发光有机材料。通过印刷醛，苯二乙腈和叔丁醇钾，很容易产生刺激（蒸汽/热）响应性荧光染料以及发光共轭聚合物。