rhenium(III) iodide

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: rhenium(III) iodide
• 英文别名: rhenium;trihydroiodide
• 化学式: I₃Re
• 分子量: 566.92
• InChiKey: BSMABMYXKITCBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.85
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  rhenium(III) iodide 在 sodium tetrahydroborate 、 庚胺 、 dimethyldioctylammonium iodide 、 氨 作用下， 以 正庚烷 为溶剂， 反应 0.5h， 生成 铼
  参考文献：
  名称：

  Ammonia-in-Oil-Microemulsions and Their Application

  摘要：

  Liquid ammonia on the nanoscale: Ammonia-in-oil microemulsions are used to synthesize Bi, Re, CoN, and GaN nanoparticles, which can be obtained without further thermal treatment. These microemulsions are as reproducible and simple as their water-in-oil conterparts, with the exception of the required low temperature of -40 °C.

  DOI：

  10.1002/anie.201305289

文献信息

• Products of reactions between ReX3 (X=Cl, I) and N-heterocyclic compounds – Structural and spectroscopic studies
  作者：Monika K. Krawczyk、Marta S. Krawczyk、Miłosz Siczek、Tadeusz Lis

  DOI：10.1016/j.ica.2014.04.002

  日期：2014.7

  N-heterocyclic compounds were carried out, which revealed the formation of two sorts of complexes: (I) [Re 3 Cl 6 (μ-Cl) 3 L 3 ] L = pyridine (py), pyrazine (pyz), pyridine 1-oxide (NOpy)} ( 1 – 3 ) and (II) trans- [ReO 2 L 4 ]I (L = py, 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy)) ( 4a – 6c ). The structural studies of the first series (I) revealed that each complex comprises of trinuclear rhenium(III)

  摘要对氯化of（Ⅲ）和碘化（Ⅲ）与N-杂环化合物的反应产物进行了研究，发现形成了两种络合物：（I）[Re 3 Cl 6（μ-Cl） 3 L 3] L =吡啶（py），吡嗪（pyz），1-氧化吡啶（NOpy）}（1-3）和（II）反式[ReO 2 L 4] I（L = py，3-甲基吡啶（3-Mepy），4-甲基吡啶（4-Mepy））（4a – 6c）。第一个系列（I）的结构研究表明，每个配合物均包含三核rh（III）核，该核由三个带有三个末端氯代配体和三个N-杂环配体的μ-氯代配体桥接。第二类产品是单核rh（V）反式-二氧化物复合物。所有配合物的特征均在于单晶X射线衍射，NMR，IR，FIR，UV-Vis光谱，
• Specific Features of the Coordination of [Ni(Еn)2]2+ Cations to the [{Re4(µ3-CCN)4}(CN)12]8– Cluster Anion
  作者：A. S. Pronin、A. I. Smolentsev、Yu. V. Mironov

  DOI：10.1134/s1070328421080054

  日期：2021.8

  complex (Me4N)K7[Re4(µ3-CCN)4}(CN)12]·10H2O (I) is synthesized by the high-temperature reaction of ReI3 with KCN and subsequent recrystallization from an aqueous solution with the addition of Me4NI. The anion of complex I contains ligands µ3-CCN3– stabilized due to coordination to the triangular faces of the Re4} tetrahedral metal cluster. It is shown for [Ni(Еn)2]2+ as an example that the µ3-CCN3–

  摘要 簇配合物 (Me 4 N)K 7 [Re 4 (µ 3 -CCN) 4 }(CN) 12 ]·10H 2 O ( I ) 通过 ReI 3与 KCN的高温反应和随后的重结晶合成从添加 Me 4 NI的水溶液中提取。配合物I的阴离子包含配体 μ 3 -CCN 3–由于与 Re 4 } 四面体金属簇的三角形面配位而稳定。以[Ni(Еn) 2 ] 2+为例，μ 3-CCN 3–配体是双齿的，可以与类似于端基 CN 基团的过渡金属阳离子相互作用，提供配位聚合物 [Ni(En) 2 (NH 3 ) 2 ][Ni(En) 2 } 3 Re 4 ( µ 3 -CCN) 4 }(CN) 12 ]·7.5H 2 O ( II )。复合物I和II的结构由 X 射线衍射分析确定（CIF 文件 ССDС 编号 2057450 ( I ) 和 2057451 ( II )）。
• Cation effect on the structure of tetrahedral rhenium arsenide cyano clusters
  作者：A. S. Pronin、A. I. Smolentsev、Y. V. Mironov

  DOI：10.1007/s11172-020-3010-5

  日期：2020.11

  New cyanometallate cluster complexes of the composition Na8[Re4As1.5(AsO)2.5}(CN) 12]··20.5H2O (1) and Cs7K[Re4As2(AsO)2}(CN)12]·12H2O (2) were synthesized by high-temperature reactions of ReI3 with As and MCN (M is Na or Cs) followed by the recrystallization of the soluble products from water. The crystal structures of the synthesized compounds were studied by X-ray diffraction. An increase in the

  组成为 Na8[Re4As1.5(AsO)2.5}(CN) 12]··20.5H2O (1) 和 Cs7K[Re4As2(AsO)2}(CN)12]·12H2O (2) 的新型氰基金属化物簇配合物通过 ReI3 与 As 和 MCN（M 是 Na 或 Cs）的高温反应合成，然后从水中重结晶可溶性产物。通过X射线衍射研究了合成化合物的晶体结构。阳离子离子半径的增加导致晶格从单斜晶格到四方晶格的对称性增加。
• Synthesis and Structure of a Tetrahedral Rhenium Complex with a Mixed-Ligand Cluster Core {Re4As0.75(AsO)2.25Te}5+
  作者：A. S. Pronin、A. I. Smolentsev、Yu. V. Mironov

  DOI：10.1134/s0022476620010102

  日期：2020.1

  A novel mixed-ligand cluster complex of the composition K7[Re4As0.75(AsO)2,25Te}(CN)12]·9H2O is obtained by a high-temperature reaction of ReI3, As, and Te with KCN followed by recrystallization from an aqueous solution. The structure of the complex is determined by X-ray crystallography. The compound crystallizes in the triclinic crystal system, space group P1¯\documentclass[12pt]minimal} \usepackageamsmath}

  通过 ReI3、As 和 Te 与 KCN 的高温反应，然后重结晶，获得了一种新型混合配体簇复合物，其组成为 K7[Re4As0.75(AsO)2,25Te}(CN)12]·9H2O来自水溶液。复合物的结构由 X 射线晶体学确定。该化合物在三斜晶系中结晶，空间群 P1¯\documentclass[12pt]minimal} \usepackageamsmath} \usepackagewasysym} \usepackageamsfonts} \usepackageamssymb} \usepackageamsbsy} \usepackagemathrsfs } \usepackageupgreek} \setlength\oddsidemargin}-69pt} \begindocument}$$P\overline 1 $$\enddocument} 单元格参数
• SYNTHESIS AND STRUCTURE OF A RHENIUM TETRAHEDRAL CLUSTER COMPLEX WITH THE {Re4(PO)4}4+ CORE
  作者：A. S. Pronin、K. A. Brylev、M. Ströbele、H. -J. Meyer、Yu. V. Mironov

  DOI：10.1134/s002247662107012x

  日期：2021.7

  rhenium(III) iodide and red phosphorus with an excess of sodium cyanide followed by recrystallization from an aqueous solution a new tetrahedral [Re4(PO)4}(CN)12]8– anionic cluster complex is obtained. It is isolated as a salt of the composition Na8[Re4(PO)4}(CN)12] 18H2O·MeOH. The structure of the obtained compound is determined by X-ray crystallography. The compound crystallizes in the monoclinic crystal system

  摘要 通过碘化铼 (III) 和红磷与过量氰化钠的高温反应，然后从水溶液中重结晶形成新的四面体 [Re 4 (PO) 4 }(CN) 12 ] 8–阴离子簇配合物获得。它被分离为组成为 Na 8 [Re 4 (PO) 4 }(CN) 12 ] 18H 2 O·MeOH的盐。所得化合物的结构由X射线晶体学确定。化合物在单斜晶系中结晶，P 2 1 / n空间群，晶胞参数a = 26.826(3) Å, b  = 11.4975(12) Å, c  = 29.141(3) Å, β = 97.879(2)°, V  = 8903.2(16) Å 3 , Z  = 8。