1,2,4,5-tetra-1'-naphthylbenzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2,4,5-tetra-1'-naphthylbenzene
• 英文别名: 1,2,4,5-tetra(naphthalen-1-yl)benzene；1-(2,4,5-Trinaphthalen-1-ylphenyl)naphthalene
• 化学式: C₄₆H₃₀
• 分子量: 582.744
• InChiKey: LSRIIIQLEZAIBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  46
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2,4,5-tetra-1'-naphthylbenzene 在 iron(III) chloride 作用下， 以 硝基甲烷 、 二氯甲烷 为溶剂， 反应 12.0h， 以72%的产率得到
  参考文献：
  名称：

  Nonlinear Polyfused Aromatics with Extended π-Conjugation from Phenanthrotriphenylene, Tetracene, and Pentacene: Syntheses, Crystal Packings, and Properties

  摘要：

  New classes of nonlinear polyaromatics with extended conjugation at lateral and longitudinal directions from triphenylene, tetracene, and pentacene backbones are reported. These planar and twisted polyfused aromatics are obtained through specific and selective multifold Scholl reactions from predesigned polyaryls. These derivatives displayed shifted or perfect cofacial packing motifs. Single crystals of one derivative, phenanthro[9,10:b]triphenylene, were used as p-channel materials in fabricating transistor devices, which exhibited an average mobility of 0.38 cm(2) s(-1) and a maximum mobility reaching 1.15 cm(2) V-1 s(-1)

  DOI：

  10.1021/acs.joc.8b01582
• 作为产物：
  描述：

  1,4-二氯苯 、 alkaline earth salt of/the/ methylsulfuric acid 在 硫酸 、 三氧化硫 、 溴 、 碘 、 铁粉 、 magnesium 作用下， 反应 19.0h， 生成 1,2,4,5-tetra-1'-naphthylbenzene
  参考文献：
  名称：

  Reaction of aryl Grignard reagents with hexahalobenzenes: novel arenes via multiple aryne sequence

  摘要：

  DOI：

  10.1021/jo00350a018

文献信息

• HARADA, KATSUMASA;HART, H.;DU, CHI-JEN, F., J. ORG. CHEM., 1985, 50, N 26, 5524-5528
  作者：HARADA, KATSUMASA、HART, H.、DU, CHI-JEN, F.

  DOI：——

  日期：——
• Reaction of aryl Grignard reagents with hexahalobenzenes: novel arenes via multiple aryne sequence
  作者：Katsumasa Harada、Harold Hart、Chi Jen Frank Du

  DOI：10.1021/jo00350a018

  日期：1985.12
• Nonlinear Polyfused Aromatics with Extended π-Conjugation from Phenanthrotriphenylene, Tetracene, and Pentacene: Syntheses, Crystal Packings, and Properties
  作者：Sushil Kumar、Ding-Chi Huang、Samala Venkateswarlu、Yu-Tai Tao

  DOI：10.1021/acs.joc.8b01582

  日期：2018.10.5

  New classes of nonlinear polyaromatics with extended conjugation at lateral and longitudinal directions from triphenylene, tetracene, and pentacene backbones are reported. These planar and twisted polyfused aromatics are obtained through specific and selective multifold Scholl reactions from predesigned polyaryls. These derivatives displayed shifted or perfect cofacial packing motifs. Single crystals of one derivative, phenanthro[9,10:b]triphenylene, were used as p-channel materials in fabricating transistor devices, which exhibited an average mobility of 0.38 cm(2) s(-1) and a maximum mobility reaching 1.15 cm(2) V-1 s(-1)