1,3-dicyclohexyl-1-tetrathiafulvalenyl-urea

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: 1,3-dicyclohexyl-1-tetrathiafulvalenyl-urea
• 英文别名: N-cyclohexyl-N-(cyclohexylcarbamoyl)-2-(1,3-dithiol-2-ylidene)-1,3-dithiole-4-carboxamide
• 化学式: C₂₀H₂₆N₂O₂S₄
• 分子量: 454.703
• InChiKey: QXTYQFUDDBXEPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  151
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  tetrathiafulvalene-4-carboxylic acid 、 N,N'-二环己基碳二亚胺 在 4-二甲氨基吡啶 、 2-(6-hydroxyhexyloxy)-3-methoxy-6,7,10,11-tetrahexyloxytriphenylene 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以94%的产率得到1,3-dicyclohexyl-1-tetrathiafulvalenyl-urea
  参考文献：
  名称：

  Synthesis and Characterisation of Tetrathiafulvalenyl- and Ferrocenyl-Triphenylenes

  摘要：

  The synthesis, electrochemistry and mesogenic properties of novel tetrathiafulvalenyl- and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivatives displaying a discotic mesophase. Solution electrochemistry of derivatives 7 and 13 has revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(00)00250-7

文献信息

• Synthesis and Characterisation of Tetrathiafulvalenyl- and Ferrocenyl-Triphenylenes
  作者：Graeme Cooke、Abdulla Radhi、Neville Boden、Richard J Bushby、Zhibao Lu、Sarah Brown、Sarah L Heath

  DOI：10.1016/s0040-4020(00)00250-7

  日期：2000.5

  The synthesis, electrochemistry and mesogenic properties of novel tetrathiafulvalenyl- and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivatives displaying a discotic mesophase. Solution electrochemistry of derivatives 7 and 13 has revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. (C) 2000 Elsevier Science Ltd. All rights reserved.